Luminescent lanthanide coordination polymers synthesized via in-situ hydrolysis of dimethyl-3,4-furandicarboxylate

Natalie E. Greig; Jeffrey D. Einkauf; Jessica M. Clark; Eric J. Corcoran; Joseph P. Karram; Charles A. Kent; Vadine E. Eugene; Benny C. Chan; Daniel T. De Lill

doi:10.1016/j.jssc.2015.01.014

Luminescent lanthanide coordination polymers synthesized via in-situ hydrolysis of dimethyl-3,4-furandicarboxylate

Natalie E. Greig, Jeffrey D. Einkauf, Jessica M. Clark, Eric J. Corcoran, Joseph P. Karram, Charles A. Kent, Vadine E. Eugene, Benny C. Chan, Daniel T. De Lill

Research output: Contribution to journal › Article › peer-review

15 Scopus citations

Abstract

Dimethyl-3,4-furandicarboxylate undergoes hydrolysis under hydrothermal conditions with lanthanide (Ln) ions to form two-dimensional coordination polymers, [Ln(C₆H₂O₅)(C₆H₃O₅)(H₂O)]_n (Ln=Sm, Eu, Gd, Tb, Dy, Ho, Er, Tm, Yb, Lu). The resulting materials exhibit luminescent properties with quantum yields and lifetimes for the Eu(III) and Tb(III) compounds of 1.1±0.3% and 0.387±0.0001 ms, and 3.3±0.8% and 0.769±0.006 ms, respectively. Energy values for the singlet and triplet states were determined for dimethyl-3,4-furandicarboxylate and 3,4-furandicarboxylic acid. Excited state dynamics and structural features are examined to explicate the reported quantum yields. A series of other FDC structures is briefly presented.

Original language	English
Pages (from-to)	402-409
Number of pages	8
Journal	Journal of Solid State Chemistry
Volume	225
DOIs	https://doi.org/10.1016/j.jssc.2015.01.014
State	Published - May 2015
Externally published	Yes

Funding

The authors would like to thank Florida Atlantic University for funding this project along with the NSF MRI Grant (No. 0922931 ). The authors would also like to thank Andrew Kerr and Dr. Christopher L. Cahill at The George Washington University for PXRD data, and Dr. Sharon Rivera for assistance with Gaussian. Many of the undergraduate students working on this project were funded through grants from FAU׳s Office of Undergraduate Research and Inquiry.

Funders	Funder number
FAU׳s Office of Undergraduate Research and Inquiry
NSF MRI	0922931
Florida Atlantic University

Keywords

Coordination polymers
Crystal structure
Lanthanide luminescence
Quantum yield

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10.1016/j.jssc.2015.01.014

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@article{2ed64d3a9e1c4ba1a6d4e9ba4143dbe7,

title = "Luminescent lanthanide coordination polymers synthesized via in-situ hydrolysis of dimethyl-3,4-furandicarboxylate",

abstract = "Dimethyl-3,4-furandicarboxylate undergoes hydrolysis under hydrothermal conditions with lanthanide (Ln) ions to form two-dimensional coordination polymers, [Ln(C6H2O5)(C6H3O5)(H2O)]n (Ln=Sm, Eu, Gd, Tb, Dy, Ho, Er, Tm, Yb, Lu). The resulting materials exhibit luminescent properties with quantum yields and lifetimes for the Eu(III) and Tb(III) compounds of 1.1±0.3% and 0.387±0.0001 ms, and 3.3±0.8% and 0.769±0.006 ms, respectively. Energy values for the singlet and triplet states were determined for dimethyl-3,4-furandicarboxylate and 3,4-furandicarboxylic acid. Excited state dynamics and structural features are examined to explicate the reported quantum yields. A series of other FDC structures is briefly presented.",

keywords = "Coordination polymers, Crystal structure, Lanthanide luminescence, Quantum yield",

author = "Greig, {Natalie E.} and Einkauf, {Jeffrey D.} and Clark, {Jessica M.} and Corcoran, {Eric J.} and Karram, {Joseph P.} and Kent, {Charles A.} and Eugene, {Vadine E.} and Chan, {Benny C.} and {De Lill}, {Daniel T.}",

year = "2015",

month = may,

doi = "10.1016/j.jssc.2015.01.014",

language = "English",

volume = "225",

pages = "402--409",

journal = "Journal of Solid State Chemistry",

issn = "0022-4596",

publisher = "Elsevier",

}

TY - JOUR

T1 - Luminescent lanthanide coordination polymers synthesized via in-situ hydrolysis of dimethyl-3,4-furandicarboxylate

AU - Greig, Natalie E.

AU - Einkauf, Jeffrey D.

AU - Clark, Jessica M.

AU - Corcoran, Eric J.

AU - Karram, Joseph P.

AU - Kent, Charles A.

AU - Eugene, Vadine E.

AU - Chan, Benny C.

AU - De Lill, Daniel T.

PY - 2015/5

Y1 - 2015/5

N2 - Dimethyl-3,4-furandicarboxylate undergoes hydrolysis under hydrothermal conditions with lanthanide (Ln) ions to form two-dimensional coordination polymers, [Ln(C6H2O5)(C6H3O5)(H2O)]n (Ln=Sm, Eu, Gd, Tb, Dy, Ho, Er, Tm, Yb, Lu). The resulting materials exhibit luminescent properties with quantum yields and lifetimes for the Eu(III) and Tb(III) compounds of 1.1±0.3% and 0.387±0.0001 ms, and 3.3±0.8% and 0.769±0.006 ms, respectively. Energy values for the singlet and triplet states were determined for dimethyl-3,4-furandicarboxylate and 3,4-furandicarboxylic acid. Excited state dynamics and structural features are examined to explicate the reported quantum yields. A series of other FDC structures is briefly presented.

AB - Dimethyl-3,4-furandicarboxylate undergoes hydrolysis under hydrothermal conditions with lanthanide (Ln) ions to form two-dimensional coordination polymers, [Ln(C6H2O5)(C6H3O5)(H2O)]n (Ln=Sm, Eu, Gd, Tb, Dy, Ho, Er, Tm, Yb, Lu). The resulting materials exhibit luminescent properties with quantum yields and lifetimes for the Eu(III) and Tb(III) compounds of 1.1±0.3% and 0.387±0.0001 ms, and 3.3±0.8% and 0.769±0.006 ms, respectively. Energy values for the singlet and triplet states were determined for dimethyl-3,4-furandicarboxylate and 3,4-furandicarboxylic acid. Excited state dynamics and structural features are examined to explicate the reported quantum yields. A series of other FDC structures is briefly presented.

KW - Coordination polymers

KW - Crystal structure

KW - Lanthanide luminescence

KW - Quantum yield

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U2 - 10.1016/j.jssc.2015.01.014

DO - 10.1016/j.jssc.2015.01.014

M3 - Article

AN - SCOPUS:84922344246

SN - 0022-4596

VL - 225

SP - 402

EP - 409

JO - Journal of Solid State Chemistry

JF - Journal of Solid State Chemistry

ER -

Luminescent lanthanide coordination polymers synthesized via in-situ hydrolysis of dimethyl-3,4-furandicarboxylate

Abstract

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Keywords

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