How small variations in crystal interactions affect macroscopic properties

F. Albert Cotton; Santiago Herrero; Reyes Jiménez-Aparicio; Carlos A. Murillo; Francisco A. Urbanos; Dino Villagrán; Xiaoping Wang

doi:10.1021/ja075808z

How small variations in crystal interactions affect macroscopic properties

F. Albert Cotton, Santiago Herrero, Reyes Jiménez-Aparicio, Carlos A. Murillo, Francisco A. Urbanos, Dino Villagrán, Xiaoping Wang

Research output: Contribution to journal › Article › peer-review

32 Scopus citations

Abstract

A Ru₂⁵⁺ compound having two crystallographically independent molecules that differ only in that one molecule has an additional hydrogen bond shows Ru-Ru distances that vary by ca. 0.07 Å at 30 K; as the temperature is raised, one molecule displays a spin transition but the other one remains in the same spin state, as indicated by variable temperature magnetic and structural data.

Original language	English
Pages (from-to)	12666-12667
Number of pages	2
Journal	Journal of the American Chemical Society
Volume	129
Issue number	42
DOIs	https://doi.org/10.1021/ja075808z
State	Published - Oct 24 2007
Externally published	Yes

Access to Document

10.1021/ja075808z

Cite this

@article{7d0716bf662543f8bf2c116f0c4b3378,

title = "How small variations in crystal interactions affect macroscopic properties",

abstract = "A Ru25+ compound having two crystallographically independent molecules that differ only in that one molecule has an additional hydrogen bond shows Ru-Ru distances that vary by ca. 0.07 {\AA} at 30 K; as the temperature is raised, one molecule displays a spin transition but the other one remains in the same spin state, as indicated by variable temperature magnetic and structural data.",

author = "Cotton, {F. Albert} and Santiago Herrero and Reyes Jim{\'e}nez-Aparicio and Murillo, {Carlos A.} and Urbanos, {Francisco A.} and Dino Villagr{\'a}n and Xiaoping Wang",

year = "2007",

month = oct,

day = "24",

doi = "10.1021/ja075808z",

language = "English",

volume = "129",

pages = "12666--12667",

journal = "Journal of the American Chemical Society",

issn = "0002-7863",

publisher = "American Chemical Society",

number = "42",

}

TY - JOUR

T1 - How small variations in crystal interactions affect macroscopic properties

AU - Cotton, F. Albert

AU - Herrero, Santiago

AU - Jiménez-Aparicio, Reyes

AU - Murillo, Carlos A.

AU - Urbanos, Francisco A.

AU - Villagrán, Dino

AU - Wang, Xiaoping

PY - 2007/10/24

Y1 - 2007/10/24

N2 - A Ru25+ compound having two crystallographically independent molecules that differ only in that one molecule has an additional hydrogen bond shows Ru-Ru distances that vary by ca. 0.07 Å at 30 K; as the temperature is raised, one molecule displays a spin transition but the other one remains in the same spin state, as indicated by variable temperature magnetic and structural data.

AB - A Ru25+ compound having two crystallographically independent molecules that differ only in that one molecule has an additional hydrogen bond shows Ru-Ru distances that vary by ca. 0.07 Å at 30 K; as the temperature is raised, one molecule displays a spin transition but the other one remains in the same spin state, as indicated by variable temperature magnetic and structural data.

UR - http://www.scopus.com/inward/record.url?scp=35548979998&partnerID=8YFLogxK

U2 - 10.1021/ja075808z

DO - 10.1021/ja075808z

M3 - Article

C2 - 17910458

AN - SCOPUS:35548979998

SN - 0002-7863

VL - 129

SP - 12666

EP - 12667

JO - Journal of the American Chemical Society

JF - Journal of the American Chemical Society

IS - 42

ER -

How small variations in crystal interactions affect macroscopic properties

Abstract

Access to Document

Other files and links

Fingerprint

Cite this