Luminescence from neptunyl(VI) species in solution

Catherine Talbot-Eeckelaers; Simon J.A. Pope; Amanda J. Hynes; Roy Copping; Chris J. Jones; Robin J. Taylor; Stephen Faulkner; Daniel Sykes; Francis R. Livens; Iain May

doi:10.1021/ja068522n

Luminescence from neptunyl(VI) species in solution

Catherine Talbot-Eeckelaers, Simon J.A. Pope, Amanda J. Hynes, Roy Copping, Chris J. Jones, Robin J. Taylor, Stephen Faulkner, Daniel Sykes, Francis R. Livens, Iain May

Research output: Contribution to journal › Article › peer-review

36 Scopus citations

Abstract

The luminescence from the neptunyl(VI) ion and its polyoxometallate complexes has been investigated in solution for the first time. Emission occurs in the near-IR and is quenched effectively by O-H oscillators in the hydrated ion. The polyoxometallate complexes exclude solvent from the neptunyl coordination sphere and have much more intense and longer-lived emission spectra.

Original language	English
Pages (from-to)	2442-2443
Number of pages	2
Journal	Journal of the American Chemical Society
Volume	129
Issue number	9
DOIs	https://doi.org/10.1021/ja068522n
State	Published - Mar 7 2007
Externally published	Yes

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title = "Luminescence from neptunyl(VI) species in solution",

abstract = "The luminescence from the neptunyl(VI) ion and its polyoxometallate complexes has been investigated in solution for the first time. Emission occurs in the near-IR and is quenched effectively by O-H oscillators in the hydrated ion. The polyoxometallate complexes exclude solvent from the neptunyl coordination sphere and have much more intense and longer-lived emission spectra.",

author = "Catherine Talbot-Eeckelaers and Pope, {Simon J.A.} and Hynes, {Amanda J.} and Roy Copping and Jones, {Chris J.} and Taylor, {Robin J.} and Stephen Faulkner and Daniel Sykes and Livens, {Francis R.} and Iain May",

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T1 - Luminescence from neptunyl(VI) species in solution

AU - Talbot-Eeckelaers, Catherine

AU - Pope, Simon J.A.

AU - Hynes, Amanda J.

AU - Copping, Roy

AU - Jones, Chris J.

AU - Taylor, Robin J.

AU - Faulkner, Stephen

AU - Sykes, Daniel

AU - Livens, Francis R.

AU - May, Iain

PY - 2007/3/7

Y1 - 2007/3/7

N2 - The luminescence from the neptunyl(VI) ion and its polyoxometallate complexes has been investigated in solution for the first time. Emission occurs in the near-IR and is quenched effectively by O-H oscillators in the hydrated ion. The polyoxometallate complexes exclude solvent from the neptunyl coordination sphere and have much more intense and longer-lived emission spectra.

AB - The luminescence from the neptunyl(VI) ion and its polyoxometallate complexes has been investigated in solution for the first time. Emission occurs in the near-IR and is quenched effectively by O-H oscillators in the hydrated ion. The polyoxometallate complexes exclude solvent from the neptunyl coordination sphere and have much more intense and longer-lived emission spectra.

UR - http://www.scopus.com/inward/record.url?scp=33847655151&partnerID=8YFLogxK

U2 - 10.1021/ja068522n

DO - 10.1021/ja068522n

M3 - Article

AN - SCOPUS:33847655151

SN - 0002-7863

VL - 129

SP - 2442

EP - 2443

JO - Journal of the American Chemical Society

JF - Journal of the American Chemical Society

IS - 9

ER -

Luminescence from neptunyl(VI) species in solution

Abstract

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