Hot water from cold. the dissociative recombination of water cluster ions

R. D. Thomas; V. Zhaunerchyk; F. Hellberg; A. Ehlerding; W. D. Geppert; E. Bahati; M. E. Bannister; M. R. Fogle; C. R. Vane; A. Petrignani; P. U. Andersson; J. Öjekull; J. B.C. Pettersson; W. J. Van Der Zande; M. Larsson

doi:10.1021/jp9095979

Hot water from cold. the dissociative recombination of water cluster ions

R. D. Thomas
, V. Zhaunerchyk
, F. Hellberg
, A. Ehlerding
, W. D. Geppert
, E. Bahati
, M. E. Bannister
, M. R. Fogle
, C. R. Vane
, A. Petrignani
, P. U. Andersson
, J. Öjekull
, J. B.C. Pettersson
, W. J. Van Der Zande
, M. Larsson

Electrical & Chemical Operations

Research output: Contribution to journal › Article › peer-review

4 Scopus citations

Abstract

Dissociative recombination of the Zundel cation D₅O2⁺ almost exclusively produces D + 2 D₂O with a maximum kinetic energy release of 5.1 eV. An imaging technique is used to investigate the distribution of the available reaction energy among these products. Analysis shows that as much as 4 eV can be stored internally by the molecular fragments, with a preference for producing highly excited molecular fragments, and that the deuteron shows a nonrandom distribution of kinetic energies. A possible mechanism and the implications for these observations are addressed.

Original language	English
Pages (from-to)	4843-4846
Number of pages	4
Journal	Journal of Physical Chemistry A
Volume	114
Issue number	14
DOIs	https://doi.org/10.1021/jp9095979
State	Published - Apr 15 2010

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Thomas, R. D., Zhaunerchyk, V., Hellberg, F., Ehlerding, A., Geppert, W. D., Bahati, E., Bannister, M. E., Fogle, M. R., Vane, C. R., Petrignani, A., Andersson, P. U., Öjekull, J., Pettersson, J. B. C., Van Der Zande, W. J., & Larsson, M. (2010). Hot water from cold. the dissociative recombination of water cluster ions. Journal of Physical Chemistry A, 114(14), 4843-4846. https://doi.org/10.1021/jp9095979

@article{4639d375faa9421fb3698c9969b3409d,

title = "Hot water from cold. the dissociative recombination of water cluster ions",

abstract = "Dissociative recombination of the Zundel cation D5O2+ almost exclusively produces D + 2 D2O with a maximum kinetic energy release of 5.1 eV. An imaging technique is used to investigate the distribution of the available reaction energy among these products. Analysis shows that as much as 4 eV can be stored internally by the molecular fragments, with a preference for producing highly excited molecular fragments, and that the deuteron shows a nonrandom distribution of kinetic energies. A possible mechanism and the implications for these observations are addressed.",

author = "Thomas, \{R. D.\} and V. Zhaunerchyk and F. Hellberg and A. Ehlerding and Geppert, \{W. D.\} and E. Bahati and Bannister, \{M. E.\} and Fogle, \{M. R.\} and Vane, \{C. R.\} and A. Petrignani and Andersson, \{P. U.\} and J. {\"O}jekull and Pettersson, \{J. B.C.\} and \{Van Der Zande\}, \{W. J.\} and M. Larsson",

year = "2010",

month = apr,

day = "15",

doi = "10.1021/jp9095979",

language = "English",

volume = "114",

pages = "4843--4846",

journal = "Journal of Physical Chemistry A",

issn = "1089-5639",

publisher = "American Chemical Society",

number = "14",

}

Thomas, RD, Zhaunerchyk, V, Hellberg, F, Ehlerding, A, Geppert, WD, Bahati, E, Bannister, ME, Fogle, MR, Vane, CR, Petrignani, A, Andersson, PU, Öjekull, J, Pettersson, JBC, Van Der Zande, WJ & Larsson, M 2010, 'Hot water from cold. the dissociative recombination of water cluster ions', Journal of Physical Chemistry A, vol. 114, no. 14, pp. 4843-4846. https://doi.org/10.1021/jp9095979

TY - JOUR

T1 - Hot water from cold. the dissociative recombination of water cluster ions

AU - Thomas, R. D.

AU - Zhaunerchyk, V.

AU - Hellberg, F.

AU - Ehlerding, A.

AU - Geppert, W. D.

AU - Bahati, E.

AU - Bannister, M. E.

AU - Fogle, M. R.

AU - Vane, C. R.

AU - Petrignani, A.

AU - Andersson, P. U.

AU - Öjekull, J.

AU - Pettersson, J. B.C.

AU - Van Der Zande, W. J.

AU - Larsson, M.

PY - 2010/4/15

Y1 - 2010/4/15

N2 - Dissociative recombination of the Zundel cation D5O2+ almost exclusively produces D + 2 D2O with a maximum kinetic energy release of 5.1 eV. An imaging technique is used to investigate the distribution of the available reaction energy among these products. Analysis shows that as much as 4 eV can be stored internally by the molecular fragments, with a preference for producing highly excited molecular fragments, and that the deuteron shows a nonrandom distribution of kinetic energies. A possible mechanism and the implications for these observations are addressed.

AB - Dissociative recombination of the Zundel cation D5O2+ almost exclusively produces D + 2 D2O with a maximum kinetic energy release of 5.1 eV. An imaging technique is used to investigate the distribution of the available reaction energy among these products. Analysis shows that as much as 4 eV can be stored internally by the molecular fragments, with a preference for producing highly excited molecular fragments, and that the deuteron shows a nonrandom distribution of kinetic energies. A possible mechanism and the implications for these observations are addressed.

UR - https://www.scopus.com/pages/publications/77950655943

U2 - 10.1021/jp9095979

DO - 10.1021/jp9095979

M3 - Article

AN - SCOPUS:77950655943

SN - 1089-5639

VL - 114

SP - 4843

EP - 4846

JO - Journal of Physical Chemistry A

JF - Journal of Physical Chemistry A

IS - 14

ER -

Hot water from cold. the dissociative recombination of water cluster ions

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