Green Emitting Single-Crystalline Bulk Assembly of Metal Halide Clusters with Near-Unity Photoluminescence Quantum Efficiency

Chenkun Zhou; Haoran Lin; Jennifer Neu; Yan Zhou; Maya Chaaban; Sujin Lee; Michael Worku; Banghao Chen; Ronald Clark; Wenhao Cheng; Jingjiao Guan; Peter Djurovich; Dongzhou Zhang; Xujie Lü; James Bullock; Chongin Pak; Michael Shatruk; Mao Hua Du; Theo Siegrist; Biwu Ma

doi:10.1021/acsenergylett.9b00991

Green Emitting Single-Crystalline Bulk Assembly of Metal Halide Clusters with Near-Unity Photoluminescence Quantum Efficiency

Chenkun Zhou, Haoran Lin, Jennifer Neu, Yan Zhou, Maya Chaaban, Sujin Lee, Michael Worku, Banghao Chen, Ronald Clark, Wenhao Cheng, Jingjiao Guan, Peter Djurovich, Dongzhou Zhang, Xujie Lü, James Bullock, Chongin Pak, Michael Shatruk, Mao Hua Du, Theo Siegrist, Biwu Ma

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Abstract

Organic metal halide hybrids with zero-dimensional (0D) structure at the molecular level, or single-crystalline bulk assemblies of metal halides, are an emerging class of light-emitting materials with high photoluminescence quantum efficiencies (PLQEs) and color tunability. Here we report the synthesis and characterization of a new single-crystalline bulk assembly of metal halide clusters, (bmpy)₉[ZnCl₄]₂[Pb₃Cl₁₁] (bmpy: 1-butyl-1-methylpyrrolidinium), which exhibits green emission peaked at 512 nm with a remarkable near-unity PLQE at room temperature. Detailed structural and photophysical studies suggest that there are two emitting states in [Pb₃Cl₁₁]^5- clusters, whose populations are strongly dependent on the surrounding molecular environment that controls the excited-state structural distortion of [Pb₃Cl₁₁]^5- clusters. High chemical- and photostability have also been demonstrated in this new material.

Original language	English
Pages (from-to)	1579-1583
Number of pages	5
Journal	ACS Energy Letters
Volume	4
Issue number	7
DOIs	https://doi.org/10.1021/acsenergylett.9b00991
State	Published - Jul 12 2019
Externally published	Yes

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Zhou, C., Lin, H., Neu, J., Zhou, Y., Chaaban, M., Lee, S., Worku, M., Chen, B., Clark, R., Cheng, W., Guan, J., Djurovich, P., Zhang, D., Lü, X., Bullock, J., Pak, C., Shatruk, M., Du, M. H., Siegrist, T., & Ma, B. (2019). Green Emitting Single-Crystalline Bulk Assembly of Metal Halide Clusters with Near-Unity Photoluminescence Quantum Efficiency. ACS Energy Letters, 4(7), 1579-1583. https://doi.org/10.1021/acsenergylett.9b00991

@article{752c563e845b4f2aa0cb0167e599d3c8,

title = "Green Emitting Single-Crystalline Bulk Assembly of Metal Halide Clusters with Near-Unity Photoluminescence Quantum Efficiency",

abstract = "Organic metal halide hybrids with zero-dimensional (0D) structure at the molecular level, or single-crystalline bulk assemblies of metal halides, are an emerging class of light-emitting materials with high photoluminescence quantum efficiencies (PLQEs) and color tunability. Here we report the synthesis and characterization of a new single-crystalline bulk assembly of metal halide clusters, (bmpy)9[ZnCl4]2[Pb3Cl11] (bmpy: 1-butyl-1-methylpyrrolidinium), which exhibits green emission peaked at 512 nm with a remarkable near-unity PLQE at room temperature. Detailed structural and photophysical studies suggest that there are two emitting states in [Pb3Cl11]5- clusters, whose populations are strongly dependent on the surrounding molecular environment that controls the excited-state structural distortion of [Pb3Cl11]5- clusters. High chemical- and photostability have also been demonstrated in this new material.",

