High-Pressure, High-Temperature Synthesis and Characterization of Polar and Magnetic LuCrWO6

Sun Woo Kim; Xiaoyan Tan; Corey E. Frank; Zheng Deng; Huaiyu Wang; Liam Collins; Saul H. Lapidus; Changqing Jin; Venkatraman Gopalan; Sergei V. Kalinin; David Walker; Martha Greenblatt

doi:10.1021/acs.inorgchem.9b02900

High-Pressure, High-Temperature Synthesis and Characterization of Polar and Magnetic LuCrWO₆

Sun Woo Kim, Xiaoyan Tan, Corey E. Frank, Zheng Deng, Huaiyu Wang, Liam Collins, Saul H. Lapidus, Changqing Jin, Venkatraman Gopalan, Sergei V. Kalinin, David Walker, Martha Greenblatt

Functional Atomic Force Microscopy Group

Research output: Contribution to journal › Article › peer-review

9 Scopus citations

Abstract

A new polar and magnetic oxide, LuCrWO₆, was synthesized under high pressure (6 GPa) and high temperature (1673 K). LuCrWO₆ is isostructural with the previously reported polar YCrWO₆ (SG: Pna2₁, no. 33). The ordering of CrO₆ and WO₆ octahedra in the edge-shared dimers induce the polar structure. The effective size of rare earth, Ln cation does not seem to affect the symmetry of LnCrWO₆. Second harmonic generation measurements of LuCrWO₆ confirmed the noncentrosymmetric character and strong piezoelectric domains are observed from piezoresponse force microscopy at room temperature. LuCrWO₆ exhibits antiferromagnetic behavior, T_N, of ∼18 K with a Weiss temperature of -30.7 K.

Original language	English
Pages (from-to)	3579-3584
Number of pages	6
Journal	Inorganic Chemistry
Volume	59
Issue number	6
DOIs	https://doi.org/10.1021/acs.inorgchem.9b02900
State	Published - Mar 16 2020

Funding

S.W.K. gratefully acknowledges support from the National Research Foundation of Korea (NRF) funded by the Ministry of Science and ICT (2018R1C1B5085301). The work at Rutgers was supported by the US NSF-DMR-1507252 grant. H.W. and V.G. acknowledge funding from NSF grant DMR-1729338 and the Penn State NSF-MRSEC Center for Nanoscale Science grant no. DMR-1420620. The use of the Advanced Photon Source at the Argonne National Laboratory was supported by the U. S. Department of Energy, Office of Science, Office of Basic Sciences, under Contact no. DE-AC02-06CH11357.

Funders	Funder number
Office of Basic Sciences	DE-AC02-06CH11357
Penn State NSF-MRSEC Center for Nanoscale Science	DMR-1420620
US NSF-DMR-1507252
National Science Foundation	DMR-1729338
U.S. Department of Energy
Office of Science
Ministry of Science, ICT and Future Planning	2018R1C1B5085301
National Research Foundation of Korea

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title = "High-Pressure, High-Temperature Synthesis and Characterization of Polar and Magnetic LuCrWO6 ",

abstract = "A new polar and magnetic oxide, LuCrWO6, was synthesized under high pressure (6 GPa) and high temperature (1673 K). LuCrWO6 is isostructural with the previously reported polar YCrWO6 (SG: Pna21, no. 33). The ordering of CrO6 and WO6 octahedra in the edge-shared dimers induce the polar structure. The effective size of rare earth, Ln cation does not seem to affect the symmetry of LnCrWO6. Second harmonic generation measurements of LuCrWO6 confirmed the noncentrosymmetric character and strong piezoelectric domains are observed from piezoresponse force microscopy at room temperature. LuCrWO6 exhibits antiferromagnetic behavior, TN, of ∼18 K with a Weiss temperature of -30.7 K.",

author = "Kim, {Sun Woo} and Xiaoyan Tan and Frank, {Corey E.} and Zheng Deng and Huaiyu Wang and Liam Collins and Lapidus, {Saul H.} and Changqing Jin and Venkatraman Gopalan and Kalinin, {Sergei V.} and David Walker and Martha Greenblatt",

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doi = "10.1021/acs.inorgchem.9b02900",

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T1 - High-Pressure, High-Temperature Synthesis and Characterization of Polar and Magnetic LuCrWO6

AU - Kim, Sun Woo

AU - Tan, Xiaoyan

AU - Frank, Corey E.

AU - Deng, Zheng

AU - Wang, Huaiyu

AU - Collins, Liam

AU - Lapidus, Saul H.

AU - Jin, Changqing

AU - Gopalan, Venkatraman

AU - Kalinin, Sergei V.

AU - Walker, David

AU - Greenblatt, Martha

PY - 2020/3/16

Y1 - 2020/3/16

N2 - A new polar and magnetic oxide, LuCrWO6, was synthesized under high pressure (6 GPa) and high temperature (1673 K). LuCrWO6 is isostructural with the previously reported polar YCrWO6 (SG: Pna21, no. 33). The ordering of CrO6 and WO6 octahedra in the edge-shared dimers induce the polar structure. The effective size of rare earth, Ln cation does not seem to affect the symmetry of LnCrWO6. Second harmonic generation measurements of LuCrWO6 confirmed the noncentrosymmetric character and strong piezoelectric domains are observed from piezoresponse force microscopy at room temperature. LuCrWO6 exhibits antiferromagnetic behavior, TN, of ∼18 K with a Weiss temperature of -30.7 K.

AB - A new polar and magnetic oxide, LuCrWO6, was synthesized under high pressure (6 GPa) and high temperature (1673 K). LuCrWO6 is isostructural with the previously reported polar YCrWO6 (SG: Pna21, no. 33). The ordering of CrO6 and WO6 octahedra in the edge-shared dimers induce the polar structure. The effective size of rare earth, Ln cation does not seem to affect the symmetry of LnCrWO6. Second harmonic generation measurements of LuCrWO6 confirmed the noncentrosymmetric character and strong piezoelectric domains are observed from piezoresponse force microscopy at room temperature. LuCrWO6 exhibits antiferromagnetic behavior, TN, of ∼18 K with a Weiss temperature of -30.7 K.

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SN - 0020-1669

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SP - 3579

EP - 3584

JO - Inorganic Chemistry

JF - Inorganic Chemistry

IS - 6

ER -

High-Pressure, High-Temperature Synthesis and Characterization of Polar and Magnetic LuCrWO₆

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