Knoevenagel condensation reactions catalysed by metal-organic frameworks

Andrew R. Burgoyne; Reinout Meijboom

doi:10.1007/s10562-013-0995-5

Knoevenagel condensation reactions catalysed by metal-organic frameworks

Andrew R. Burgoyne, Reinout Meijboom

Research output: Contribution to journal › Article › peer-review

65 Scopus citations

Abstract

Functionalised metal-organic frameworks (MOFs) which contain amino groups on their secondary building units (SBUs) are basic catalysts in the Knoevenagel condensation. University of Michigan Crystalline Material-1-amine (UMCM-1-NH₂), Isoreticular MOF-3 (IRMOF-3) and a 5 % IRMOF-3 mixed in Isoreticular MOF-1 (MIXMOF) were evaluated as solid basic catalysts and demonstrated to be more active than aniline, their homogenous anologue. UMCM-1-NH₂'s performance was higher than that of the other MOFs studied. IRMOF-3 and MIXMOF proved to have equal catalytic ability. Their catalytic performance was monitored at various temperatures and in different solvents for the reaction between benzaldehyde and ethyl acetoacetate or ethyl cyanoacetate.

Original language	English
Pages (from-to)	563-571
Number of pages	9
Journal	Catalysis Letters
Volume	143
Issue number	6
DOIs	https://doi.org/10.1007/s10562-013-0995-5
State	Published - Jun 2013
Externally published	Yes

Keywords

C-C coupling
Catalysis activity
Elementary kinetics
Heterogeneous catalysis
Organic chemicals and reactions

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10.1007/s10562-013-0995-5

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title = "Knoevenagel condensation reactions catalysed by metal-organic frameworks",

abstract = "Functionalised metal-organic frameworks (MOFs) which contain amino groups on their secondary building units (SBUs) are basic catalysts in the Knoevenagel condensation. University of Michigan Crystalline Material-1-amine (UMCM-1-NH2), Isoreticular MOF-3 (IRMOF-3) and a 5 % IRMOF-3 mixed in Isoreticular MOF-1 (MIXMOF) were evaluated as solid basic catalysts and demonstrated to be more active than aniline, their homogenous anologue. UMCM-1-NH2's performance was higher than that of the other MOFs studied. IRMOF-3 and MIXMOF proved to have equal catalytic ability. Their catalytic performance was monitored at various temperatures and in different solvents for the reaction between benzaldehyde and ethyl acetoacetate or ethyl cyanoacetate.",

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T1 - Knoevenagel condensation reactions catalysed by metal-organic frameworks

AU - Burgoyne, Andrew R.

AU - Meijboom, Reinout

PY - 2013/6

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N2 - Functionalised metal-organic frameworks (MOFs) which contain amino groups on their secondary building units (SBUs) are basic catalysts in the Knoevenagel condensation. University of Michigan Crystalline Material-1-amine (UMCM-1-NH2), Isoreticular MOF-3 (IRMOF-3) and a 5 % IRMOF-3 mixed in Isoreticular MOF-1 (MIXMOF) were evaluated as solid basic catalysts and demonstrated to be more active than aniline, their homogenous anologue. UMCM-1-NH2's performance was higher than that of the other MOFs studied. IRMOF-3 and MIXMOF proved to have equal catalytic ability. Their catalytic performance was monitored at various temperatures and in different solvents for the reaction between benzaldehyde and ethyl acetoacetate or ethyl cyanoacetate.

AB - Functionalised metal-organic frameworks (MOFs) which contain amino groups on their secondary building units (SBUs) are basic catalysts in the Knoevenagel condensation. University of Michigan Crystalline Material-1-amine (UMCM-1-NH2), Isoreticular MOF-3 (IRMOF-3) and a 5 % IRMOF-3 mixed in Isoreticular MOF-1 (MIXMOF) were evaluated as solid basic catalysts and demonstrated to be more active than aniline, their homogenous anologue. UMCM-1-NH2's performance was higher than that of the other MOFs studied. IRMOF-3 and MIXMOF proved to have equal catalytic ability. Their catalytic performance was monitored at various temperatures and in different solvents for the reaction between benzaldehyde and ethyl acetoacetate or ethyl cyanoacetate.

KW - C-C coupling

KW - Catalysis activity

KW - Elementary kinetics

KW - Heterogeneous catalysis

KW - Organic chemicals and reactions

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DO - 10.1007/s10562-013-0995-5

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SP - 563

EP - 571

JO - Catalysis Letters

JF - Catalysis Letters

IS - 6

ER -

Knoevenagel condensation reactions catalysed by metal-organic frameworks

Abstract

Keywords

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