Abstract
Molybdenum hexafluoride (MoF6) is used as a non-radioactive substitute for uranium to study the hydrolysis of metal hexafluorides. Molybdenum hexafluoride gas and water vapor, from the air, were sequentially layered onto a diamond substrate kept at liquid nitrogen temperature using a custom designed cryogenic cell with a copper cold finger. Reaction progress was monitored by transmission Fourier Transform Infrared Spectroscopy (FTIR) through the layers and diamond substrate over several hours while allowing the substrate to warm. Changes in the modes in the 500-1000 cm−1 region are tracked as the reaction progresses in order to identify intermediate species. Strong absorption features are also observed in the 1000-3000 cm−1 range, suggesting the presence of ionic dissociation intermediates trapped in a disordered H-bonded network of cryogenic hydrofluoric acid. A possible reaction pathway is proposed and the final hydrolysis product is characterized by FTIR, UV-vis, and scanning electron microscopy/energy dispersive X-ray spectroscopy (SEM/EDS).
| Original language | English |
|---|---|
| Pages (from-to) | 2990-2998 |
| Number of pages | 9 |
| Journal | Physical Chemistry Chemical Physics |
| Volume | 25 |
| Issue number | 4 |
| DOIs | |
| State | Published - Dec 22 2022 |
| Externally published | Yes |
Funding
This work was produced by Battelle Savannah River Alliance, LLC under Contract No. 89303321CEM000080 with the US Department of Energy. Publisher acknowledges the US Government license to provide public access under the DOE Public Access Plan ( http://energy.gov/downloads/doe-public-access-plan ). Financial support for this work was provided by the National Nuclear Security Administration under Defense Nuclear Nonproliferation R&D. Assistance from Dr Daniel Morrall at SRNL with TEM and SEM/EDS is gratefully acknowledged. This work was produced by Battelle Savannah River Alliance, LLC under Contract No. 89303321CEM000080 with the US Department of Energy. Publisher acknowledges the US Government license to provide public access under the DOE Public Access Plan (http://energy.gov/downloads/doe-public-access-plan). Financial support for this work was provided by the National Nuclear Security Administration under Defense Nuclear Nonproliferation R&D. Assistance from Dr Daniel Morrall at SRNL with TEM and SEM/EDS is gratefully acknowledged.