Interaction of elemental mercury with selenium surfaces: model experiments for investigations of superheavy elements copernicium and flerovium

N. M. Chiera; N. V. Aksenov; Y. V. Albin; G. A. Bozhikov; V. I. Chepigin; S. N. Dmitriev; R. Dressler; R. Eichler; V. Ya Lebedev; A. Madumarov; O. N. Malyshev; D. Piguet; Y. A. Popov; A. V. Sabelnikov; P. Steinegger; A. I. Svirikhin; A. Türler; G. K. Vostokin; A. Vögele; A. V. Yeremin

doi:10.1007/s10967-016-5018-8

Interaction of elemental mercury with selenium surfaces: model experiments for investigations of superheavy elements copernicium and flerovium

N. M. Chiera
, N. V. Aksenov
, Y. V. Albin
, G. A. Bozhikov
, V. I. Chepigin
, S. N. Dmitriev
, R. Dressler
, R. Eichler
, V. Ya Lebedev
, A. Madumarov
, O. N. Malyshev
, D. Piguet
, Y. A. Popov
, A. V. Sabelnikov
, P. Steinegger
, A. I. Svirikhin
, A. Türler
, G. K. Vostokin
, A. Vögele
, A. V. Yeremin

Medical Isotopes and Development

Research output: Contribution to journal › Article › peer-review

7 Scopus citations

Abstract

The adsorption behavior of ¹⁹⁷Hg and ^183–185Hg on red amorphous selenium (red a-Se) and trigonal selenium (t-Se) was investigated experimentally by off-line and on-line gas chromatographic methods, in preparation of a sensitive chemical separation and characterization of the transactinides copernicium (Cn, Z = 112) and flerovium (Fl, Z = 114). Monte-Carlo simulations of a diffusion controlled deposition were in good agreement with the experimental results, assuming as interaction limits −ΔH_ads ^red a-Se(Hg) > 85 kJ/mol, and −ΔH_ads ^t-Se(Hg) < 60 kJ/mol. Both Se allotropes can be used as stationary surfaces in comparative gas-chromatographic chemical investigations of Cn and Fl.

Original language	English
Pages (from-to)	99-108
Number of pages	10
Journal	Journal of Radioanalytical and Nuclear Chemistry
Volume	311
Issue number	1
DOIs	https://doi.org/10.1007/s10967-016-5018-8
State	Published - Jan 1 2017

Keywords

Adsorption
Isothermal gas chromatography
Mercury
Model experiments for Cn and Fl
Selenium surface
Superheavy elements

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10.1007/s10967-016-5018-8

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Chiera, N. M., Aksenov, N. V., Albin, Y. V., Bozhikov, G. A., Chepigin, V. I., Dmitriev, S. N., Dressler, R., Eichler, R., Lebedev, V. Y., Madumarov, A., Malyshev, O. N., Piguet, D., Popov, Y. A., Sabelnikov, A. V., Steinegger, P., Svirikhin, A. I., Türler, A., Vostokin, G. K., Vögele, A., & Yeremin, A. V. (2017). Interaction of elemental mercury with selenium surfaces: model experiments for investigations of superheavy elements copernicium and flerovium. Journal of Radioanalytical and Nuclear Chemistry, 311(1), 99-108. https://doi.org/10.1007/s10967-016-5018-8

@article{7960b928e5394578be8696ea7c5a000d,

title = "Interaction of elemental mercury with selenium surfaces: model experiments for investigations of superheavy elements copernicium and flerovium",

abstract = "The adsorption behavior of 197Hg and 183–185Hg on red amorphous selenium (red a-Se) and trigonal selenium (t-Se) was investigated experimentally by off-line and on-line gas chromatographic methods, in preparation of a sensitive chemical separation and characterization of the transactinides copernicium (Cn, Z = 112) and flerovium (Fl, Z = 114). Monte-Carlo simulations of a diffusion controlled deposition were in good agreement with the experimental results, assuming as interaction limits −ΔHads red a-Se(Hg) > 85 kJ/mol, and −ΔHads t-Se(Hg) < 60 kJ/mol. Both Se allotropes can be used as stationary surfaces in comparative gas-chromatographic chemical investigations of Cn and Fl.",

keywords = "Adsorption, Isothermal gas chromatography, Mercury, Model experiments for Cn and Fl, Selenium surface, Superheavy elements",

