Ionic conductivities of lithium phosphorus oxynitride glasses, polycrystals and thin films

B. Wang; J. B. Bates; B. C. Chakoumakos; B. C. Sales; B. S. Kwak; R. A. Zuhr; J. D. Robertson

Ionic conductivities of lithium phosphorus oxynitride glasses, polycrystals and thin films

B. Wang
, J. B. Bates
, B. C. Chakoumakos
, B. C. Sales
, B. S. Kwak
, R. A. Zuhr
, J. D. Robertson

Single Crystal Diffraction

Research output: Contribution to journal › Conference article › peer-review

2 Scopus citations

Abstract

Various lithium phosphorus oxynitrides have been prepared in the form of glasses, polycrystals, and thin films. The structures of these compounds were investigated by X-ray and neutron diffraction, X-ray photoelectron spectroscopy (XPS), and high-performance liquid chromatography (HPLC). The ac impedance measurements indicate a significant improvement of ionic conductivity as the result of incorporation of nitrogen into the structure. In the case of polycrystalline Li_2.88PO_3.73N_0.14 with the γ-Li₃PO₄ structure, the conductivity increased by several orders of magnitude on small addition of nitrogen. The highest conductivities in the bulk glasses and thin films were found to be 3.0×10^-7 and 8.9×10^-7 S·cm^-1 at 25 °C, respectively.

Original language	English
Pages (from-to)	445-456
Number of pages	12
Journal	Materials Research Society Symposium - Proceedings
Volume	369
State	Published - 1995
Event	Proceedings of the 1994 MRS Fall Meeting - Boston, MA, USA Duration: Nov 28 1994 → Nov 30 1994

Cite this

@article{91c830aa029b4ad0936e0dba054a1124,

title = "Ionic conductivities of lithium phosphorus oxynitride glasses, polycrystals and thin films",

abstract = "Various lithium phosphorus oxynitrides have been prepared in the form of glasses, polycrystals, and thin films. The structures of these compounds were investigated by X-ray and neutron diffraction, X-ray photoelectron spectroscopy (XPS), and high-performance liquid chromatography (HPLC). The ac impedance measurements indicate a significant improvement of ionic conductivity as the result of incorporation of nitrogen into the structure. In the case of polycrystalline Li2.88PO3.73N0.14 with the γ-Li3PO4 structure, the conductivity increased by several orders of magnitude on small addition of nitrogen. The highest conductivities in the bulk glasses and thin films were found to be 3.0×10-7 and 8.9×10-7 S·cm-1 at 25 °C, respectively.",

author = "B. Wang and Bates, \{J. B.\} and Chakoumakos, \{B. C.\} and Sales, \{B. C.\} and Kwak, \{B. S.\} and Zuhr, \{R. A.\} and Robertson, \{J. D.\}",

year = "1995",

language = "English",

volume = "369",

pages = "445--456",

journal = "Materials Research Society Symposium - Proceedings",

issn = "0272-9172",

note = "Proceedings of the 1994 MRS Fall Meeting ; Conference date: 28-11-1994 Through 30-11-1994",

}

TY - JOUR

T1 - Ionic conductivities of lithium phosphorus oxynitride glasses, polycrystals and thin films

AU - Wang, B.

AU - Bates, J. B.

AU - Chakoumakos, B. C.

AU - Sales, B. C.

AU - Kwak, B. S.

AU - Zuhr, R. A.

AU - Robertson, J. D.

PY - 1995

Y1 - 1995

N2 - Various lithium phosphorus oxynitrides have been prepared in the form of glasses, polycrystals, and thin films. The structures of these compounds were investigated by X-ray and neutron diffraction, X-ray photoelectron spectroscopy (XPS), and high-performance liquid chromatography (HPLC). The ac impedance measurements indicate a significant improvement of ionic conductivity as the result of incorporation of nitrogen into the structure. In the case of polycrystalline Li2.88PO3.73N0.14 with the γ-Li3PO4 structure, the conductivity increased by several orders of magnitude on small addition of nitrogen. The highest conductivities in the bulk glasses and thin films were found to be 3.0×10-7 and 8.9×10-7 S·cm-1 at 25 °C, respectively.

AB - Various lithium phosphorus oxynitrides have been prepared in the form of glasses, polycrystals, and thin films. The structures of these compounds were investigated by X-ray and neutron diffraction, X-ray photoelectron spectroscopy (XPS), and high-performance liquid chromatography (HPLC). The ac impedance measurements indicate a significant improvement of ionic conductivity as the result of incorporation of nitrogen into the structure. In the case of polycrystalline Li2.88PO3.73N0.14 with the γ-Li3PO4 structure, the conductivity increased by several orders of magnitude on small addition of nitrogen. The highest conductivities in the bulk glasses and thin films were found to be 3.0×10-7 and 8.9×10-7 S·cm-1 at 25 °C, respectively.

UR - https://www.scopus.com/pages/publications/0029216759

M3 - Conference article

AN - SCOPUS:0029216759

SN - 0272-9172

VL - 369

SP - 445

EP - 456

JO - Materials Research Society Symposium - Proceedings

JF - Materials Research Society Symposium - Proceedings

T2 - Proceedings of the 1994 MRS Fall Meeting

Y2 - 28 November 1994 through 30 November 1994

ER -

Ionic conductivities of lithium phosphorus oxynitride glasses, polycrystals and thin films

Abstract

Other files and links

Fingerprint

Cite this