Highly Permeable Oligo(ethylene oxide)-co-poly(dimethylsiloxane) Membranes for Carbon Dioxide Separation

Tao Hong; Sophia Lai; Shannon M. Mahurin; Peng Fei Cao; Dmitry N. Voylov; Harry M. Meyer; Christopher B. Jacobs; Jan Michael Y. Carrillo; Alexander Kisliuk; Ilia N. Ivanov; De en Jiang; Brian K. Long; Jimmy W. Mays; Alexei P. Sokolov; Tomonori Saito

doi:10.1002/adsu.201700113

Highly Permeable Oligo(ethylene oxide)-co-poly(dimethylsiloxane) Membranes for Carbon Dioxide Separation

Tao Hong, Sophia Lai, Shannon M. Mahurin, Peng Fei Cao, Dmitry N. Voylov, Harry M. Meyer, Christopher B. Jacobs, Jan Michael Y. Carrillo, Alexander Kisliuk, Ilia N. Ivanov, De en Jiang, Brian K. Long, Jimmy W. Mays, Alexei P. Sokolov, Tomonori Saito

Research output: Contribution to journal › Article › peer-review

10 Scopus citations

Abstract

A series of cross-linked, freestanding oligo(ethylene oxide)-co-(polydimethylsiloxane-norbornene) membranes with varied composition is synthesized via in situ ring-opening metathesis polymerization. These membranes show remarkably high CO₂ permeabilities (3400 Barrer) and their separation performance approaches the Robeson upper bound. The excellent permeability of these copolymer membranes provides great potential for real-world applications where enormous volumes of gases must be separated. The gas transport properties of these films are found to be directly proportional to oligo(ethylene oxide) content incorporation, which stems from the increased solubility selectivity change within the copolymer matrix. This work provides a systematic study of how gas separation performance in rubbery membranes can be enhanced by tuning the CO₂-philicity of their constituent monomeric subunits.

Original language	English
Article number	1700113
Journal	Advanced Sustainable Systems
Volume	2
Issue number	4
DOIs	https://doi.org/10.1002/adsu.201700113
State	Published - Apr 1 2018

Keywords

CO-philic
high permeability
membrane gas separation
oligo(ethylene oxide)
polydimethylsiloxane

UN SDGs

This output contributes to the following UN Sustainable Development Goals (SDGs)

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10.1002/adsu.201700113

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Hong, T., Lai, S., Mahurin, S. M., Cao, P. F., Voylov, D. N., Meyer, H. M., Jacobs, C. B., Carrillo, J. M. Y., Kisliuk, A., Ivanov, I. N., Jiang, D. E., Long, B. K., Mays, J. W., Sokolov, A. P., & Saito, T. (2018). Highly Permeable Oligo(ethylene oxide)-co-poly(dimethylsiloxane) Membranes for Carbon Dioxide Separation. Advanced Sustainable Systems, 2(4), Article 1700113. https://doi.org/10.1002/adsu.201700113

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title = "Highly Permeable Oligo(ethylene oxide)-co-poly(dimethylsiloxane) Membranes for Carbon Dioxide Separation",

abstract = "A series of cross-linked, freestanding oligo(ethylene oxide)-co-(polydimethylsiloxane-norbornene) membranes with varied composition is synthesized via in situ ring-opening metathesis polymerization. These membranes show remarkably high CO2 permeabilities (3400 Barrer) and their separation performance approaches the Robeson upper bound. The excellent permeability of these copolymer membranes provides great potential for real-world applications where enormous volumes of gases must be separated. The gas transport properties of these films are found to be directly proportional to oligo(ethylene oxide) content incorporation, which stems from the increased solubility selectivity change within the copolymer matrix. This work provides a systematic study of how gas separation performance in rubbery membranes can be enhanced by tuning the CO2-philicity of their constituent monomeric subunits.",

keywords = "CO-philic, high permeability, membrane gas separation, oligo(ethylene oxide), polydimethylsiloxane",

