Lutetium functionalities supported by a sterically encumbered β-diketiminate ligand

Ross J. Beattie; Andrew D. Sutton; Brian L. Scott; David L. Clark; Jaqueline L. Kiplinger; John C. Gordon

doi:10.1016/j.jorganchem.2017.12.032

Lutetium functionalities supported by a sterically encumbered β-diketiminate ligand

Ross J. Beattie, Andrew D. Sutton, Brian L. Scott, David L. Clark, Jaqueline L. Kiplinger, John C. Gordon

Research output: Contribution to journal › Article › peer-review

5 Scopus citations

Abstract

The sterically encumbered NacNac ligand, [HC(MeCNAr)₂]⁻ (Ar = 2,6-i-Pr₂C₆H₃), was investigated as a platform for supporting Lu-halide complexes, sought for their potential capability of being further converted into hydrocarbyl derivatives via metathetical chemistries with alkali metal alkyls. These substituted analogs were targeted as potentially viable candidates for alkane elimination chemistries, with an eye towards the formation of an isolable Lu-alkylidene fragment.

Original language	English
Pages (from-to)	187-190
Number of pages	4
Journal	Journal of Organometallic Chemistry
Volume	857
DOIs	https://doi.org/10.1016/j.jorganchem.2017.12.032
State	Published - Feb 15 2018
Externally published	Yes

Funding

ADS acknowledges the G.T. Seaborg Institute at Los Alamos National Laboratory for funding a Postdoctoral Fellowship. Los Alamos National Laboratory is operated by Los Alamos National Security, LLC, for the National Nuclear Security Administration of the U.S. Department of Energy under contract DE-AC5206NA25396.

Funders	Funder number
G.T. Seaborg Institute
U.S. Department of Energy	DE-AC5206NA25396
National Nuclear Security Administration
Los Alamos National Laboratory

Keywords

Alkyl
Alkylidene
Chloride/Halide
Lutetium
NacNac

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10.1016/j.jorganchem.2017.12.032

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title = "Lutetium functionalities supported by a sterically encumbered β-diketiminate ligand",

abstract = "The sterically encumbered NacNac ligand, [HC(MeCNAr)2]− (Ar = 2,6-i-Pr2C6H3), was investigated as a platform for supporting Lu-halide complexes, sought for their potential capability of being further converted into hydrocarbyl derivatives via metathetical chemistries with alkali metal alkyls. These substituted analogs were targeted as potentially viable candidates for alkane elimination chemistries, with an eye towards the formation of an isolable Lu-alkylidene fragment.",

keywords = "Alkyl, Alkylidene, Chloride/Halide, Lutetium, NacNac",

author = "Beattie, {Ross J.} and Sutton, {Andrew D.} and Scott, {Brian L.} and Clark, {David L.} and Kiplinger, {Jaqueline L.} and Gordon, {John C.}",

note = "Publisher Copyright: {\textcopyright} 2018 Elsevier B.V.",

year = "2018",

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day = "15",

doi = "10.1016/j.jorganchem.2017.12.032",

language = "English",

volume = "857",

pages = "187--190",

journal = "Journal of Organometallic Chemistry",

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T1 - Lutetium functionalities supported by a sterically encumbered β-diketiminate ligand

AU - Beattie, Ross J.

AU - Sutton, Andrew D.

AU - Scott, Brian L.

AU - Clark, David L.

AU - Kiplinger, Jaqueline L.

AU - Gordon, John C.

PY - 2018/2/15

Y1 - 2018/2/15

N2 - The sterically encumbered NacNac ligand, [HC(MeCNAr)2]− (Ar = 2,6-i-Pr2C6H3), was investigated as a platform for supporting Lu-halide complexes, sought for their potential capability of being further converted into hydrocarbyl derivatives via metathetical chemistries with alkali metal alkyls. These substituted analogs were targeted as potentially viable candidates for alkane elimination chemistries, with an eye towards the formation of an isolable Lu-alkylidene fragment.

AB - The sterically encumbered NacNac ligand, [HC(MeCNAr)2]− (Ar = 2,6-i-Pr2C6H3), was investigated as a platform for supporting Lu-halide complexes, sought for their potential capability of being further converted into hydrocarbyl derivatives via metathetical chemistries with alkali metal alkyls. These substituted analogs were targeted as potentially viable candidates for alkane elimination chemistries, with an eye towards the formation of an isolable Lu-alkylidene fragment.

KW - Alkyl

KW - Alkylidene

KW - Chloride/Halide

KW - Lutetium

KW - NacNac

UR - http://www.scopus.com/inward/record.url?scp=85040662777&partnerID=8YFLogxK

U2 - 10.1016/j.jorganchem.2017.12.032

DO - 10.1016/j.jorganchem.2017.12.032

M3 - Article

AN - SCOPUS:85040662777

SN - 0022-328X

VL - 857

SP - 187

EP - 190

JO - Journal of Organometallic Chemistry

JF - Journal of Organometallic Chemistry

ER -

Lutetium functionalities supported by a sterically encumbered β-diketiminate ligand

Abstract

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Keywords

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