Improved electrical, mechanical and EMI shielding properties of PANI-VGCF-DBSA/DVB hybrid nanocomposite

Vipin Kumar, Tomohiro Yokozeki, Teruya Goto, Tatsuhiro Takahashi, Sanjay R. Dhakate, Bhanu Pratap Singh

Research output: Chapter in Book/Report/Conference proceedingConference contributionpeer-review

Abstract

A Polyaniline (PANI) based electrically conductive thermosetting hybrid nano-composite has been prepared by incorporating high apparent-density type vapor grown carbon fibers (VGCF-H) as additional conductive filler. The main conducting component of the matrix is PANI, protonated with a protonic acid, dodecylbenzenesulfonic acid (DBSA). Divinylbenzene (DVB) is used as a cross-linked thermosetting polymer. With addition of VGCF-H higher electrical conductivity and better mechanical properties have been achieved. Different weight percentages of VGCF-H in the PANI-DBSA/DVB matrix, were used and their effect on composite's properties have been investigated. Electrical conductivity up to 1.97 S/cm with the addition of 5 wt. % VGCF-H and flexural modulus of 1.71 GPa with 3 wt. % of VGCF-H have been achieved. Electromagnetic interference (EMI) shielding properties of composite with and without VGCF-H are measured in X-band frequencies and compared. Composite with 5 wt. % VGCF-H has shown EMI shielding effectiveness about 51 dB in X-band, which is higher than the composite without VGCF-H (around 22 dB). The morphologies of the composites were studied by SEM analysis. The effect of dispersion on electrical and mechanical properties also has been explained using SEM micrographs. The results of these studies confirmed that a polymer thermoset conductive composite with improved electrical, mechanical and EMI shielding effectiveness has been successfully prepared.

Original languageEnglish
Title of host publicationECCM 2016 - Proceeding of the 17th European Conference on Composite Materials
PublisherEuropean Conference on Composite Materials, ECCM
ISBN (Electronic)9783000533877
StatePublished - 2016
Externally publishedYes
Event17th European Conference on Composite Materials, ECCM 2016 - Munich, Germany
Duration: Jun 26 2016Jun 30 2016

Publication series

NameECCM 2016 - Proceeding of the 17th European Conference on Composite Materials

Conference

Conference17th European Conference on Composite Materials, ECCM 2016
Country/TerritoryGermany
CityMunich
Period06/26/1606/30/16

Funding

This study was partially supported by JSPS and DST under the Japan-India Science Cooperative Program. Authors would like to thank Dr. S. K. Dhawan from CSIR-NPL, New Delhi for great discussion and guidance. Authors also wish to thank Mr. Takahashi Yuuki and Mr. Suganuma Yuuki for their kind help in conducting experiments during stay in Yamagata University.

FundersFunder number
Department of Science and Technology, Ministry of Science and Technology, India
Japan Society for the Promotion of Science
National Physical Laboratory

    Keywords

    • Electrical conductivity
    • Polyaniline
    • Thermoset
    • VGCF

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