Guest-controlled incommensurate modulation in a meta-rigid metal-organic framework material

Jiangnan Li; Zhengyang Zhou; Xue Han; Xinran Zhang; Yong Yan; Weiyao Li; Gemma L. Smith; Yongqiang Cheng; Laura J. McCormick McPherson; Simon J. Teat; Mark D. Frogley; Svemir Rudić; Anibal J. Ramirez-Cuesta; Alexander J. Blake; Junliang Sun; Martin Schröder; Sihai Yang

doi:10.1021/jacs.0c08794

Guest-controlled incommensurate modulation in a meta-rigid metal-organic framework material

Jiangnan Li, Zhengyang Zhou, Xue Han, Xinran Zhang, Yong Yan, Weiyao Li, Gemma L. Smith, Yongqiang Cheng, Laura J. McCormick McPherson, Simon J. Teat, Mark D. Frogley, Svemir Rudić, Anibal J. Ramirez-Cuesta, Alexander J. Blake, Junliang Sun, Martin Schröder, Sihai Yang

Research output: Contribution to journal › Article › peer-review

24 Scopus citations

Abstract

Structural transitions of host systems in response to guest binding dominate many chemical processes. We report an unprecedented type of structural flexibility within a meta-rigid material, MFM-520, which exhibits a reversible periodic-to-aperiodic structural transition resulting from a drastic distortion of a [ZnO4N] node controlled by the specific host-guest interactions. The aperiodic crystal structure of MFM-520 has no three-dimensional (3D) lattice periodicity but shows translational symmetry in higher-dimensional (3 + 2)D space. We have directly visualized the aperiodic state which is induced by incommensurate modulation of the periodic framework of MFM-520·H2O upon dehydration to give MFM-520. Filling MFM-520 with CO2 and SO2 reveals that, while CO2 has a minimal structural influence, SO2 can further modulate the structure incommensurately. MFM-520 shows exceptional selectivity for SO2 under flue-gas desulfurization conditions, and the facile release of captured SO2 from MFM-520 enabled the conversion to valuable sulfonamide products. MFM-520 can thus be used as a highly efficient capture and delivery system for SO2.

Original language	English
Pages (from-to)	19189-19197
Number of pages	9
Journal	Journal of the American Chemical Society
Volume	142
Issue number	45
DOIs	https://doi.org/10.1021/jacs.0c08794
State	Published - Nov 11 2020

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Li, J., Zhou, Z., Han, X., Zhang, X., Yan, Y., Li, W., Smith, G. L., Cheng, Y., McCormick McPherson, L. J., Teat, S. J., Frogley, M. D., Rudić, S., Ramirez-Cuesta, A. J., Blake, A. J., Sun, J., Schröder, M., & Yang, S. (2020). Guest-controlled incommensurate modulation in a meta-rigid metal-organic framework material. Journal of the American Chemical Society, 142(45), 19189-19197. https://doi.org/10.1021/jacs.0c08794

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title = "Guest-controlled incommensurate modulation in a meta-rigid metal-organic framework material",

abstract = "Structural transitions of host systems in response to guest binding dominate many chemical processes. We report an unprecedented type of structural flexibility within a meta-rigid material, MFM-520, which exhibits a reversible periodic-to-aperiodic structural transition resulting from a drastic distortion of a [ZnO4N] node controlled by the specific host-guest interactions. The aperiodic crystal structure of MFM-520 has no three-dimensional (3D) lattice periodicity but shows translational symmetry in higher-dimensional (3 + 2)D space. We have directly visualized the aperiodic state which is induced by incommensurate modulation of the periodic framework of MFM-520·H2O upon dehydration to give MFM-520. Filling MFM-520 with CO2 and SO2 reveals that, while CO2 has a minimal structural influence, SO2 can further modulate the structure incommensurately. MFM-520 shows exceptional selectivity for SO2 under flue-gas desulfurization conditions, and the facile release of captured SO2 from MFM-520 enabled the conversion to valuable sulfonamide products. MFM-520 can thus be used as a highly efficient capture and delivery system for SO2.",

author = "Jiangnan Li and Zhengyang Zhou and Xue Han and Xinran Zhang and Yong Yan and Weiyao Li and Smith, {Gemma L.} and Yongqiang Cheng and {McCormick McPherson}, {Laura J.} and Teat, {Simon J.} and Frogley, {Mark D.} and Svemir Rudi{\'c} and Ramirez-Cuesta, {Anibal J.} and Blake, {Alexander J.} and Junliang Sun and Martin Schr{\"o}der and Sihai Yang",

