Initial growth stages of epitaxial BaTiO3 films on vicinal SrTiO3:Nb (001) substrates

A. Visinoiu, M. Alexe, H. N. Lee, D. N. Zakharov, A. Pignolet, D. Hesse, U. Gösele

Research output: Contribution to journalArticlepeer-review

Abstract

The growth mechanism of epitaxial BaTiO3 films on vicinal Nb-doped SrTiO3 (SrTiO3:Nb) (001) substrate surfaces was studied in terms of surface morphology, crystalline orientation, microstructure, and film/substrate interface. Well-oriented BaTiO3 thin films were grown on SrTiO3 substrates with well-defined terraces by pulsed laser deposition. The regularly terraced TiO2-terminated surfaces of vicinal SrTiO3:Nb (001) substrates were prepared by a definite chemical and thermal treatment. Under our conditions, BaTiO3 seems to grow with a layer-then-island (Stranski-Krastanov) growth mechanism. In order to investigate the orientation and crystallinity of the BaTiO3 films, x-ray diffraction and high-resolution transmission electron microscopy were performed. Ferroelectricity of the BaTiO3 films was proved by electrical measurements performed on Pt/BaTiO3/SrTiO3:Nb heterostructures.

Original languageEnglish
Pages (from-to)285-290
Number of pages6
JournalMaterials Research Society Symposium - Proceedings
Volume688
StatePublished - 2002
Externally publishedYes

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