Hydriding of titanium: Recent trends and perspectives in advanced characterization and multiscale modeling

Yakun Zhu; Tae Wook Heo; Jennifer N. Rodriguez; Peter K. Weber; Rongpei Shi; Bruce J. Baer; Felipe F. Morgado; Stoichko Antonov; Kyoung E. Kweon; Erik B. Watkins; Daniel J. Savage; James E. Chapman; Nathan D. Keilbart; Younggil Song; Qi Zhen; Baptiste Gault; Sven C. Vogel; Shohini T. Sen-Britain; Matthew G. Shalloo; Chris Orme; Michael Bagge-Hansen; Christopher Hahn; Tuan A. Pham; Digby D. Macdonald; S. Roger Qiu; Brandon C. Wood

doi:10.1016/j.cossms.2022.101020

Hydriding of titanium: Recent trends and perspectives in advanced characterization and multiscale modeling

Yakun Zhu
, Tae Wook Heo
, Jennifer N. Rodriguez
, Peter K. Weber
, Rongpei Shi
, Bruce J. Baer
, Felipe F. Morgado
, Stoichko Antonov
, Kyoung E. Kweon
, Erik B. Watkins
, Daniel J. Savage
, James E. Chapman
, Nathan D. Keilbart
, Younggil Song
, Qi Zhen
, Baptiste Gault
, Sven C. Vogel
, Shohini T. Sen-Britain
, Matthew G. Shalloo
, Chris Orme

Michael Bagge-Hansen, Christopher Hahn, Tuan A. Pham, Digby D. Macdonald, S. Roger Qiu, Brandon C. Wood

Research output: Contribution to journal › Review article › peer-review

48 Scopus citations

Abstract

Titanium (Ti) and its alloys are attractive for a wide variety of structural and functional applications owing to excellent specific strength, toughness and stiffness, and corrosion resistance. However, if exposed to hydrogen sources, these alloys are susceptible to hydride formation in the form of TiH_x (0 < x ≤ 2), leading to crack initiation and mechanical failure due to lattice deformation and stress accumulation. The kinetics of the hydriding process depends on several factors, including the critical saturation threshold for hydrogen within Ti, the specific interaction of hydrogen with protective surface oxide, the rates of mass transport, and the kinetics of nucleation and phase transformation. Unfortunately, key knowledge gaps and challenges remain regarding the details of these coupled processes, which take place across vast ranges of time and length scales and are often difficult to probe directly. This work reviews recent advances in multiscale characterization and modeling efforts in Ti hydriding. We identify unanswered questions and key challenges, propose new perspectives on how to solve these remaining issues, and close knowledge gaps by discussing and demonstrating specific opportunities for integrating advanced characterization and multiscale modeling to elucidate chemistry and composition, microstructure phenomena, and macroscale performance and testing.

Original language	English
Article number	101020
Journal	Current Opinion in Solid State and Materials Science
Volume	26
Issue number	6
DOIs	https://doi.org/10.1016/j.cossms.2022.101020
State	Published - Dec 2022
Externally published	Yes

Funding

This work was performed under the auspices of the U.S. Department of Energy by Lawrence Livermore National Laboratory under Contract DE-AC52-07NA27344. This work was funded by the Laboratory Directed Research and Development (LDRD) program (20-SI-04) at Lawrence Livermore National Laboratory. BCW and TWH acknowledge additional funding from the Hydrogen Materials—Advanced Research Consortium, provided by the U.S. Department of Energy Hydrogen and Fuel Cell Technologies Office, Office of Energy Efficiency and Renewable Energy, under Contract DE-AC52-07NA27344.

Access to Document

10.1016/j.cossms.2022.101020

Cite this

Zhu, Y., Wook Heo, T., Rodriguez, J. N., Weber, P. K., Shi, R., Baer, B. J., Morgado, F. F., Antonov, S., Kweon, K. E., Watkins, E. B., Savage, D. J., Chapman, J. E., Keilbart, N. D., Song, Y., Zhen, Q., Gault, B., Vogel, S. C., Sen-Britain, S. T., Shalloo, M. G., ... Wood, B. C. (2022). Hydriding of titanium: Recent trends and perspectives in advanced characterization and multiscale modeling. Current Opinion in Solid State and Materials Science, 26(6), Article 101020. https://doi.org/10.1016/j.cossms.2022.101020

@article{a0f6dd84bd084ceda24f62d31bb5ee03,

title = "Hydriding of titanium: Recent trends and perspectives in advanced characterization and multiscale modeling",

abstract = "Titanium (Ti) and its alloys are attractive for a wide variety of structural and functional applications owing to excellent specific strength, toughness and stiffness, and corrosion resistance. However, if exposed to hydrogen sources, these alloys are susceptible to hydride formation in the form of TiHx (0 < x ≤ 2), leading to crack initiation and mechanical failure due to lattice deformation and stress accumulation. The kinetics of the hydriding process depends on several factors, including the critical saturation threshold for hydrogen within Ti, the specific interaction of hydrogen with protective surface oxide, the rates of mass transport, and the kinetics of nucleation and phase transformation. Unfortunately, key knowledge gaps and challenges remain regarding the details of these coupled processes, which take place across vast ranges of time and length scales and are often difficult to probe directly. This work reviews recent advances in multiscale characterization and modeling efforts in Ti hydriding. We identify unanswered questions and key challenges, propose new perspectives on how to solve these remaining issues, and close knowledge gaps by discussing and demonstrating specific opportunities for integrating advanced characterization and multiscale modeling to elucidate chemistry and composition, microstructure phenomena, and macroscale performance and testing.",