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year = "2020",

month = nov,

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doi = "10.1021/jacs.0c08794",

language = "English",

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Li, J, Zhou, Z, Han, X, Zhang, X, Yan, Y, Li, W, Smith, GL, Cheng, Y, McCormick McPherson, LJ, Teat, SJ, Frogley, MD, Rudić, S, Ramirez-Cuesta, AJ, Blake, AJ, Sun, J, Schröder, M & Yang, S 2020, 'Guest-controlled incommensurate modulation in a meta-rigid metal-organic framework material', Journal of the American Chemical Society, vol. 142, no. 45, pp. 19189-19197. https://doi.org/10.1021/jacs.0c08794

TY - JOUR

T1 - Guest-controlled incommensurate modulation in a meta-rigid metal-organic framework material

AU - Li, Jiangnan

AU - Zhou, Zhengyang

AU - Han, Xue

AU - Zhang, Xinran

AU - Yan, Yong

AU - Li, Weiyao

AU - Smith, Gemma L.

AU - Cheng, Yongqiang

AU - McCormick McPherson, Laura J.

AU - Teat, Simon J.

AU - Frogley, Mark D.

AU - Rudić, Svemir

AU - Ramirez-Cuesta, Anibal J.

AU - Blake, Alexander J.

AU - Sun, Junliang

AU - Schröder, Martin

AU - Yang, Sihai

PY - 2020/11/11

Y1 - 2020/11/11

N2 - Structural transitions of host systems in response to guest binding dominate many chemical processes. We report an unprecedented type of structural flexibility within a meta-rigid material, MFM-520, which exhibits a reversible periodic-to-aperiodic structural transition resulting from a drastic distortion of a [ZnO4N] node controlled by the specific host-guest interactions. The aperiodic crystal structure of MFM-520 has no three-dimensional (3D) lattice periodicity but shows translational symmetry in higher-dimensional (3 + 2)D space. We have directly visualized the aperiodic state which is induced by incommensurate modulation of the periodic framework of MFM-520·H2O upon dehydration to give MFM-520. Filling MFM-520 with CO2 and SO2 reveals that, while CO2 has a minimal structural influence, SO2 can further modulate the structure incommensurately. MFM-520 shows exceptional selectivity for SO2 under flue-gas desulfurization conditions, and the facile release of captured SO2 from MFM-520 enabled the conversion to valuable sulfonamide products. MFM-520 can thus be used as a highly efficient capture and delivery system for SO2.

AB - Structural transitions of host systems in response to guest binding dominate many chemical processes. We report an unprecedented type of structural flexibility within a meta-rigid material, MFM-520, which exhibits a reversible periodic-to-aperiodic structural transition resulting from a drastic distortion of a [ZnO4N] node controlled by the specific host-guest interactions. The aperiodic crystal structure of MFM-520 has no three-dimensional (3D) lattice periodicity but shows translational symmetry in higher-dimensional (3 + 2)D space. We have directly visualized the aperiodic state which is induced by incommensurate modulation of the periodic framework of MFM-520·H2O upon dehydration to give MFM-520. Filling MFM-520 with CO2 and SO2 reveals that, while CO2 has a minimal structural influence, SO2 can further modulate the structure incommensurately. MFM-520 shows exceptional selectivity for SO2 under flue-gas desulfurization conditions, and the facile release of captured SO2 from MFM-520 enabled the conversion to valuable sulfonamide products. MFM-520 can thus be used as a highly efficient capture and delivery system for SO2.

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U2 - 10.1021/jacs.0c08794

DO - 10.1021/jacs.0c08794

M3 - Article

C2 - 33124803

AN - SCOPUS:85095842502

SN - 0002-7863

VL - 142

SP - 19189

EP - 19197

JO - Journal of the American Chemical Society

JF - Journal of the American Chemical Society

IS - 45

ER -

Guest-controlled incommensurate modulation in a meta-rigid metal-organic framework material

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