Ion beam synthesis of Au and Cu nanoclusters in MgO

R. L. Zimmerman, D. Ila, E. K. Williams, D. B. Poker, D. K. Hensley, C. Klatt, S. Kalbitzer

Research output: Contribution to journalArticlepeer-review

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Abstract

Implantation of 2 MeV ions of Au or Cu into single crystals of MgO (100) at room temperature results in the spontaneous formation of metallic nanoclusters for implantation fluences above a threshold value. The formation and growth of these clusters may be induced by post implantation bombardment with silicon ions which stop beyond the implantation layer, as well as by thermal annealing. We have compared spontaneous nanocluster formation, ion bombardment induced cluster formation and post thermal annealing. The size and number of nanoclusters were studied by optical absorption spectroscopy and using the Mie and Doyle theories which relate the optical absorption bands to the formation of nanoclusters. The post bombardment of the gold implanted samples was made with 1.2, 2.0 and 5.0 MeV silicon ions. The depth and distribution of the gold and silicon were observed using RBS.

Original languageEnglish
Pages (from-to)1064-1068
Number of pages5
JournalNuclear Instruments and Methods in Physics Research, Section B: Beam Interactions with Materials and Atoms
Volume148
Issue number1-4
DOIs
StatePublished - 1999

Funding

Research supported by the Center for Irradiation of Materials, Alabama A&M University, US Army Research Office Contract No. DAAH04-96-1-0127 and the US Department of Energy, under contract DE-AC05-96OR22464 with Lockheed Martin Energy Research Corp.

FundersFunder number
Alabama A&M University
U.S. Department of EnergyDE-AC05-96OR22464
Army Research OfficeDAAH04-96-1-0127

    Keywords

    • Implantation
    • Nanoclusters
    • Optical materials

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