Lipophilic Re(CO)3pyca complexes for Mid-IR imaging applications

Briana R. Schrage; Baylee R. Frisinger; Sarah J. Schmidtke Sobeck; Christopher J. Ziegler

doi:10.1039/d0dt03743e

Lipophilic Re(CO)₃pyca complexes for Mid-IR imaging applications

Briana R. Schrage, Baylee R. Frisinger, Sarah J. Schmidtke Sobeck, Christopher J. Ziegler

Research output: Contribution to journal › Article › peer-review

3 Scopus citations

Abstract

Several Re(i)pyca conjugates incorporating long aliphatic amines have been synthesized through a one-pot methodology. The compounds have been fully characterized, and seven compounds have been structurally elucidated by single crystal X-ray diffraction. The C14 variant was probed as a potential organometallic IR dye. Large unilamellar vesicles were generated with DOPC and the C14 compound and we observed incorporation of the rhenium complex as observed by FTIR microscopy.

Original language	English
Pages (from-to)	1069-1075
Number of pages	7
Journal	Dalton Transactions
Volume	50
Issue number	3
DOIs	https://doi.org/10.1039/d0dt03743e
State	Published - Jan 21 2021
Externally published	Yes

Funding

CJZ acknowledges the National Institutes of Health (1R15GM119030) for support of this research.

Access to Document

10.1039/d0dt03743e

Cite this

@article{17f7bc327c3b464eac1e0d5d081b3008,

title = "Lipophilic Re(CO)3pyca complexes for Mid-IR imaging applications",

abstract = "Several Re(i)pyca conjugates incorporating long aliphatic amines have been synthesized through a one-pot methodology. The compounds have been fully characterized, and seven compounds have been structurally elucidated by single crystal X-ray diffraction. The C14 variant was probed as a potential organometallic IR dye. Large unilamellar vesicles were generated with DOPC and the C14 compound and we observed incorporation of the rhenium complex as observed by FTIR microscopy.",

author = "Schrage, \{Briana R.\} and Frisinger, \{Baylee R.\} and \{Schmidtke Sobeck\}, \{Sarah J.\} and Ziegler, \{Christopher J.\}",

note = "Publisher Copyright: {\textcopyright} The Royal Society of Chemistry.",

year = "2021",

month = jan,

day = "21",

doi = "10.1039/d0dt03743e",

language = "English",

volume = "50",

pages = "1069--1075",

journal = "Dalton Transactions",

issn = "1477-9226",

publisher = "Royal Society of Chemistry",

number = "3",

}

TY - JOUR

T1 - Lipophilic Re(CO)3pyca complexes for Mid-IR imaging applications

AU - Schrage, Briana R.

AU - Frisinger, Baylee R.

AU - Schmidtke Sobeck, Sarah J.

AU - Ziegler, Christopher J.

N1 - Publisher Copyright: © The Royal Society of Chemistry.

PY - 2021/1/21

Y1 - 2021/1/21

N2 - Several Re(i)pyca conjugates incorporating long aliphatic amines have been synthesized through a one-pot methodology. The compounds have been fully characterized, and seven compounds have been structurally elucidated by single crystal X-ray diffraction. The C14 variant was probed as a potential organometallic IR dye. Large unilamellar vesicles were generated with DOPC and the C14 compound and we observed incorporation of the rhenium complex as observed by FTIR microscopy.

AB - Several Re(i)pyca conjugates incorporating long aliphatic amines have been synthesized through a one-pot methodology. The compounds have been fully characterized, and seven compounds have been structurally elucidated by single crystal X-ray diffraction. The C14 variant was probed as a potential organometallic IR dye. Large unilamellar vesicles were generated with DOPC and the C14 compound and we observed incorporation of the rhenium complex as observed by FTIR microscopy.

UR - https://www.scopus.com/pages/publications/85100010798

U2 - 10.1039/d0dt03743e

DO - 10.1039/d0dt03743e

M3 - Article

C2 - 33367427

AN - SCOPUS:85100010798

SN - 1477-9226

VL - 50

SP - 1069

EP - 1075

JO - Dalton Transactions

JF - Dalton Transactions

IS - 3

ER -

Lipophilic Re(CO)₃pyca complexes for Mid-IR imaging applications

Abstract

Funding

Access to Document

Other files and links

Fingerprint

Cite this