Indium-doped gallophosphate NH4[NiGa1.84In 0.16(PO4)3(H2O)2]: Synthesis, X-ray crystal structure and IR spectroscopy

Francesco Capitelli; Annalisa Masi; Brahim El Bali; Rachid Essehli

doi:10.1524/zkri.2010.1254

Indium-doped gallophosphate NH₄[NiGa_1.84In _0.16(PO₄)₃(H₂O)₂]: Synthesis, X-ray crystal structure and IR spectroscopy

Francesco Capitelli
, Annalisa Masi
, Brahim El Bali
, Rachid Essehli

Research output: Contribution to journal › Article › peer-review

4 Scopus citations

Abstract

NH₄[NiGa_1.84In_0.16(PO₄) ₃(H₂O)₂] orthophosphate was prepared through hydrothermal synthesis and analyzed by means of single crystal X-ray diffractometry. It was solved within C2/c monoclinic space group; a = 13.2483(8)Å, b = 10.2468(8)Å, c = 8.9033(7)Å, bβ = 108.637(1)°, V = 1145.27(15)Å3. Phosphorous atoms display tetrahedral arrangement, occupying two distinct sites; Ni atoms form NiO4(OH ₂)₂ distorted octahedra, while Ga and In atoms share the same site forming (Ga,In)O₅ units with trigonal bipyramidal geometry. (Ga,In)O₅, NiO₄(OH₂)₂ and PO ₄ units are linked together through edge- and vertex-sharing arrangements, making up the three-dimensional framework, completed by (NH ₄)⁺ counter-ions. Strong O-H⋯O and N-H⋯O hydrogen bonds contribute to stabilize the array: O-H⋯O interactions were also investigated by means of Libowitzky formula (Libowitzky, 1999) application, owing to the results of IR spectroscopy.

Original language	English
Pages (from-to)	359-365
Number of pages	7
Journal	Zeitschrift fur Kristallographie
Volume	225
Issue number	9
DOIs	https://doi.org/10.1524/zkri.2010.1254
State	Published - Sep 2010
Externally published	Yes

Keywords

Gallophosphates
Hydrogen bond
Hydrothermal synthesis
IR spectroscopy
Single-crystal structure analysis
X-ray diffraction

Access to Document

10.1524/zkri.2010.1254

Cite this

@article{f03b6be2a3b043b8bad32cae21cd281c,

title = "Indium-doped gallophosphate NH4[NiGa1.84In 0.16(PO4)3(H2O)2]: Synthesis, X-ray crystal structure and IR spectroscopy",

abstract = "NH4[NiGa1.84In0.16(PO4) 3(H2O)2] orthophosphate was prepared through hydrothermal synthesis and analyzed by means of single crystal X-ray diffractometry. It was solved within C2/c monoclinic space group; a = 13.2483(8){\AA}, b = 10.2468(8){\AA}, c = 8.9033(7){\AA}, bβ = 108.637(1)°, V = 1145.27(15){\AA}3. Phosphorous atoms display tetrahedral arrangement, occupying two distinct sites; Ni atoms form NiO4(OH 2)2 distorted octahedra, while Ga and In atoms share the same site forming (Ga,In)O5 units with trigonal bipyramidal geometry. (Ga,In)O5, NiO4(OH2)2 and PO 4 units are linked together through edge- and vertex-sharing arrangements, making up the three-dimensional framework, completed by (NH 4)+ counter-ions. Strong O-H⋯O and N-H⋯O hydrogen bonds contribute to stabilize the array: O-H⋯O interactions were also investigated by means of Libowitzky formula (Libowitzky, 1999) application, owing to the results of IR spectroscopy.",

keywords = "Gallophosphates, Hydrogen bond, Hydrothermal synthesis, IR spectroscopy, Single-crystal structure analysis, X-ray diffraction",

author = "Francesco Capitelli and Annalisa Masi and Bali, \{Brahim El\} and Rachid Essehli",

year = "2010",

month = sep,

doi = "10.1524/zkri.2010.1254",

language = "English",

volume = "225",

pages = "359--365",

journal = "Zeitschrift fur Kristallographie",

issn = "0044-2968",

publisher = "De Gruyter",

number = "9",

}

TY - JOUR

T1 - Indium-doped gallophosphate NH4[NiGa1.84In 0.16(PO4)3(H2O)2]

T2 - Synthesis, X-ray crystal structure and IR spectroscopy

AU - Capitelli, Francesco

AU - Masi, Annalisa

AU - Bali, Brahim El

AU - Essehli, Rachid

PY - 2010/9

Y1 - 2010/9

N2 - NH4[NiGa1.84In0.16(PO4) 3(H2O)2] orthophosphate was prepared through hydrothermal synthesis and analyzed by means of single crystal X-ray diffractometry. It was solved within C2/c monoclinic space group; a = 13.2483(8)Å, b = 10.2468(8)Å, c = 8.9033(7)Å, bβ = 108.637(1)°, V = 1145.27(15)Å3. Phosphorous atoms display tetrahedral arrangement, occupying two distinct sites; Ni atoms form NiO4(OH 2)2 distorted octahedra, while Ga and In atoms share the same site forming (Ga,In)O5 units with trigonal bipyramidal geometry. (Ga,In)O5, NiO4(OH2)2 and PO 4 units are linked together through edge- and vertex-sharing arrangements, making up the three-dimensional framework, completed by (NH 4)+ counter-ions. Strong O-H⋯O and N-H⋯O hydrogen bonds contribute to stabilize the array: O-H⋯O interactions were also investigated by means of Libowitzky formula (Libowitzky, 1999) application, owing to the results of IR spectroscopy.

AB - NH4[NiGa1.84In0.16(PO4) 3(H2O)2] orthophosphate was prepared through hydrothermal synthesis and analyzed by means of single crystal X-ray diffractometry. It was solved within C2/c monoclinic space group; a = 13.2483(8)Å, b = 10.2468(8)Å, c = 8.9033(7)Å, bβ = 108.637(1)°, V = 1145.27(15)Å3. Phosphorous atoms display tetrahedral arrangement, occupying two distinct sites; Ni atoms form NiO4(OH 2)2 distorted octahedra, while Ga and In atoms share the same site forming (Ga,In)O5 units with trigonal bipyramidal geometry. (Ga,In)O5, NiO4(OH2)2 and PO 4 units are linked together through edge- and vertex-sharing arrangements, making up the three-dimensional framework, completed by (NH 4)+ counter-ions. Strong O-H⋯O and N-H⋯O hydrogen bonds contribute to stabilize the array: O-H⋯O interactions were also investigated by means of Libowitzky formula (Libowitzky, 1999) application, owing to the results of IR spectroscopy.

KW - Gallophosphates

KW - Hydrogen bond

KW - Hydrothermal synthesis

KW - IR spectroscopy

KW - Single-crystal structure analysis

KW - X-ray diffraction

UR - https://www.scopus.com/pages/publications/79951668343

U2 - 10.1524/zkri.2010.1254

DO - 10.1524/zkri.2010.1254

M3 - Article

AN - SCOPUS:79951668343

SN - 0044-2968

VL - 225

SP - 359

EP - 365

JO - Zeitschrift fur Kristallographie

JF - Zeitschrift fur Kristallographie

IS - 9

ER -

Indium-doped gallophosphate NH₄[NiGa_1.84In _0.16(PO₄)₃(H₂O)₂]: Synthesis, X-ray crystal structure and IR spectroscopy

Abstract

Keywords

Access to Document

Other files and links

Fingerprint

Cite this