High-energy and high-power Li-rich nickel manganese oxide electrode materials

Donghan Kim; Sun Ho Kang; Mahalingam Balasubramanian; Christopher S. Johnson

doi:10.1016/j.elecom.2010.09.009

High-energy and high-power Li-rich nickel manganese oxide electrode materials

Donghan Kim
, Sun Ho Kang
, Mahalingam Balasubramanian
, Christopher S. Johnson

Emerging and Solid-State Batteries

Research output: Contribution to journal › Article › peer-review

99 Scopus citations

Abstract

A lithium-rich nickel-manganese oxide compound Li_x(Ni _0.25Mn_0.75)O_y (x > 1) was synthesized from layered Na_0.9Li_0.3Ni_0.25Mn_0.75O _δ precursor using a lithium ion-exchange reaction. The electrochemical behavior of the material as a cathode for lithium batteries, and a preliminary discussion of its structure are reported. The product Li _1.32Na_0.02Ni_0.25Mn_0.75O_y (IE-LNMO) shows broad X-ray diffraction peaks, but possesses a high intensity sharp (003) layering peak and multiple peaks with intensity in the 20-23° 2θ region which suggest Ni-Mn ordering in the transition metal layer (TM). Li/IE-LNMO cells demonstrate very stable reversible capacities of 220 mAh/g @ 15 mA/g and possess extremely high power of 150 mAh/g @ 1500 mA/g (15C). The Li/IE-LNMO cell dQ/dV plot exhibits three reversible electrochemical processes due to Ni/Mn redox behavior in a layered component, and Mn redox exchange in a spinel component. No alteration in the dQ/dV curves and no detectable change in the voltage profiles over 40 cycles were observed, thus indicating a stable structure for lithium insertion/extraction. This new material is attractive for demanding Li-ion battery applications.

Original language	English
Pages (from-to)	1618-1621
Number of pages	4
Journal	Electrochemistry Communications
Volume	12
Issue number	11
DOIs	https://doi.org/10.1016/j.elecom.2010.09.009
State	Published - Nov 2010

Funding

Financial support from the Office of Vehicle Technologies of the U.S. Department of Energy under Contract DE-AC02-06CH11357 is gratefully acknowledged. Work at PNC/XSD facilities at the Advanced Photon Source, and research at these facilities, are supported by the USDOE-Basic Energy Sciences, NSERC-Canada and its founding institutions. The submitted manuscript has been created by UChicago Argonne, LLC, Operator of Argonne National Laboratory (“Argonne”). Argonne, a U.S. Department of Energy Office of Science laboratory, is operated under Contract No. DE-AC02-06CH11357. The U.S. Government retains for itself, and others acting on its behalf, a paid-up, nonexclusive, irrevocable worldwide license in said article to reproduce, prepare derivative works, distribute copies to the public, and perform publicly and display publicly, by or on behalf of the Government.

Keywords

Ion exchange
Lithium batteries
Oxides
Sodium

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10.1016/j.elecom.2010.09.009

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title = "High-energy and high-power Li-rich nickel manganese oxide electrode materials",

abstract = "A lithium-rich nickel-manganese oxide compound Lix(Ni 0.25Mn0.75)Oy (x > 1) was synthesized from layered Na0.9Li0.3Ni0.25Mn0.75O δ precursor using a lithium ion-exchange reaction. The electrochemical behavior of the material as a cathode for lithium batteries, and a preliminary discussion of its structure are reported. The product Li 1.32Na0.02Ni0.25Mn0.75Oy (IE-LNMO) shows broad X-ray diffraction peaks, but possesses a high intensity sharp (003) layering peak and multiple peaks with intensity in the 20-23° 2θ region which suggest Ni-Mn ordering in the transition metal layer (TM). Li/IE-LNMO cells demonstrate very stable reversible capacities of 220 mAh/g @ 15 mA/g and possess extremely high power of 150 mAh/g @ 1500 mA/g (15C). The Li/IE-LNMO cell dQ/dV plot exhibits three reversible electrochemical processes due to Ni/Mn redox behavior in a layered component, and Mn redox exchange in a spinel component. No alteration in the dQ/dV curves and no detectable change in the voltage profiles over 40 cycles were observed, thus indicating a stable structure for lithium insertion/extraction. This new material is attractive for demanding Li-ion battery applications.",

