Hybrid uranyl-vanadium nano-wheels

G. A. Senchyk; E. M. Wylie; S. Prizio; J. E.S. Szymanowski; G. E. Sigmon; P. C. Burns

doi:10.1039/c5cc01524c

Hybrid uranyl-vanadium nano-wheels

G. A. Senchyk
, E. M. Wylie
, S. Prizio
, J. E.S. Szymanowski
, G. E. Sigmon
, P. C. Burns

Research output: Contribution to journal › Article › peer-review

29 Scopus citations

Abstract

Hybrid uranyl-vanadium oxide clusters intermediate between transition metal polyoxometalates and uranyl peroxide cage clusters were obtained by dissolving uranyl nitrate in the ionic liquid 3-ethyl-1-methylimidazolium ethyl sulfate mixed with an aqueous solution containing vanadium. Where sulfate was present, wheel-shaped {U₂₀V₂₀} crystallized and contains ten sulfate tetrahedra, and in the absence of added sulfate, {U₂V₁₆}, a derivative of {V₁₈}, was obtained.

Original language	English
Pages (from-to)	10134-10137
Number of pages	4
Journal	Chemical Communications
Volume	51
Issue number	50
DOIs	https://doi.org/10.1039/c5cc01524c
State	Published - May 28 2015
Externally published	Yes

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title = "Hybrid uranyl-vanadium nano-wheels",

abstract = "Hybrid uranyl-vanadium oxide clusters intermediate between transition metal polyoxometalates and uranyl peroxide cage clusters were obtained by dissolving uranyl nitrate in the ionic liquid 3-ethyl-1-methylimidazolium ethyl sulfate mixed with an aqueous solution containing vanadium. Where sulfate was present, wheel-shaped \{U20V20\} crystallized and contains ten sulfate tetrahedra, and in the absence of added sulfate, \{U2V16\}, a derivative of \{V18\}, was obtained.",

author = "Senchyk, \{G. A.\} and Wylie, \{E. M.\} and S. Prizio and Szymanowski, \{J. E.S.\} and Sigmon, \{G. E.\} and Burns, \{P. C.\}",

note = "Publisher Copyright: {\textcopyright} The Royal Society of Chemistry 2015.",

year = "2015",

month = may,

day = "28",

doi = "10.1039/c5cc01524c",

language = "English",

volume = "51",

pages = "10134--10137",

journal = "Chemical Communications",

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publisher = "Royal Society of Chemistry",

number = "50",

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TY - JOUR

T1 - Hybrid uranyl-vanadium nano-wheels

AU - Senchyk, G. A.

AU - Wylie, E. M.

AU - Prizio, S.

AU - Szymanowski, J. E.S.

AU - Sigmon, G. E.

AU - Burns, P. C.

PY - 2015/5/28

Y1 - 2015/5/28

N2 - Hybrid uranyl-vanadium oxide clusters intermediate between transition metal polyoxometalates and uranyl peroxide cage clusters were obtained by dissolving uranyl nitrate in the ionic liquid 3-ethyl-1-methylimidazolium ethyl sulfate mixed with an aqueous solution containing vanadium. Where sulfate was present, wheel-shaped {U20V20} crystallized and contains ten sulfate tetrahedra, and in the absence of added sulfate, {U2V16}, a derivative of {V18}, was obtained.

AB - Hybrid uranyl-vanadium oxide clusters intermediate between transition metal polyoxometalates and uranyl peroxide cage clusters were obtained by dissolving uranyl nitrate in the ionic liquid 3-ethyl-1-methylimidazolium ethyl sulfate mixed with an aqueous solution containing vanadium. Where sulfate was present, wheel-shaped {U20V20} crystallized and contains ten sulfate tetrahedra, and in the absence of added sulfate, {U2V16}, a derivative of {V18}, was obtained.

UR - https://www.scopus.com/pages/publications/84931275673

U2 - 10.1039/c5cc01524c

DO - 10.1039/c5cc01524c

M3 - Article

AN - SCOPUS:84931275673

SN - 1359-7345

VL - 51

SP - 10134

EP - 10137

JO - Chemical Communications

JF - Chemical Communications

IS - 50

ER -

Hybrid uranyl-vanadium nano-wheels

Abstract

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