Abstract
The exploration of new high-dielectric materials is crucial for the advancement of modern electronic applications. Most previous research on high dielectrics has been limited to oxides. Here, the structures of nitrides SrHfN2 and SrZrN2 were investigated by neutron powder diffraction, which confirmed their α-NaFeO2-type layered structure without showing apparent preferences of octahedral distortion or polar structure. The SrHfN2 and SrZrN2 ceramics were found to possess high dielectric permittivities (εr) of approximately 290−650 at 106 Hz from 5 to 280 K. Impedance spectroscopy measurements indicate the ceramics could contain conducting grains and less conducting grain boundary regions with extremely small activation energies, inducing the internal barrier capacitance effect and therefore extrinsically high dielectric permittivities. Density functional theory calculations indicate that both SrHfN2 and SrZrN2 are semiconductors with ∼ 1.0 eV band gaps and possess high bulk εr values of 280 and 470, respectively. The exceptionally high εr values of these layered nitrides originate from the anisotropic and large ionic polarization within the a−b plane due to the low-frequency infrared active phonon modes concomitant with a large mode effective charge. Our study not only sheds light on the potential of high-εr materials but also provides a reference for the study of the dielectric mechanism of layered nitrides.
Original language | English |
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Pages (from-to) | 4505-4513 |
Number of pages | 9 |
Journal | Chemistry of Materials |
Volume | 34 |
Issue number | 10 |
DOIs | |
State | Published - May 24 2022 |
Funding
The National Natural Science Foundation of China (21875049 and 11864008) and the Guangxi Natural Science Foundation (2019GXNSFGA245006, 2018GXNSFDA281015, and 2018AD19200) are acknowledged for their financial support. The computational work was carried out at Shanxi Supercomputing Center, and the calculations were performed on TianHe-2.
Funders | Funder number |
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National Natural Science Foundation of China | 21875049, 11864008 |
Natural Science Foundation of Guangxi Province | 2019GXNSFGA245006, 2018AD19200, 2018GXNSFDA281015 |