Lipophilic Re(CO)3pyca complexes for Mid-IR imaging applications

Briana R. Schrage; Baylee R. Frisinger; Sarah J. Schmidtke Sobeck; Christopher J. Ziegler

doi:10.1039/d0dt03743e

Lipophilic Re(CO)₃pyca complexes for Mid-IR imaging applications

Briana R. Schrage, Baylee R. Frisinger, Sarah J. Schmidtke Sobeck, Christopher J. Ziegler

Research output: Contribution to journal › Article › peer-review

2 Scopus citations

Abstract

Several Re(i)pyca conjugates incorporating long aliphatic amines have been synthesized through a one-pot methodology. The compounds have been fully characterized, and seven compounds have been structurally elucidated by single crystal X-ray diffraction. The C14 variant was probed as a potential organometallic IR dye. Large unilamellar vesicles were generated with DOPC and the C14 compound and we observed incorporation of the rhenium complex as observed by FTIR microscopy.

Original language	English
Pages (from-to)	1069-1075
Number of pages	7
Journal	Dalton Transactions
Volume	50
Issue number	3
DOIs	https://doi.org/10.1039/d0dt03743e
State	Published - Jan 21 2021
Externally published	Yes

Funding

CJZ acknowledges the National Institutes of Health (1R15GM119030) for support of this research.

Funders	Funder number
National Institutes of Health
National Institute of General Medical Sciences	R15GM119030

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abstract = "Several Re(i)pyca conjugates incorporating long aliphatic amines have been synthesized through a one-pot methodology. The compounds have been fully characterized, and seven compounds have been structurally elucidated by single crystal X-ray diffraction. The C14 variant was probed as a potential organometallic IR dye. Large unilamellar vesicles were generated with DOPC and the C14 compound and we observed incorporation of the rhenium complex as observed by FTIR microscopy.",

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AU - Ziegler, Christopher J.

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AB - Several Re(i)pyca conjugates incorporating long aliphatic amines have been synthesized through a one-pot methodology. The compounds have been fully characterized, and seven compounds have been structurally elucidated by single crystal X-ray diffraction. The C14 variant was probed as a potential organometallic IR dye. Large unilamellar vesicles were generated with DOPC and the C14 compound and we observed incorporation of the rhenium complex as observed by FTIR microscopy.

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Lipophilic Re(CO)₃pyca complexes for Mid-IR imaging applications

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