How Cerium and Lanthanum as Coproducts Promote Stable Rare Earth Production and New Alloys

Zachary C. Sims, Michael S. Kesler, Hunter B. Henderson, Emilio Castillo, Tomer Fishman, David Weiss, Prentice Singleton, Roderick Eggert, Scott K. McCall, Orlando Rios

Research output: Contribution to journalArticlepeer-review

30 Scopus citations

Abstract

The largest outputs of rare earth mining are the low-value byproducts cerium and lanthanum, which burden rare earth supply chains because they must be separated from more desirable rare earths used in magnet production. Promoting demand for cerium and lanthanum can potentially diversify the economics of rare earth mining and improve supply chain stability for all rare earth elements. A promising avenue for increasing byproduct rare earth element demand is their use in aluminum alloys; an application for cerium and lanthanum offering multiple benefits to manufacturing such as energy reduction and improved throughput. Experimental materials science and economic implications of Al-rare earth element alloys will be discussed. We show that Al–La/Ce alloys have elevated mechanical strength compared to more traditional aluminum alloys, in some formulations can be used without heat treatment, and possess a highly castable eutectic microstructure. This report presents the use of cerium and lanthanum in aluminum alloys as an example of how supply chain focused approaches to technological development can benefit stakeholders at every step in production. Graphical Abstract: [Figure not available: see fulltext.]

Original languageEnglish
Pages (from-to)1225-1234
Number of pages10
JournalJournal of Sustainable Metallurgy
Volume8
Issue number3
DOIs
StatePublished - Sep 2022

Funding

This research was sponsored by the Critical Materials Institute, an Energy Innovation Hub funded by the U.S. Department of Energy (DOE), Office of Energy Efficiency and Renewable Energy and Advanced Manufacturing Office. Work performed at LLNL under contract DE-AC52-07NA27344 and ORNL under contract number DE-AC05-00OR22725.

FundersFunder number
Critical Materials Institute
Office of Energy Efficiency and Renewable Energy and Advanced Manufacturing OfficeDE-AC52-07NA27344
U.S. Department of Energy
Oak Ridge National LaboratoryDE-AC05-00OR22725

    Keywords

    • Alloys
    • Aluminum
    • Cerium
    • Critical materials
    • Rare earth elements
    • Sustainability

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