Growth of crystalline polyaminoborane through catalytic dehydrogenation of ammonia borane on FeB nanoalloy

Teng He; Junhu Wang; Guotao Wu; Hyunjeong Kim; Thomas Proffen; Anan Wu; Wen Li; Tao Liu; Zhitao Xiong; Chengzhang Wu; Hailiang Chu; Jianping Guo; Tom Autrey; Tao Zhang; Ping Chen

doi:10.1002/chem.201001844

Growth of crystalline polyaminoborane through catalytic dehydrogenation of ammonia borane on FeB nanoalloy

Teng He, Junhu Wang, Guotao Wu, Hyunjeong Kim, Thomas Proffen, Anan Wu, Wen Li, Tao Liu, Zhitao Xiong, Chengzhang Wu, Hailiang Chu, Jianping Guo, Tom Autrey, Tao Zhang, Ping Chen

Research output: Contribution to journal › Article › peer-review

38 Scopus citations

Abstract

Nano-alloy: Crystalline polyaminoborane is formed upon releasing 1.0 equivalent H₂ from ammonia borane at 60°C catalyzed by a nano-FeB alloy. Our experimental results show that about 1.0 and 1.5equiv H₂ can be released at 60 and 100°C, respectively.

Original language	English
Pages (from-to)	12814-12817
Number of pages	4
Journal	Chemistry - A European Journal
Volume	16
Issue number	43
DOIs	https://doi.org/10.1002/chem.201001844
State	Published - Nov 15 2010
Externally published	Yes

Keywords

alloys
boranes
dehydrogenation
heterogeneous catalysis
nanoalloy

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10.1002/chem.201001844

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title = "Growth of crystalline polyaminoborane through catalytic dehydrogenation of ammonia borane on FeB nanoalloy",

abstract = "Nano-alloy: Crystalline polyaminoborane is formed upon releasing 1.0 equivalent H2 from ammonia borane at 60°C catalyzed by a nano-FeB alloy. Our experimental results show that about 1.0 and 1.5equiv H2 can be released at 60 and 100°C, respectively.",

keywords = "alloys, boranes, dehydrogenation, heterogeneous catalysis, nanoalloy",

author = "Teng He and Junhu Wang and Guotao Wu and Hyunjeong Kim and Thomas Proffen and Anan Wu and Wen Li and Tao Liu and Zhitao Xiong and Chengzhang Wu and Hailiang Chu and Jianping Guo and Tom Autrey and Tao Zhang and Ping Chen",

year = "2010",

month = nov,

day = "15",

doi = "10.1002/chem.201001844",

language = "English",

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journal = "Chemistry - A European Journal",

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TY - JOUR

T1 - Growth of crystalline polyaminoborane through catalytic dehydrogenation of ammonia borane on FeB nanoalloy

AU - He, Teng

AU - Wang, Junhu

AU - Wu, Guotao

AU - Kim, Hyunjeong

AU - Proffen, Thomas

AU - Wu, Anan

AU - Li, Wen

AU - Liu, Tao

AU - Xiong, Zhitao

AU - Wu, Chengzhang

AU - Chu, Hailiang

AU - Guo, Jianping

AU - Autrey, Tom

AU - Zhang, Tao

AU - Chen, Ping

PY - 2010/11/15

Y1 - 2010/11/15

N2 - Nano-alloy: Crystalline polyaminoborane is formed upon releasing 1.0 equivalent H2 from ammonia borane at 60°C catalyzed by a nano-FeB alloy. Our experimental results show that about 1.0 and 1.5equiv H2 can be released at 60 and 100°C, respectively.

AB - Nano-alloy: Crystalline polyaminoborane is formed upon releasing 1.0 equivalent H2 from ammonia borane at 60°C catalyzed by a nano-FeB alloy. Our experimental results show that about 1.0 and 1.5equiv H2 can be released at 60 and 100°C, respectively.

KW - alloys

KW - boranes

KW - dehydrogenation

KW - heterogeneous catalysis

KW - nanoalloy

UR - http://www.scopus.com/inward/record.url?scp=78449285947&partnerID=8YFLogxK

U2 - 10.1002/chem.201001844

DO - 10.1002/chem.201001844

M3 - Article

AN - SCOPUS:78449285947

SN - 0947-6539

VL - 16

SP - 12814

EP - 12817

JO - Chemistry - A European Journal

JF - Chemistry - A European Journal

IS - 43

ER -

Growth of crystalline polyaminoborane through catalytic dehydrogenation of ammonia borane on FeB nanoalloy

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Keywords

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