Abstract
The mesoscopic structure of the binary system isobutyric acid+heavy water (D2 O) confined in a porous glass (controlled-pore silica glass, mean pore width ca. 10 nm) was studied by small-angle neutron scattering at off-critical compositions in a temperature range above and below the upper critical solution point. The scattering data were analyzed in terms of a structure factor model similar to that proposed by Formisano and Teixeira [Eur. Phys. J. E 1, 1 (2000)], but allowing for both Ornstein-Zernike-type composition fluctuations and domainlike structures in the microphase-separated state of the pore liquid. The results indicate that the phase separation in the pores is shifted by ca. 10 K and spread out in temperature. Microphase separation is pictured as a transition from partial segregation at high temperature, due to the strong preferential adsorption of water at the pore wall, to a tube or capsule configuration of the two phases at low temperatures, depending on the overall composition of the pore liquid. Results for samples in which the composition of the pore liquid can vary with temperature due to equilibration with extra-pore liquid are consistent with this picture.
| Original language | English |
|---|---|
| Article number | 244718 |
| Journal | Journal of Chemical Physics |
| Volume | 122 |
| Issue number | 24 |
| DOIs | |
| State | Published - 2005 |
Funding
The authors wish to thank J. Teixeira and T. Hellweg for valuable discussions on several aspects of the data analysis. This work was supported by the Deutsche Forschungsgemeinschaft through the Sonderforschungsbereich 448 “Mesoscopically Organized Composites.”