How small variations in crystal interactions affect macroscopic properties

F. Albert Cotton; Santiago Herrero; Reyes Jiménez-Aparicio; Carlos A. Murillo; Francisco A. Urbanos; Dino Villagrán; Xiaoping Wang

doi:10.1021/ja075808z

How small variations in crystal interactions affect macroscopic properties

F. Albert Cotton
, Santiago Herrero
, Reyes Jiménez-Aparicio
, Carlos A. Murillo
, Francisco A. Urbanos
, Dino Villagrán
, Xiaoping Wang

Research output: Contribution to journal › Article › peer-review

34 Scopus citations

Abstract

A Ru₂⁵⁺ compound having two crystallographically independent molecules that differ only in that one molecule has an additional hydrogen bond shows Ru-Ru distances that vary by ca. 0.07 Å at 30 K; as the temperature is raised, one molecule displays a spin transition but the other one remains in the same spin state, as indicated by variable temperature magnetic and structural data.

Original language	English
Pages (from-to)	12666-12667
Number of pages	2
Journal	Journal of the American Chemical Society
Volume	129
Issue number	42
DOIs	https://doi.org/10.1021/ja075808z
State	Published - Oct 24 2007
Externally published	Yes

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10.1021/ja075808z

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title = "How small variations in crystal interactions affect macroscopic properties",

abstract = "A Ru25+ compound having two crystallographically independent molecules that differ only in that one molecule has an additional hydrogen bond shows Ru-Ru distances that vary by ca. 0.07 {\AA} at 30 K; as the temperature is raised, one molecule displays a spin transition but the other one remains in the same spin state, as indicated by variable temperature magnetic and structural data.",

author = "Cotton, \{F. Albert\} and Santiago Herrero and Reyes Jim{\'e}nez-Aparicio and Murillo, \{Carlos A.\} and Urbanos, \{Francisco A.\} and Dino Villagr{\'a}n and Xiaoping Wang",

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AU - Cotton, F. Albert

AU - Herrero, Santiago

AU - Jiménez-Aparicio, Reyes

AU - Murillo, Carlos A.

AU - Urbanos, Francisco A.

AU - Villagrán, Dino

AU - Wang, Xiaoping

PY - 2007/10/24

Y1 - 2007/10/24

N2 - A Ru25+ compound having two crystallographically independent molecules that differ only in that one molecule has an additional hydrogen bond shows Ru-Ru distances that vary by ca. 0.07 Å at 30 K; as the temperature is raised, one molecule displays a spin transition but the other one remains in the same spin state, as indicated by variable temperature magnetic and structural data.

AB - A Ru25+ compound having two crystallographically independent molecules that differ only in that one molecule has an additional hydrogen bond shows Ru-Ru distances that vary by ca. 0.07 Å at 30 K; as the temperature is raised, one molecule displays a spin transition but the other one remains in the same spin state, as indicated by variable temperature magnetic and structural data.

UR - https://www.scopus.com/pages/publications/35548979998

U2 - 10.1021/ja075808z

DO - 10.1021/ja075808z

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AN - SCOPUS:35548979998

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EP - 12667

JO - Journal of the American Chemical Society

JF - Journal of the American Chemical Society

IS - 42

ER -

How small variations in crystal interactions affect macroscopic properties

Abstract

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