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author = "Donghan Kim and Kang, \{Sun Ho\} and Mahalingam Balasubramanian and Johnson, \{Christopher S.\}",

year = "2010",

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doi = "10.1016/j.elecom.2010.09.009",

language = "English",

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T1 - High-energy and high-power Li-rich nickel manganese oxide electrode materials

AU - Kim, Donghan

AU - Kang, Sun Ho

AU - Balasubramanian, Mahalingam

AU - Johnson, Christopher S.

PY - 2010/11

Y1 - 2010/11

N2 - A lithium-rich nickel-manganese oxide compound Lix(Ni 0.25Mn0.75)Oy (x > 1) was synthesized from layered Na0.9Li0.3Ni0.25Mn0.75O δ precursor using a lithium ion-exchange reaction. The electrochemical behavior of the material as a cathode for lithium batteries, and a preliminary discussion of its structure are reported. The product Li 1.32Na0.02Ni0.25Mn0.75Oy (IE-LNMO) shows broad X-ray diffraction peaks, but possesses a high intensity sharp (003) layering peak and multiple peaks with intensity in the 20-23° 2θ region which suggest Ni-Mn ordering in the transition metal layer (TM). Li/IE-LNMO cells demonstrate very stable reversible capacities of 220 mAh/g @ 15 mA/g and possess extremely high power of 150 mAh/g @ 1500 mA/g (15C). The Li/IE-LNMO cell dQ/dV plot exhibits three reversible electrochemical processes due to Ni/Mn redox behavior in a layered component, and Mn redox exchange in a spinel component. No alteration in the dQ/dV curves and no detectable change in the voltage profiles over 40 cycles were observed, thus indicating a stable structure for lithium insertion/extraction. This new material is attractive for demanding Li-ion battery applications.

AB - A lithium-rich nickel-manganese oxide compound Lix(Ni 0.25Mn0.75)Oy (x > 1) was synthesized from layered Na0.9Li0.3Ni0.25Mn0.75O δ precursor using a lithium ion-exchange reaction. The electrochemical behavior of the material as a cathode for lithium batteries, and a preliminary discussion of its structure are reported. The product Li 1.32Na0.02Ni0.25Mn0.75Oy (IE-LNMO) shows broad X-ray diffraction peaks, but possesses a high intensity sharp (003) layering peak and multiple peaks with intensity in the 20-23° 2θ region which suggest Ni-Mn ordering in the transition metal layer (TM). Li/IE-LNMO cells demonstrate very stable reversible capacities of 220 mAh/g @ 15 mA/g and possess extremely high power of 150 mAh/g @ 1500 mA/g (15C). The Li/IE-LNMO cell dQ/dV plot exhibits three reversible electrochemical processes due to Ni/Mn redox behavior in a layered component, and Mn redox exchange in a spinel component. No alteration in the dQ/dV curves and no detectable change in the voltage profiles over 40 cycles were observed, thus indicating a stable structure for lithium insertion/extraction. This new material is attractive for demanding Li-ion battery applications.

KW - Ion exchange

KW - Lithium batteries

KW - Oxides

KW - Sodium

UR - https://www.scopus.com/pages/publications/78049256791

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DO - 10.1016/j.elecom.2010.09.009

M3 - Article

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EP - 1621

JO - Electrochemistry Communications

JF - Electrochemistry Communications

IS - 11

ER -

High-energy and high-power Li-rich nickel manganese oxide electrode materials

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