author = "Yakun Zhu and \{Wook Heo\}, Tae and Rodriguez, \{Jennifer N.\} and Weber, \{Peter K.\} and Rongpei Shi and Baer, \{Bruce J.\} and Morgado, \{Felipe F.\} and Stoichko Antonov and Kweon, \{Kyoung E.\} and Watkins, \{Erik B.\} and Savage, \{Daniel J.\} and Chapman, \{James E.\} and Keilbart, \{Nathan D.\} and Younggil Song and Qi Zhen and Baptiste Gault and Vogel, \{Sven C.\} and Sen-Britain, \{Shohini T.\} and Shalloo, \{Matthew G.\} and Chris Orme and Michael Bagge-Hansen and Christopher Hahn and Pham, \{Tuan A.\} and Macdonald, \{Digby D.\} and \{Roger Qiu\}, S. and Wood, \{Brandon C.\}",

note = "Publisher Copyright: {\textcopyright} 2022 The Authors",

year = "2022",

month = dec,

doi = "10.1016/j.cossms.2022.101020",

language = "English",

volume = "26",

journal = "Current Opinion in Solid State and Materials Science",

issn = "1359-0286",

publisher = "Elsevier",

number = "6",

}

Zhu, Y, Wook Heo, T, Rodriguez, JN, Weber, PK, Shi, R, Baer, BJ, Morgado, FF, Antonov, S, Kweon, KE, Watkins, EB, Savage, DJ, Chapman, JE, Keilbart, ND, Song, Y, Zhen, Q, Gault, B, Vogel, SC, Sen-Britain, ST, Shalloo, MG, Orme, C, Bagge-Hansen, M, Hahn, C, Pham, TA, Macdonald, DD, Roger Qiu, S & Wood, BC 2022, 'Hydriding of titanium: Recent trends and perspectives in advanced characterization and multiscale modeling', Current Opinion in Solid State and Materials Science, vol. 26, no. 6, 101020. https://doi.org/10.1016/j.cossms.2022.101020

TY - JOUR

T1 - Hydriding of titanium

T2 - Recent trends and perspectives in advanced characterization and multiscale modeling

AU - Zhu, Yakun

AU - Wook Heo, Tae

AU - Rodriguez, Jennifer N.

AU - Weber, Peter K.

AU - Shi, Rongpei

AU - Baer, Bruce J.

AU - Morgado, Felipe F.

AU - Antonov, Stoichko

AU - Kweon, Kyoung E.

AU - Watkins, Erik B.

AU - Savage, Daniel J.

AU - Chapman, James E.

AU - Keilbart, Nathan D.

AU - Song, Younggil

AU - Zhen, Qi

AU - Gault, Baptiste

AU - Vogel, Sven C.

AU - Sen-Britain, Shohini T.

AU - Shalloo, Matthew G.

AU - Orme, Chris

AU - Bagge-Hansen, Michael

AU - Hahn, Christopher

AU - Pham, Tuan A.

AU - Macdonald, Digby D.

AU - Roger Qiu, S.

AU - Wood, Brandon C.

PY - 2022/12

Y1 - 2022/12

N2 - Titanium (Ti) and its alloys are attractive for a wide variety of structural and functional applications owing to excellent specific strength, toughness and stiffness, and corrosion resistance. However, if exposed to hydrogen sources, these alloys are susceptible to hydride formation in the form of TiHx (0 < x ≤ 2), leading to crack initiation and mechanical failure due to lattice deformation and stress accumulation. The kinetics of the hydriding process depends on several factors, including the critical saturation threshold for hydrogen within Ti, the specific interaction of hydrogen with protective surface oxide, the rates of mass transport, and the kinetics of nucleation and phase transformation. Unfortunately, key knowledge gaps and challenges remain regarding the details of these coupled processes, which take place across vast ranges of time and length scales and are often difficult to probe directly. This work reviews recent advances in multiscale characterization and modeling efforts in Ti hydriding. We identify unanswered questions and key challenges, propose new perspectives on how to solve these remaining issues, and close knowledge gaps by discussing and demonstrating specific opportunities for integrating advanced characterization and multiscale modeling to elucidate chemistry and composition, microstructure phenomena, and macroscale performance and testing.

AB - Titanium (Ti) and its alloys are attractive for a wide variety of structural and functional applications owing to excellent specific strength, toughness and stiffness, and corrosion resistance. However, if exposed to hydrogen sources, these alloys are susceptible to hydride formation in the form of TiHx (0 < x ≤ 2), leading to crack initiation and mechanical failure due to lattice deformation and stress accumulation. The kinetics of the hydriding process depends on several factors, including the critical saturation threshold for hydrogen within Ti, the specific interaction of hydrogen with protective surface oxide, the rates of mass transport, and the kinetics of nucleation and phase transformation. Unfortunately, key knowledge gaps and challenges remain regarding the details of these coupled processes, which take place across vast ranges of time and length scales and are often difficult to probe directly. This work reviews recent advances in multiscale characterization and modeling efforts in Ti hydriding. We identify unanswered questions and key challenges, propose new perspectives on how to solve these remaining issues, and close knowledge gaps by discussing and demonstrating specific opportunities for integrating advanced characterization and multiscale modeling to elucidate chemistry and composition, microstructure phenomena, and macroscale performance and testing.

UR - https://www.scopus.com/pages/publications/85133789118

U2 - 10.1016/j.cossms.2022.101020

DO - 10.1016/j.cossms.2022.101020

M3 - Review article

AN - SCOPUS:85133789118

SN - 1359-0286

VL - 26

JO - Current Opinion in Solid State and Materials Science

JF - Current Opinion in Solid State and Materials Science

IS - 6

M1 - 101020

ER -

Hydriding of titanium: Recent trends and perspectives in advanced characterization and multiscale modeling

Abstract

Funding

Access to Document

Other files and links

Fingerprint

Cite this