author = "Tao Hong and Sophia Lai and Mahurin, {Shannon M.} and Cao, {Peng Fei} and Voylov, {Dmitry N.} and Meyer, {Harry M.} and Jacobs, {Christopher B.} and Carrillo, {Jan Michael Y.} and Alexander Kisliuk and Ivanov, {Ilia N.} and Jiang, {De en} and Long, {Brian K.} and Mays, {Jimmy W.} and Sokolov, {Alexei P.} and Tomonori Saito",

note = "Publisher Copyright: {\textcopyright} 2017 WILEY-VCH Verlag GmbH & Co. KGaA, Weinheim",

year = "2018",

month = apr,

day = "1",

doi = "10.1002/adsu.201700113",

language = "English",

volume = "2",

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Hong, T, Lai, S, Mahurin, SM, Cao, PF, Voylov, DN, Meyer, HM, Jacobs, CB, Carrillo, JMY, Kisliuk, A, Ivanov, IN, Jiang, DE, Long, BK, Mays, JW, Sokolov, AP & Saito, T 2018, 'Highly Permeable Oligo(ethylene oxide)-co-poly(dimethylsiloxane) Membranes for Carbon Dioxide Separation', Advanced Sustainable Systems, vol. 2, no. 4, 1700113. https://doi.org/10.1002/adsu.201700113

TY - JOUR

T1 - Highly Permeable Oligo(ethylene oxide)-co-poly(dimethylsiloxane) Membranes for Carbon Dioxide Separation

AU - Hong, Tao

AU - Lai, Sophia

AU - Mahurin, Shannon M.

AU - Cao, Peng Fei

AU - Voylov, Dmitry N.

AU - Meyer, Harry M.

AU - Jacobs, Christopher B.

AU - Carrillo, Jan Michael Y.

AU - Kisliuk, Alexander

AU - Ivanov, Ilia N.

AU - Jiang, De en

AU - Long, Brian K.

AU - Mays, Jimmy W.

AU - Sokolov, Alexei P.

AU - Saito, Tomonori

PY - 2018/4/1

Y1 - 2018/4/1

N2 - A series of cross-linked, freestanding oligo(ethylene oxide)-co-(polydimethylsiloxane-norbornene) membranes with varied composition is synthesized via in situ ring-opening metathesis polymerization. These membranes show remarkably high CO2 permeabilities (3400 Barrer) and their separation performance approaches the Robeson upper bound. The excellent permeability of these copolymer membranes provides great potential for real-world applications where enormous volumes of gases must be separated. The gas transport properties of these films are found to be directly proportional to oligo(ethylene oxide) content incorporation, which stems from the increased solubility selectivity change within the copolymer matrix. This work provides a systematic study of how gas separation performance in rubbery membranes can be enhanced by tuning the CO2-philicity of their constituent monomeric subunits.

AB - A series of cross-linked, freestanding oligo(ethylene oxide)-co-(polydimethylsiloxane-norbornene) membranes with varied composition is synthesized via in situ ring-opening metathesis polymerization. These membranes show remarkably high CO2 permeabilities (3400 Barrer) and their separation performance approaches the Robeson upper bound. The excellent permeability of these copolymer membranes provides great potential for real-world applications where enormous volumes of gases must be separated. The gas transport properties of these films are found to be directly proportional to oligo(ethylene oxide) content incorporation, which stems from the increased solubility selectivity change within the copolymer matrix. This work provides a systematic study of how gas separation performance in rubbery membranes can be enhanced by tuning the CO2-philicity of their constituent monomeric subunits.

KW - CO-philic

KW - high permeability

KW - membrane gas separation

KW - oligo(ethylene oxide)

KW - polydimethylsiloxane

UR - http://www.scopus.com/inward/record.url?scp=85095665885&partnerID=8YFLogxK

U2 - 10.1002/adsu.201700113

DO - 10.1002/adsu.201700113

M3 - Article

AN - SCOPUS:85095665885

SN - 2366-7486

VL - 2

JO - Advanced Sustainable Systems

JF - Advanced Sustainable Systems

IS - 4

M1 - 1700113

ER -

Highly Permeable Oligo(ethylene oxide)-co-poly(dimethylsiloxane) Membranes for Carbon Dioxide Separation

Abstract

Keywords

UN SDGs

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