Infrared spectra of ClF, Cl2, and Cl complexes with HCl in solid argon

Lester Andrews; Rodney D. Hunt

doi:10.1063/1.454921

Infrared spectra of ClF, Cl₂, and Cl complexes with HCl in solid argon

Lester Andrews, Rodney D. Hunt

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Abstract

Argon mixtures of ClF, Cl₂, and Cl atoms have been codeposited with Ar/HCl at 5 and 12 K. Infrared spectra in the HCl stretching region give evidence for the FCl-HCl, Cl2-HCl, and Cl-HCl hydrogen-bonded complexes. The molecular complexes are more stable in the hydrogen-bonded than antihydrogren-bonded forms as no evidence for the latter were observed. The Cl-HCl radical hydrogen-bonded complex is considerably different from the centrosymmetric (Cl-H-Cl)^- anion.

Original language	English
Pages (from-to)	3502-3504
Number of pages	3
Journal	Journal of Chemical Physics
Volume	89
Issue number	6
DOIs	https://doi.org/10.1063/1.454921
State	Published - 1988
Externally published	Yes

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title = "Infrared spectra of ClF, Cl2, and Cl complexes with HCl in solid argon",

abstract = "Argon mixtures of ClF, Cl2, and Cl atoms have been codeposited with Ar/HCl at 5 and 12 K. Infrared spectra in the HCl stretching region give evidence for the FCl-HCl, Cl2-HCl, and Cl-HCl hydrogen-bonded complexes. The molecular complexes are more stable in the hydrogen-bonded than antihydrogren-bonded forms as no evidence for the latter were observed. The Cl-HCl radical hydrogen-bonded complex is considerably different from the centrosymmetric (Cl-H-Cl)- anion.",

author = "Lester Andrews and Hunt, {Rodney D.}",

year = "1988",

doi = "10.1063/1.454921",

language = "English",

volume = "89",

pages = "3502--3504",

journal = "Journal of Chemical Physics",

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publisher = "American Institute of Physics",

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T1 - Infrared spectra of ClF, Cl2, and Cl complexes with HCl in solid argon

AU - Andrews, Lester

AU - Hunt, Rodney D.

PY - 1988

Y1 - 1988

N2 - Argon mixtures of ClF, Cl2, and Cl atoms have been codeposited with Ar/HCl at 5 and 12 K. Infrared spectra in the HCl stretching region give evidence for the FCl-HCl, Cl2-HCl, and Cl-HCl hydrogen-bonded complexes. The molecular complexes are more stable in the hydrogen-bonded than antihydrogren-bonded forms as no evidence for the latter were observed. The Cl-HCl radical hydrogen-bonded complex is considerably different from the centrosymmetric (Cl-H-Cl)- anion.

AB - Argon mixtures of ClF, Cl2, and Cl atoms have been codeposited with Ar/HCl at 5 and 12 K. Infrared spectra in the HCl stretching region give evidence for the FCl-HCl, Cl2-HCl, and Cl-HCl hydrogen-bonded complexes. The molecular complexes are more stable in the hydrogen-bonded than antihydrogren-bonded forms as no evidence for the latter were observed. The Cl-HCl radical hydrogen-bonded complex is considerably different from the centrosymmetric (Cl-H-Cl)- anion.

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U2 - 10.1063/1.454921

DO - 10.1063/1.454921

M3 - Article

AN - SCOPUS:0006931150

SN - 0021-9606

VL - 89

SP - 3502

EP - 3504

JO - Journal of Chemical Physics

JF - Journal of Chemical Physics

IS - 6

ER -

Infrared spectra of ClF, Cl₂, and Cl complexes with HCl in solid argon

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