Hole-Size Relationships in the Assembly of a Furandicarboxylate-Based Metallolinker in Praseodymium Coordination Polymers Synthesized under Basic Conditions

Jeffrey D. Einkauf; Joseph P. Karram; Natalie E. Greig; Benny C. Chan; Daniel T. De Lill

doi:10.1002/ejic.201501350

Hole-Size Relationships in the Assembly of a Furandicarboxylate-Based Metallolinker in Praseodymium Coordination Polymers Synthesized under Basic Conditions

Jeffrey D. Einkauf, Joseph P. Karram, Natalie E. Greig, Benny C. Chan, Daniel T. De Lill

Research output: Contribution to journal › Article › peer-review

6 Scopus citations

Abstract

Two new coordination polymers have been synthesized with 2,5-furandicarboxylic acid upon base modification. The resulting structures are dependent on the base added. When KOH was used as base, potassium was incorporated into the two-dimensional coordination polymer, acting as a metallolinker to give [Pr₂K₂(OH)₂(C₆H₂O₅)₃(H₂O)₃]·H₂O (1). Synthesis with other alkali hydroxides produced a three-dimensional metal-organic framework, [Pr₈(OH)₆(C₆H₂O₅)₉(H₂O)₁₅]·3H₂O (2), and the alkali metal cations were not incorporated into the structure. Hole-size effects with bite-angle analyses indicate that metallolinker formation depends on the cation size. The resulting compounds were characterized by single-crystal X-ray diffraction, powder X-ray diffraction, elemental analysis, and thermogravimetric analysis.

Original language	English
Pages (from-to)	1085-1092
Number of pages	8
Journal	European Journal of Inorganic Chemistry
Volume	2016
Issue number	7
DOIs	https://doi.org/10.1002/ejic.201501350
State	Published - Mar 1 2016
Externally published	Yes

Funding

The authors would like to thank Florida Atlantic University (FAU) for funding this project, in particular the FAU''s Office of Undergraduate Research and Inquiry for funding part of this project (J. P. K.) along with the National Science Foundation MRI (grant no. 0922931; B. C. C.).

Funders	Funder number
National Science Foundation MRI	0922931
Office of Undergraduate Research and Inquiry
Florida Atlantic University

Keywords

Coordination polymers
Furandicarboxylate
Lanthanides
Structure elucidation

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10.1002/ejic.201501350

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title = "Hole-Size Relationships in the Assembly of a Furandicarboxylate-Based Metallolinker in Praseodymium Coordination Polymers Synthesized under Basic Conditions",

abstract = "Two new coordination polymers have been synthesized with 2,5-furandicarboxylic acid upon base modification. The resulting structures are dependent on the base added. When KOH was used as base, potassium was incorporated into the two-dimensional coordination polymer, acting as a metallolinker to give [Pr2K2(OH)2(C6H2O5)3(H2O)3]·H2O (1). Synthesis with other alkali hydroxides produced a three-dimensional metal-organic framework, [Pr8(OH)6(C6H2O5)9(H2O)15]·3H2O (2), and the alkali metal cations were not incorporated into the structure. Hole-size effects with bite-angle analyses indicate that metallolinker formation depends on the cation size. The resulting compounds were characterized by single-crystal X-ray diffraction, powder X-ray diffraction, elemental analysis, and thermogravimetric analysis.",

keywords = "Coordination polymers, Furandicarboxylate, Lanthanides, Structure elucidation",

author = "Einkauf, {Jeffrey D.} and Karram, {Joseph P.} and Greig, {Natalie E.} and Chan, {Benny C.} and {De Lill}, {Daniel T.}",

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Hole-Size Relationships in the Assembly of a Furandicarboxylate-Based Metallolinker in Praseodymium Coordination Polymers Synthesized under Basic Conditions. / Einkauf, Jeffrey D.; Karram, Joseph P.; Greig, Natalie E. et al.
In: European Journal of Inorganic Chemistry, Vol. 2016, No. 7, 01.03.2016, p. 1085-1092.

Research output: Contribution to journal › Article › peer-review

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T1 - Hole-Size Relationships in the Assembly of a Furandicarboxylate-Based Metallolinker in Praseodymium Coordination Polymers Synthesized under Basic Conditions

AU - Einkauf, Jeffrey D.

AU - Karram, Joseph P.

AU - Greig, Natalie E.

AU - Chan, Benny C.

AU - De Lill, Daniel T.

PY - 2016/3/1

Y1 - 2016/3/1

N2 - Two new coordination polymers have been synthesized with 2,5-furandicarboxylic acid upon base modification. The resulting structures are dependent on the base added. When KOH was used as base, potassium was incorporated into the two-dimensional coordination polymer, acting as a metallolinker to give [Pr2K2(OH)2(C6H2O5)3(H2O)3]·H2O (1). Synthesis with other alkali hydroxides produced a three-dimensional metal-organic framework, [Pr8(OH)6(C6H2O5)9(H2O)15]·3H2O (2), and the alkali metal cations were not incorporated into the structure. Hole-size effects with bite-angle analyses indicate that metallolinker formation depends on the cation size. The resulting compounds were characterized by single-crystal X-ray diffraction, powder X-ray diffraction, elemental analysis, and thermogravimetric analysis.

AB - Two new coordination polymers have been synthesized with 2,5-furandicarboxylic acid upon base modification. The resulting structures are dependent on the base added. When KOH was used as base, potassium was incorporated into the two-dimensional coordination polymer, acting as a metallolinker to give [Pr2K2(OH)2(C6H2O5)3(H2O)3]·H2O (1). Synthesis with other alkali hydroxides produced a three-dimensional metal-organic framework, [Pr8(OH)6(C6H2O5)9(H2O)15]·3H2O (2), and the alkali metal cations were not incorporated into the structure. Hole-size effects with bite-angle analyses indicate that metallolinker formation depends on the cation size. The resulting compounds were characterized by single-crystal X-ray diffraction, powder X-ray diffraction, elemental analysis, and thermogravimetric analysis.

KW - Coordination polymers

KW - Furandicarboxylate

KW - Lanthanides

KW - Structure elucidation

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Hole-Size Relationships in the Assembly of a Furandicarboxylate-Based Metallolinker in Praseodymium Coordination Polymers Synthesized under Basic Conditions

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