Infrared spectra of the O3- -HF and SO2- -HF complexes in solid argon

Lester Andrews; Robert Withnall; Rodney D. Hunt

doi:10.1021/j100312a019

Infrared spectra of the O₃- -HF and SO₂- -HF complexes in solid argon

Lester Andrews, Robert Withnall, Rodney D. Hunt

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Abstract

Argon matrix spectra of the O₃- -HF and SO₂- -HF complexes are similar, and the structure deduced for O₃- -HF from the infrared spectrum is similar to the microwave structure for SO₂- -HF. All three ozone submolecule fundamentals were observed for the complex, and v₁^c was considerably enhanced in intensity relative to v₃^c. The asymmetric mixed isotopic ozone complexes exhibited split v₁^c bands which indicate inequivalent terminal oxygen atoms and attachment of HF at this position in the complex.

Original language	English
Pages (from-to)	78-81
Number of pages	4
Journal	Journal of Physical Chemistry
Volume	92
Issue number	1
DOIs	https://doi.org/10.1021/j100312a019
State	Published - 1988
Externally published	Yes

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title = "Infrared spectra of the O3- -HF and SO2- -HF complexes in solid argon",

abstract = "Argon matrix spectra of the O3- -HF and SO2- -HF complexes are similar, and the structure deduced for O3- -HF from the infrared spectrum is similar to the microwave structure for SO2- -HF. All three ozone submolecule fundamentals were observed for the complex, and v1c was considerably enhanced in intensity relative to v3c. The asymmetric mixed isotopic ozone complexes exhibited split v1c bands which indicate inequivalent terminal oxygen atoms and attachment of HF at this position in the complex.",

author = "Lester Andrews and Robert Withnall and Hunt, {Rodney D.}",

year = "1988",

doi = "10.1021/j100312a019",

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journal = "Journal of Physical Chemistry",

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T1 - Infrared spectra of the O3- -HF and SO2- -HF complexes in solid argon

AU - Andrews, Lester

AU - Withnall, Robert

AU - Hunt, Rodney D.

PY - 1988

Y1 - 1988

N2 - Argon matrix spectra of the O3- -HF and SO2- -HF complexes are similar, and the structure deduced for O3- -HF from the infrared spectrum is similar to the microwave structure for SO2- -HF. All three ozone submolecule fundamentals were observed for the complex, and v1c was considerably enhanced in intensity relative to v3c. The asymmetric mixed isotopic ozone complexes exhibited split v1c bands which indicate inequivalent terminal oxygen atoms and attachment of HF at this position in the complex.

AB - Argon matrix spectra of the O3- -HF and SO2- -HF complexes are similar, and the structure deduced for O3- -HF from the infrared spectrum is similar to the microwave structure for SO2- -HF. All three ozone submolecule fundamentals were observed for the complex, and v1c was considerably enhanced in intensity relative to v3c. The asymmetric mixed isotopic ozone complexes exhibited split v1c bands which indicate inequivalent terminal oxygen atoms and attachment of HF at this position in the complex.

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U2 - 10.1021/j100312a019

DO - 10.1021/j100312a019

M3 - Article

AN - SCOPUS:0002371397

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VL - 92

SP - 78

EP - 81

JO - Journal of Physical Chemistry

JF - Journal of Physical Chemistry

IS - 1

ER -

Infrared spectra of the O₃- -HF and SO₂- -HF complexes in solid argon

Abstract

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