Hydrodeoxygenation (HDO) of Biomass Derived Ketones Using Supported Transition Metals in a Continuous Reactor

Xiaokun Yang; Rhodri W. Jenkins; Juan H. Leal; Cameron M. Moore; Elizabeth J. Judge; Troy A. Semelsberger; Andrew D. Sutton

doi:10.1021/acssuschemeng.9b02041

Hydrodeoxygenation (HDO) of Biomass Derived Ketones Using Supported Transition Metals in a Continuous Reactor

Xiaokun Yang, Rhodri W. Jenkins, Juan H. Leal, Cameron M. Moore, Elizabeth J. Judge, Troy A. Semelsberger, Andrew D. Sutton

Chemical Process Scale Up

Research output: Contribution to journal › Article › peer-review

17 Scopus citations

Abstract

The hydrodeoxygenation (HDO) of 5-nonanone - a model compound for more complex biomass-derived molecules - to n-nonane was investigated using a variety of heterogeneous multifunctional metal-impregnated aluminosilicate catalysts in a packed-bed continuous flow reactor system. Under optimized reaction conditions (200 °C, 1.38 MPa H₂), >99% conversion and >99% selectivity to n-nonane was achieved within a 30 min residence time over both Ni (7 wt %) and Co (9 wt %) supported on Perlkat 79-3, a high-surface area amorphous aluminosilicate. This work provides a further understanding of the effects of different metals, supports, and metal loading amounts on HDO of 5-nonanone and demonstrates an efficient translation of HDO reactions of ketones from batch reactors to continuous flow systems.

Original language	English
Pages (from-to)	14521-14530
Number of pages	10
Journal	ACS Sustainable Chemistry and Engineering
Volume	7
Issue number	17
DOIs	https://doi.org/10.1021/acssuschemeng.9b02041
State	Published - Sep 3 2019

Funding

This work was funded by the U.S. Department of Energy’s Office of Energy Efficiency & Renewable Energy (EERE). The specific organization overseeing this report is the Bioenergy Technology Office (BETO) through ChemCatBio: Chemical Catalysis for Bioenergy Consortium. Los Alamos National Laboratory is operated by Triad National Security, LLC, for the National Nuclear Security Administration of the U.S. Department of Energy under contract No. 89233218CNA000001.

Funders	Funder number
U.S. Department of Energy
Office of Energy Efficiency and Renewable Energy
National Nuclear Security Administration	89233218CNA000001

Keywords

Bifunctional catalysts
Bioderived ketone
Continuous reactor
Heterogeneous catalysts
Hydrodeoxygenation (HDO)

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10.1021/acssuschemeng.9b02041

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title = "Hydrodeoxygenation (HDO) of Biomass Derived Ketones Using Supported Transition Metals in a Continuous Reactor",

abstract = "The hydrodeoxygenation (HDO) of 5-nonanone - a model compound for more complex biomass-derived molecules - to n-nonane was investigated using a variety of heterogeneous multifunctional metal-impregnated aluminosilicate catalysts in a packed-bed continuous flow reactor system. Under optimized reaction conditions (200 °C, 1.38 MPa H2), >99% conversion and >99% selectivity to n-nonane was achieved within a 30 min residence time over both Ni (7 wt %) and Co (9 wt %) supported on Perlkat 79-3, a high-surface area amorphous aluminosilicate. This work provides a further understanding of the effects of different metals, supports, and metal loading amounts on HDO of 5-nonanone and demonstrates an efficient translation of HDO reactions of ketones from batch reactors to continuous flow systems.",

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AU - Yang, Xiaokun

AU - Jenkins, Rhodri W.

AU - Leal, Juan H.

AU - Moore, Cameron M.

AU - Judge, Elizabeth J.

AU - Semelsberger, Troy A.

AU - Sutton, Andrew D.

PY - 2019/9/3

Y1 - 2019/9/3

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AB - The hydrodeoxygenation (HDO) of 5-nonanone - a model compound for more complex biomass-derived molecules - to n-nonane was investigated using a variety of heterogeneous multifunctional metal-impregnated aluminosilicate catalysts in a packed-bed continuous flow reactor system. Under optimized reaction conditions (200 °C, 1.38 MPa H2), >99% conversion and >99% selectivity to n-nonane was achieved within a 30 min residence time over both Ni (7 wt %) and Co (9 wt %) supported on Perlkat 79-3, a high-surface area amorphous aluminosilicate. This work provides a further understanding of the effects of different metals, supports, and metal loading amounts on HDO of 5-nonanone and demonstrates an efficient translation of HDO reactions of ketones from batch reactors to continuous flow systems.

KW - Bifunctional catalysts

KW - Bioderived ketone

KW - Continuous reactor

KW - Heterogeneous catalysts

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ER -

Hydrodeoxygenation (HDO) of Biomass Derived Ketones Using Supported Transition Metals in a Continuous Reactor

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