author = "Chiera, \{N. M.\} and Aksenov, \{N. V.\} and Albin, \{Y. V.\} and Bozhikov, \{G. A.\} and Chepigin, \{V. I.\} and Dmitriev, \{S. N.\} and R. Dressler and R. Eichler and Lebedev, \{V. Ya\} and A. Madumarov and Malyshev, \{O. N.\} and D. Piguet and Popov, \{Y. A.\} and Sabelnikov, \{A. V.\} and P. Steinegger and Svirikhin, \{A. I.\} and A. T{\"u}rler and Vostokin, \{G. K.\} and A. V{\"o}gele and Yeremin, \{A. V.\}",

note = "Publisher Copyright: {\textcopyright} 2016, Akad{\'e}miai Kiad{\'o}, Budapest, Hungary.",

year = "2017",

month = jan,

day = "1",

doi = "10.1007/s10967-016-5018-8",

language = "English",

volume = "311",

pages = "99--108",

journal = "Journal of Radioanalytical and Nuclear Chemistry",

issn = "0236-5731",

publisher = "Akad{\'e}miai Kiad{\'o}",

number = "1",

}

Chiera, NM, Aksenov, NV, Albin, YV, Bozhikov, GA, Chepigin, VI, Dmitriev, SN, Dressler, R, Eichler, R, Lebedev, VY, Madumarov, A, Malyshev, ON, Piguet, D, Popov, YA, Sabelnikov, AV, Steinegger, P, Svirikhin, AI, Türler, A, Vostokin, GK, Vögele, A & Yeremin, AV 2017, 'Interaction of elemental mercury with selenium surfaces: model experiments for investigations of superheavy elements copernicium and flerovium', Journal of Radioanalytical and Nuclear Chemistry, vol. 311, no. 1, pp. 99-108. https://doi.org/10.1007/s10967-016-5018-8

TY - JOUR

T1 - Interaction of elemental mercury with selenium surfaces

T2 - model experiments for investigations of superheavy elements copernicium and flerovium

AU - Chiera, N. M.

AU - Aksenov, N. V.

AU - Albin, Y. V.

AU - Bozhikov, G. A.

AU - Chepigin, V. I.

AU - Dmitriev, S. N.

AU - Dressler, R.

AU - Eichler, R.

AU - Lebedev, V. Ya

AU - Madumarov, A.

AU - Malyshev, O. N.

AU - Piguet, D.

AU - Popov, Y. A.

AU - Sabelnikov, A. V.

AU - Steinegger, P.

AU - Svirikhin, A. I.

AU - Türler, A.

AU - Vostokin, G. K.

AU - Vögele, A.

AU - Yeremin, A. V.

PY - 2017/1/1

Y1 - 2017/1/1

N2 - The adsorption behavior of 197Hg and 183–185Hg on red amorphous selenium (red a-Se) and trigonal selenium (t-Se) was investigated experimentally by off-line and on-line gas chromatographic methods, in preparation of a sensitive chemical separation and characterization of the transactinides copernicium (Cn, Z = 112) and flerovium (Fl, Z = 114). Monte-Carlo simulations of a diffusion controlled deposition were in good agreement with the experimental results, assuming as interaction limits −ΔHads red a-Se(Hg) > 85 kJ/mol, and −ΔHads t-Se(Hg) < 60 kJ/mol. Both Se allotropes can be used as stationary surfaces in comparative gas-chromatographic chemical investigations of Cn and Fl.

AB - The adsorption behavior of 197Hg and 183–185Hg on red amorphous selenium (red a-Se) and trigonal selenium (t-Se) was investigated experimentally by off-line and on-line gas chromatographic methods, in preparation of a sensitive chemical separation and characterization of the transactinides copernicium (Cn, Z = 112) and flerovium (Fl, Z = 114). Monte-Carlo simulations of a diffusion controlled deposition were in good agreement with the experimental results, assuming as interaction limits −ΔHads red a-Se(Hg) > 85 kJ/mol, and −ΔHads t-Se(Hg) < 60 kJ/mol. Both Se allotropes can be used as stationary surfaces in comparative gas-chromatographic chemical investigations of Cn and Fl.

KW - Adsorption

KW - Isothermal gas chromatography

KW - Mercury

KW - Model experiments for Cn and Fl

KW - Selenium surface

KW - Superheavy elements

UR - https://www.scopus.com/pages/publications/84984822420

U2 - 10.1007/s10967-016-5018-8

DO - 10.1007/s10967-016-5018-8

M3 - Article

AN - SCOPUS:84984822420

SN - 0236-5731

VL - 311

SP - 99

EP - 108

JO - Journal of Radioanalytical and Nuclear Chemistry

JF - Journal of Radioanalytical and Nuclear Chemistry

IS - 1

ER -

Interaction of elemental mercury with selenium surfaces: model experiments for investigations of superheavy elements copernicium and flerovium

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Keywords

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