High-Temperature Oxidation Study in a Multi-Oxidant Environment Using 18O Tracer

Juho Lehmusto; Anton Ievlev; James Kurley; Bruce A. Pint

doi:10.1007/s11085-024-10323-1

High-Temperature Oxidation Study in a Multi-Oxidant Environment Using ¹⁸O Tracer

Juho Lehmusto, Anton Ievlev, James Kurley, Bruce A. Pint

Research output: Contribution to journal › Article › peer-review

Abstract

The goal of this study was to use ¹⁸O-enriched water to better understand the role of H₂O in high-temperature oxidation. Seven model and three commercial M-Cr and M-Cr-Al alloys were studied in air with 10% of H₂O at 800 °C for 5 h. Oxygen from water vapor was more reactive than oxygen from the air and ¹⁸O enriched at the outermost layers of the formed Cr- and Al-rich oxides. Alloys with Al and/or Ti additions showed signs of internal oxidation but ¹⁸O was not enriched inside the alloy in locations with internal oxidation. Depending on the alloy Al content, the oxide went from Al oxidation beneath a chromia scale to external alumina scale formation.

Original language	English
Pages (from-to)	1-18
Number of pages	18
Journal	High Temperature Corrosion of Materials
Volume	102
Issue number	1
DOIs	https://doi.org/10.1007/s11085-024-10323-1
State	Published - Feb 2025

Funding

The authors would like to thank T. M. Lowe and T. Jordan for their assistance with the experimental work. This work has been carried out within the Research Council of Finland project \u201CInitiation and propagation of high-temperature corrosion reactions in complex oxygen-containing environments\u201D (Decision no. 348963). This research was sponsored by the U.S. Department of Energy, Office of Energy Efficiency and Renewable Energy, Industrial Efficiency and Decarbonization Office, Combined Heat and Power Program. M. Ridley and M. Romedenne provided helpful comments on the manuscript.

Funders	Funder number
U.S. Department of Energy
Industrial Efficiency and Decarbonization Office

Keywords

O-enriched water
High-temperature oxidation
Ni-based alloys
Water vapor

Access to Document

10.1007/s11085-024-10323-1

Cite this

@article{41412c6ad71e436f9a61253847e99a99,

title = "High-Temperature Oxidation Study in a Multi-Oxidant Environment Using 18O Tracer",

abstract = "The goal of this study was to use 18O-enriched water to better understand the role of H2O in high-temperature oxidation. Seven model and three commercial M-Cr and M-Cr-Al alloys were studied in air with 10% of H2O at 800 °C for 5 h. Oxygen from water vapor was more reactive than oxygen from the air and 18O enriched at the outermost layers of the formed Cr- and Al-rich oxides. Alloys with Al and/or Ti additions showed signs of internal oxidation but 18O was not enriched inside the alloy in locations with internal oxidation. Depending on the alloy Al content, the oxide went from Al oxidation beneath a chromia scale to external alumina scale formation.",

keywords = "O-enriched water, High-temperature oxidation, Ni-based alloys, Water vapor",

author = "Juho Lehmusto and Anton Ievlev and James Kurley and Pint, {Bruce A.}",

note = "Publisher Copyright: {\textcopyright} The Author(s) 2024.",

year = "2025",

month = feb,

doi = "10.1007/s11085-024-10323-1",

language = "English",

volume = "102",

pages = "1--18",

journal = "High Temperature Corrosion of Materials",

issn = "2731-8400",

publisher = "Springer",

number = "1",

}

TY - JOUR

T1 - High-Temperature Oxidation Study in a Multi-Oxidant Environment Using 18O Tracer

AU - Lehmusto, Juho

AU - Ievlev, Anton

AU - Kurley, James

AU - Pint, Bruce A.

N1 - Publisher Copyright: © The Author(s) 2024.

PY - 2025/2

Y1 - 2025/2

N2 - The goal of this study was to use 18O-enriched water to better understand the role of H2O in high-temperature oxidation. Seven model and three commercial M-Cr and M-Cr-Al alloys were studied in air with 10% of H2O at 800 °C for 5 h. Oxygen from water vapor was more reactive than oxygen from the air and 18O enriched at the outermost layers of the formed Cr- and Al-rich oxides. Alloys with Al and/or Ti additions showed signs of internal oxidation but 18O was not enriched inside the alloy in locations with internal oxidation. Depending on the alloy Al content, the oxide went from Al oxidation beneath a chromia scale to external alumina scale formation.

AB - The goal of this study was to use 18O-enriched water to better understand the role of H2O in high-temperature oxidation. Seven model and three commercial M-Cr and M-Cr-Al alloys were studied in air with 10% of H2O at 800 °C for 5 h. Oxygen from water vapor was more reactive than oxygen from the air and 18O enriched at the outermost layers of the formed Cr- and Al-rich oxides. Alloys with Al and/or Ti additions showed signs of internal oxidation but 18O was not enriched inside the alloy in locations with internal oxidation. Depending on the alloy Al content, the oxide went from Al oxidation beneath a chromia scale to external alumina scale formation.

KW - O-enriched water

KW - High-temperature oxidation

KW - Ni-based alloys

KW - Water vapor

UR - http://www.scopus.com/inward/record.url?scp=85210511682&partnerID=8YFLogxK

U2 - 10.1007/s11085-024-10323-1

DO - 10.1007/s11085-024-10323-1

M3 - Article

AN - SCOPUS:85210511682

SN - 2731-8400

VL - 102

SP - 1

EP - 18

JO - High Temperature Corrosion of Materials

JF - High Temperature Corrosion of Materials

IS - 1

ER -