TY - JOUR
T1 - Luminescent phosphonium polyelectrolyte prepared from a diphosphine chromophore
T2 - Synthesis, photophysics, and layer-by-layer assembly
AU - Tennyson, Eleanor G.
AU - He, Susan
AU - Osti, Naresh C.
AU - Perahia, Dvora
AU - Smith, Rhett C.
PY - 2010/10/7
Y1 - 2010/10/7
N2 - A luminescent phosphonium-containing polyelectrolyte (P1-OHx) has been prepared by polymerization of a chromophore-containing diphosphine. The resultant cationic polyelectrolyte displays solvatochromism and undergoes facile layer-by-layer assembly with anionic poly(acrylic acid) to form smooth, well-defined films. Solution and film characterization by absorption and photoluminescence spectroscopy, and AFM imaging of films, are reported.
AB - A luminescent phosphonium-containing polyelectrolyte (P1-OHx) has been prepared by polymerization of a chromophore-containing diphosphine. The resultant cationic polyelectrolyte displays solvatochromism and undergoes facile layer-by-layer assembly with anionic poly(acrylic acid) to form smooth, well-defined films. Solution and film characterization by absorption and photoluminescence spectroscopy, and AFM imaging of films, are reported.
UR - https://www.scopus.com/pages/publications/77956456619
U2 - 10.1039/c0jm01430c
DO - 10.1039/c0jm01430c
M3 - Article
AN - SCOPUS:77956456619
SN - 0959-9428
VL - 20
SP - 7984
EP - 7989
JO - Journal of Materials Chemistry
JF - Journal of Materials Chemistry
IS - 37
ER -