High capacity ammonia adsorption in a robust metal–organic framework mediated by reversible host–guest interactions

Lixia Guo; Xue Han; Yujie Ma; Jiangnan Li; Wanpeng Lu; Weiyao Li; Daniel Lee; Ivan da Silva; Yongqiang Cheng; Svemir Rudić; Pascal Manuel; Mark D. Frogley; Anibal J. Ramirez-Cuesta; Martin Schröder; Sihai Yang

doi:10.1039/d2cc01197b

High capacity ammonia adsorption in a robust metal–organic framework mediated by reversible host–guest interactions

Lixia Guo
, Xue Han
, Yujie Ma
, Jiangnan Li
, Wanpeng Lu
, Weiyao Li
, Daniel Lee
, Ivan da Silva
, Yongqiang Cheng
, Svemir Rudić
, Pascal Manuel
, Mark D. Frogley
, Anibal J. Ramirez-Cuesta
, Martin Schröder
, Sihai Yang

Chemical Spectroscopy

Research output: Contribution to journal › Article › peer-review

26 Scopus citations

Abstract

To understand the exceptional adsorption of ammonia (NH₃) in MFM-300(Sc) (19.5 mmol g⁻¹ at 273 K and 1 bar without hysteresis), we report a systematic investigation of the mechanism of adsorption by a combination of in situ neutron powder diffraction, inelastic neutron scattering, synchrotron infrared microspectroscopy, and solid-state ⁴⁵Sc NMR spectroscopy. These complementary techniques reveal the formation of reversible host–guest supramolecular interactions, which explains directly the observed excellent reversibility of this material over 90 adsorption–desorption cycles.

Original language	English
Pages (from-to)	5753-5756
Number of pages	4
Journal	Chemical Communications
Volume	58
Issue number	38
DOIs	https://doi.org/10.1039/d2cc01197b
State	Published - May 11 2022

Access to Document

10.1039/d2cc01197b

Cite this

Guo, L., Han, X., Ma, Y., Li, J., Lu, W., Li, W., Lee, D., da Silva, I., Cheng, Y., Rudić, S., Manuel, P., Frogley, M. D., Ramirez-Cuesta, A. J., Schröder, M., & Yang, S. (2022). High capacity ammonia adsorption in a robust metal–organic framework mediated by reversible host–guest interactions. Chemical Communications, 58(38), 5753-5756. https://doi.org/10.1039/d2cc01197b

@article{c0b92d1e1ce9446cacf4846685ef05e2,

title = "High capacity ammonia adsorption in a robust metal–organic framework mediated by reversible host–guest interactions",

abstract = "To understand the exceptional adsorption of ammonia (NH3) in MFM-300(Sc) (19.5 mmol g−1 at 273 K and 1 bar without hysteresis), we report a systematic investigation of the mechanism of adsorption by a combination of in situ neutron powder diffraction, inelastic neutron scattering, synchrotron infrared microspectroscopy, and solid-state 45Sc NMR spectroscopy. These complementary techniques reveal the formation of reversible host–guest supramolecular interactions, which explains directly the observed excellent reversibility of this material over 90 adsorption–desorption cycles.",

author = "Lixia Guo and Xue Han and Yujie Ma and Jiangnan Li and Wanpeng Lu and Weiyao Li and Daniel Lee and \{da Silva\}, Ivan and Yongqiang Cheng and Svemir Rudi{\'c} and Pascal Manuel and Frogley, \{Mark D.\} and Ramirez-Cuesta, \{Anibal J.\} and Martin Schr{\"o}der and Sihai Yang",

note = "Publisher Copyright: This journal is {\textcopyright} The Royal Society of Chemistry, 2022",

year = "2022",

month = may,

day = "11",

doi = "10.1039/d2cc01197b",

language = "English",

volume = "58",

pages = "5753--5756",

journal = "Chemical Communications",

issn = "1359-7345",

publisher = "Royal Society of Chemistry",

number = "38",

}

Guo, L, Han, X, Ma, Y, Li, J, Lu, W, Li, W, Lee, D, da Silva, I, Cheng, Y, Rudić, S, Manuel, P, Frogley, MD, Ramirez-Cuesta, AJ, Schröder, M & Yang, S 2022, 'High capacity ammonia adsorption in a robust metal–organic framework mediated by reversible host–guest interactions', Chemical Communications, vol. 58, no. 38, pp. 5753-5756. https://doi.org/10.1039/d2cc01197b

TY - JOUR

T1 - High capacity ammonia adsorption in a robust metal–organic framework mediated by reversible host–guest interactions

AU - Guo, Lixia

AU - Han, Xue

AU - Ma, Yujie

AU - Li, Jiangnan

AU - Lu, Wanpeng

AU - Li, Weiyao

AU - Lee, Daniel

AU - da Silva, Ivan

AU - Cheng, Yongqiang

AU - Rudić, Svemir

AU - Manuel, Pascal

AU - Frogley, Mark D.

AU - Ramirez-Cuesta, Anibal J.

AU - Schröder, Martin

AU - Yang, Sihai

PY - 2022/5/11

Y1 - 2022/5/11

N2 - To understand the exceptional adsorption of ammonia (NH3) in MFM-300(Sc) (19.5 mmol g−1 at 273 K and 1 bar without hysteresis), we report a systematic investigation of the mechanism of adsorption by a combination of in situ neutron powder diffraction, inelastic neutron scattering, synchrotron infrared microspectroscopy, and solid-state 45Sc NMR spectroscopy. These complementary techniques reveal the formation of reversible host–guest supramolecular interactions, which explains directly the observed excellent reversibility of this material over 90 adsorption–desorption cycles.

AB - To understand the exceptional adsorption of ammonia (NH3) in MFM-300(Sc) (19.5 mmol g−1 at 273 K and 1 bar without hysteresis), we report a systematic investigation of the mechanism of adsorption by a combination of in situ neutron powder diffraction, inelastic neutron scattering, synchrotron infrared microspectroscopy, and solid-state 45Sc NMR spectroscopy. These complementary techniques reveal the formation of reversible host–guest supramolecular interactions, which explains directly the observed excellent reversibility of this material over 90 adsorption–desorption cycles.

UR - https://www.scopus.com/pages/publications/85129720554

U2 - 10.1039/d2cc01197b

DO - 10.1039/d2cc01197b

M3 - Article

C2 - 35446330

AN - SCOPUS:85129720554

SN - 1359-7345

VL - 58

SP - 5753

EP - 5756

JO - Chemical Communications

JF - Chemical Communications

IS - 38

ER -

High capacity ammonia adsorption in a robust metal–organic framework mediated by reversible host–guest interactions

Abstract

Access to Document

Other files and links

Fingerprint

Cite this