Abstract
The low-cost hydrogen production from water electrolysis is crucial to the deployment of sustainable hydrogen economy but is currently constrained by the lack of active and robust electrocatalysts from earth-abundant materials. We describe here an unconventional heterostructure composed of strongly coupled Ni-deficient LixNiO nanoclusters and polycrystalline Ni nanocrystals and its exceptional activities toward the hydrogen evolution reaction (HER) in aqueous electrolytes. The presence of lattice oxygen species with strong Brønsted basicity is a significant feature in such heterostructure, which spontaneously split water molecules for accelerated Volmer H-OH dissociation in neutral and alkaline HER. In combination with the intimate LixNiO and Ni interfacial junctions that generate localized hotspots for promoted hydride coupling and hydrogen desorption, the catalysts produce hydrogen at a current density of 10 mA cm-2 under overpotentials of only 20, 50, and 36 mV in acidic, neutral, and alkaline electrolytes, respectively, making them among the most active Pt-free catalysts developed thus far. In addition, such heterostructures also exhibited superior activity toward the hydrogen oxidation reaction in alkaline electrolytes.
| Original language | English |
|---|---|
| Pages (from-to) | 12613-12619 |
| Number of pages | 7 |
| Journal | Journal of the American Chemical Society |
| Volume | 142 |
| Issue number | 29 |
| DOIs | |
| State | Published - Jul 22 2020 |
| Externally published | Yes |
Funding
This work is supported by startup funds provided by Northern Illinois University. Y.S. acknowledges support from the U.S. Department of Energy’s Fuel Cell Technology Office. This work was performed, in part, at the Center for Nanoscale Materials, a U.S. Department of Energy Office of Science User Facility, supported by the U.S. Department of Energy, Office of Science, under contract no. DE-AC02-06CH11357. This research used resources of the Advanced Light Source, a DOE Office of Science User Facility under contract no. DE-AC02-05CH11231. This work was supported by Northern Illinois University’s Molecular Analysis Core Facility.
