Inelastic neutron scattering study of the specific features of the phase transitions in (NH4)2WO2F4

L. S. Smirnov, A. I. Kolesnikov, I. N. Flerov, N. M. Laptash

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    Abstract

    Oxyfluoride (NH4)2WO2F4 has been studied by the inelastic neutron scattering method over a wide temperature range 10-300 K at two initial neutron energies of 15 and 60 meV. The role of tetrahedral ammonium groups in the mechanism of sequential phase transitions at T1 = 201 K and T2 = 160 K has been discussed.

    Original languageEnglish
    Pages (from-to)2362-2366
    Number of pages5
    JournalPhysics of the Solid State
    Volume51
    Issue number11
    DOIs
    StatePublished - Nov 2009

    Funding

    ACKNOWLEDGMENTS This study was supported by the Russian Founda tion for Basic Research (project no. 09 02 00062) and the ORNL/SNS controlled by UT Battelle, LLC, the U.S. Department of Energy (contract DE AC05 00OR22725); the experiments in the Argonne National Laboratory were supported by the Office of General Sciences on Energy, Division of Materials Science of the U.S. Department of Energy (contract DE AC02 06CH11357).

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