Highly soluble alkoxide magnesium salts for rechargeable magnesium batteries

Chen Liao; Bingkun Guo; De En Jiang; Radu Custelcean; Shannon M. Mahurin; Xiao Guang Sun; Sheng Dai

doi:10.1039/c3ta13691d

Highly soluble alkoxide magnesium salts for rechargeable magnesium batteries

Chen Liao, Bingkun Guo, De En Jiang, Radu Custelcean, Shannon M. Mahurin, Xiao Guang Sun, Sheng Dai

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76 Scopus citations

Abstract

A unique class of air-stable and non-pyrophoric magnesium electrolytes has been developed based on alkoxide magnesium compounds. The crystals obtained from this class of electrolytes exhibit a unique structure of tri-magnesium cluster, [Mg₃Cl₃(OR)₂(THF)₆]⁺ [(THF)MgCl₃]^-. High reversible capacities and good rate capabilities have been obtained in Mg-Mo₆S₈ batteries using these new electrolytes at both 20 and 50 °C.

Original language	English
Pages (from-to)	581-584
Number of pages	4
Journal	Journal of Materials Chemistry A
Volume	2
Issue number	3
DOIs	https://doi.org/10.1039/c3ta13691d
State	Published - Jan 21 2014

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title = "Highly soluble alkoxide magnesium salts for rechargeable magnesium batteries",

abstract = "A unique class of air-stable and non-pyrophoric magnesium electrolytes has been developed based on alkoxide magnesium compounds. The crystals obtained from this class of electrolytes exhibit a unique structure of tri-magnesium cluster, [Mg3Cl3(OR)2(THF)6]+ [(THF)MgCl3]-. High reversible capacities and good rate capabilities have been obtained in Mg-Mo6S8 batteries using these new electrolytes at both 20 and 50 °C.",

author = "Chen Liao and Bingkun Guo and Jiang, \{De En\} and Radu Custelcean and Mahurin, \{Shannon M.\} and Sun, \{Xiao Guang\} and Sheng Dai",

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T1 - Highly soluble alkoxide magnesium salts for rechargeable magnesium batteries

AU - Liao, Chen

AU - Guo, Bingkun

AU - Jiang, De En

AU - Custelcean, Radu

AU - Mahurin, Shannon M.

AU - Sun, Xiao Guang

AU - Dai, Sheng

PY - 2014/1/21

Y1 - 2014/1/21

N2 - A unique class of air-stable and non-pyrophoric magnesium electrolytes has been developed based on alkoxide magnesium compounds. The crystals obtained from this class of electrolytes exhibit a unique structure of tri-magnesium cluster, [Mg3Cl3(OR)2(THF)6]+ [(THF)MgCl3]-. High reversible capacities and good rate capabilities have been obtained in Mg-Mo6S8 batteries using these new electrolytes at both 20 and 50 °C.

AB - A unique class of air-stable and non-pyrophoric magnesium electrolytes has been developed based on alkoxide magnesium compounds. The crystals obtained from this class of electrolytes exhibit a unique structure of tri-magnesium cluster, [Mg3Cl3(OR)2(THF)6]+ [(THF)MgCl3]-. High reversible capacities and good rate capabilities have been obtained in Mg-Mo6S8 batteries using these new electrolytes at both 20 and 50 °C.

UR - https://www.scopus.com/pages/publications/84890281398

U2 - 10.1039/c3ta13691d

DO - 10.1039/c3ta13691d

M3 - Article

AN - SCOPUS:84890281398

SN - 2050-7488

VL - 2

SP - 581

EP - 584

JO - Journal of Materials Chemistry A

JF - Journal of Materials Chemistry A

IS - 3

ER -

Highly soluble alkoxide magnesium salts for rechargeable magnesium batteries

Abstract

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