Abstract
The class of AV3Sb5 (A=K, Rb, Cs) kagome metals hosts unconventional charge density wave states seemingly intertwined with their low temperature superconducting phases. The nature of the coupling between these two states and the potential presence of nearby, competing charge instabilities however remain open questions. This phenomenology is strikingly highlighted by the formation of two ‘domes’ in the superconducting transition temperature upon hole-doping CsV3Sb5. Here we track the evolution of charge correlations upon the suppression of long-range charge density wave order in the first dome and into the second of the hole-doped kagome superconductor CsV3Sb5−xSnx. Initially, hole-doping drives interlayer charge correlations to become short-ranged with their periodicity diminished along the interlayer direction. Beyond the peak of the first superconducting dome, the parent charge density wave state vanishes and incommensurate, quasi-1D charge correlations are stabilized in its place. These competing, unidirectional charge correlations demonstrate an inherent electronic rotational symmetry breaking in CsV3Sb5, and reveal a complex landscape of charge correlations within its electronic phase diagram. Our data suggest an inherent 2kf charge instability and competing charge orders in the AV3Sb5 class of kagome superconductors.
Original language | English |
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Article number | 37 |
Journal | npj Quantum Materials |
Volume | 8 |
Issue number | 1 |
DOIs | |
State | Published - Dec 2023 |
Externally published | Yes |
Funding
This work was supported by the National Science Foundation (NSF) through Enabling Quantum Leap: Convergent Accelerated Discovery Foundries for Quantum Materials Science, Engineering and Information (Q-AMASE-i): Quantum Foundry at UC Santa Barbara (DMR-1906325). I.Z. gratefully acknowledges the support from the National Science Foundation grant NSF-DMR 2216080. Z.W. is supported by U.S. Department of Energy, Basic Energy Sciences Grant No. DE-FG02-99ER45747 and the Cottrell SEED Award No. 27856 from Research Corporation for Science Advancement. The research reported here made use of shared facilities of the NSF Materials Research Science and Engineering Center at UC Santa Barbara DMR-1720256, a member of the Materials Research Facilities Network ( www.mrfn.org ). This work is based upon research conducted at the Center for High Energy X-ray Sciences (CHEXS) which is supported by the National Science Foundation under award DMR-1829070. Any opinions, findings, and conclusions or recommendations expressed in this material are those of the authors and do not necessarily reflect the views of the National Science Foundation. This work was supported by the National Science Foundation (NSF) through Enabling Quantum Leap: Convergent Accelerated Discovery Foundries for Quantum Materials Science, Engineering and Information (Q-AMASE-i): Quantum Foundry at UC Santa Barbara (DMR-1906325). I.Z. gratefully acknowledges the support from the National Science Foundation grant NSF-DMR 2216080. Z.W. is supported by U.S. Department of Energy, Basic Energy Sciences Grant No. DE-FG02-99ER45747 and the Cottrell SEED Award No. 27856 from Research Corporation for Science Advancement. The research reported here made use of shared facilities of the NSF Materials Research Science and Engineering Center at UC Santa Barbara DMR-1720256, a member of the Materials Research Facilities Network (www.mrfn.org). This work is based upon research conducted at the Center for High Energy X-ray Sciences (CHEXS) which is supported by the National Science Foundation under award DMR-1829070. Any opinions, findings, and conclusions or recommendations expressed in this material are those of the authors and do not necessarily reflect the views of the National Science Foundation.
Funders | Funder number |
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Materials Science, Engineering and Information | |
NSF Materials Research Science and Engineering Center at UC Santa Barbara | DMR-1720256 |
National Science Foundation | |
U.S. Department of Energy | |
Research Corporation for Science Advancement | DMR-1829070 |
Basic Energy Sciences | 27856, DE-FG02-99ER45747 |
University of California, Santa Barbara | NSF-DMR 2216080, DMR-1906325 |