High capacity ammonia adsorption in a robust metal-organic framework mediated by reversible host-guest interactions

Lixia Guo; Xue Han; Yujie Ma; Jiangnan Li; Wanpeng Lu; Weiyao Li; Daniel Lee; Ivan da Silva; Yongqiang Cheng; Svemir Rudić; Pascal Manuel; Mark D. Frogley; Anibal J. Ramirez-Cuesta; Martin Schröder; Sihai Yang

doi:10.1039/d2cc01197b

High capacity ammonia adsorption in a robust metal-organic framework mediated by reversible host-guest interactions

Lixia Guo, Xue Han, Yujie Ma, Jiangnan Li, Wanpeng Lu, Weiyao Li, Daniel Lee, Ivan da Silva, Yongqiang Cheng, Svemir Rudić, Pascal Manuel, Mark D. Frogley, Anibal J. Ramirez-Cuesta, Martin Schröder, Sihai Yang

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11 Scopus citations

Abstract

To understand the exceptional adsorption of ammonia (NH₃) in MFM-300(Sc) (19.5 mmol g⁻¹ at 273 K and 1 bar without hysteresis), we report a systematic investigation of the mechanism of adsorption by a combination of in situ neutron powder diffraction, inelastic neutron scattering, synchrotron infrared microspectroscopy, and solid-state ⁴⁵Sc NMR spectroscopy. These complementary techniques reveal the formation of reversible host-guest supramolecular interactions, which explains directly the observed excellent reversibility of this material over 90 adsorption-desorption cycles.

Original language	English
Journal	Chemical Communications
DOIs	https://doi.org/10.1039/d2cc01197b
State	Accepted/In press - 2022

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10.1039/d2cc01197b

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Guo, L., Han, X., Ma, Y., Li, J., Lu, W., Li, W., Lee, D., da Silva, I., Cheng, Y., Rudić, S., Manuel, P., Frogley, M. D., Ramirez-Cuesta, A. J., Schröder, M., & Yang, S. (Accepted/In press). High capacity ammonia adsorption in a robust metal-organic framework mediated by reversible host-guest interactions. Chemical Communications. https://doi.org/10.1039/d2cc01197b

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title = "High capacity ammonia adsorption in a robust metal-organic framework mediated by reversible host-guest interactions",

abstract = "To understand the exceptional adsorption of ammonia (NH3) in MFM-300(Sc) (19.5 mmol g−1 at 273 K and 1 bar without hysteresis), we report a systematic investigation of the mechanism of adsorption by a combination of in situ neutron powder diffraction, inelastic neutron scattering, synchrotron infrared microspectroscopy, and solid-state 45Sc NMR spectroscopy. These complementary techniques reveal the formation of reversible host-guest supramolecular interactions, which explains directly the observed excellent reversibility of this material over 90 adsorption-desorption cycles.",

author = "Lixia Guo and Xue Han and Yujie Ma and Jiangnan Li and Wanpeng Lu and Weiyao Li and Daniel Lee and {da Silva}, Ivan and Yongqiang Cheng and Svemir Rudi{\'c} and Pascal Manuel and Frogley, {Mark D.} and Ramirez-Cuesta, {Anibal J.} and Martin Schr{\"o}der and Sihai Yang",

note = "Publisher Copyright: {\textcopyright} 2022 The Royal Society of Chemistry.",

year = "2022",

doi = "10.1039/d2cc01197b",

language = "English",

journal = "Chemical Communications",

issn = "1359-7345",

publisher = "Royal Society of Chemistry",

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TY - JOUR

T1 - High capacity ammonia adsorption in a robust metal-organic framework mediated by reversible host-guest interactions

AU - Guo, Lixia

AU - Han, Xue

AU - Ma, Yujie

AU - Li, Jiangnan

AU - Lu, Wanpeng

AU - Li, Weiyao

AU - Lee, Daniel

AU - da Silva, Ivan

AU - Cheng, Yongqiang

AU - Rudić, Svemir

AU - Manuel, Pascal

AU - Frogley, Mark D.

AU - Ramirez-Cuesta, Anibal J.

AU - Schröder, Martin

AU - Yang, Sihai

PY - 2022

Y1 - 2022

N2 - To understand the exceptional adsorption of ammonia (NH3) in MFM-300(Sc) (19.5 mmol g−1 at 273 K and 1 bar without hysteresis), we report a systematic investigation of the mechanism of adsorption by a combination of in situ neutron powder diffraction, inelastic neutron scattering, synchrotron infrared microspectroscopy, and solid-state 45Sc NMR spectroscopy. These complementary techniques reveal the formation of reversible host-guest supramolecular interactions, which explains directly the observed excellent reversibility of this material over 90 adsorption-desorption cycles.

AB - To understand the exceptional adsorption of ammonia (NH3) in MFM-300(Sc) (19.5 mmol g−1 at 273 K and 1 bar without hysteresis), we report a systematic investigation of the mechanism of adsorption by a combination of in situ neutron powder diffraction, inelastic neutron scattering, synchrotron infrared microspectroscopy, and solid-state 45Sc NMR spectroscopy. These complementary techniques reveal the formation of reversible host-guest supramolecular interactions, which explains directly the observed excellent reversibility of this material over 90 adsorption-desorption cycles.

UR - http://www.scopus.com/inward/record.url?scp=85129720554&partnerID=8YFLogxK

U2 - 10.1039/d2cc01197b

DO - 10.1039/d2cc01197b

M3 - Article

C2 - 35446330

AN - SCOPUS:85129720554

SN - 1359-7345

JO - Chemical Communications

JF - Chemical Communications

ER -

High capacity ammonia adsorption in a robust metal-organic framework mediated by reversible host-guest interactions

Abstract

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