author = "Chenkun Zhou and Haoran Lin and Jennifer Neu and Yan Zhou and Maya Chaaban and Sujin Lee and Michael Worku and Banghao Chen and Ronald Clark and Wenhao Cheng and Jingjiao Guan and Peter Djurovich and Dongzhou Zhang and Xujie L{\"u} and James Bullock and Chongin Pak and Michael Shatruk and Du, {Mao Hua} and Theo Siegrist and Biwu Ma",

note = "Publisher Copyright: {\textcopyright} 2019 American Chemical Society.",

year = "2019",

month = jul,

day = "12",

doi = "10.1021/acsenergylett.9b00991",

language = "English",

volume = "4",

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journal = "ACS Energy Letters",

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Zhou, C, Lin, H, Neu, J, Zhou, Y, Chaaban, M, Lee, S, Worku, M, Chen, B, Clark, R, Cheng, W, Guan, J, Djurovich, P, Zhang, D, Lü, X, Bullock, J, Pak, C, Shatruk, M, Du, MH, Siegrist, T & Ma, B 2019, 'Green Emitting Single-Crystalline Bulk Assembly of Metal Halide Clusters with Near-Unity Photoluminescence Quantum Efficiency', ACS Energy Letters, vol. 4, no. 7, pp. 1579-1583. https://doi.org/10.1021/acsenergylett.9b00991

TY - JOUR

T1 - Green Emitting Single-Crystalline Bulk Assembly of Metal Halide Clusters with Near-Unity Photoluminescence Quantum Efficiency

AU - Zhou, Chenkun

AU - Lin, Haoran

AU - Neu, Jennifer

AU - Zhou, Yan

AU - Chaaban, Maya

AU - Lee, Sujin

AU - Worku, Michael

AU - Chen, Banghao

AU - Clark, Ronald

AU - Cheng, Wenhao

AU - Guan, Jingjiao

AU - Djurovich, Peter

AU - Zhang, Dongzhou

AU - Lü, Xujie

AU - Bullock, James

AU - Pak, Chongin

AU - Shatruk, Michael

AU - Du, Mao Hua

AU - Siegrist, Theo

AU - Ma, Biwu

PY - 2019/7/12

Y1 - 2019/7/12

N2 - Organic metal halide hybrids with zero-dimensional (0D) structure at the molecular level, or single-crystalline bulk assemblies of metal halides, are an emerging class of light-emitting materials with high photoluminescence quantum efficiencies (PLQEs) and color tunability. Here we report the synthesis and characterization of a new single-crystalline bulk assembly of metal halide clusters, (bmpy)9[ZnCl4]2[Pb3Cl11] (bmpy: 1-butyl-1-methylpyrrolidinium), which exhibits green emission peaked at 512 nm with a remarkable near-unity PLQE at room temperature. Detailed structural and photophysical studies suggest that there are two emitting states in [Pb3Cl11]5- clusters, whose populations are strongly dependent on the surrounding molecular environment that controls the excited-state structural distortion of [Pb3Cl11]5- clusters. High chemical- and photostability have also been demonstrated in this new material.

AB - Organic metal halide hybrids with zero-dimensional (0D) structure at the molecular level, or single-crystalline bulk assemblies of metal halides, are an emerging class of light-emitting materials with high photoluminescence quantum efficiencies (PLQEs) and color tunability. Here we report the synthesis and characterization of a new single-crystalline bulk assembly of metal halide clusters, (bmpy)9[ZnCl4]2[Pb3Cl11] (bmpy: 1-butyl-1-methylpyrrolidinium), which exhibits green emission peaked at 512 nm with a remarkable near-unity PLQE at room temperature. Detailed structural and photophysical studies suggest that there are two emitting states in [Pb3Cl11]5- clusters, whose populations are strongly dependent on the surrounding molecular environment that controls the excited-state structural distortion of [Pb3Cl11]5- clusters. High chemical- and photostability have also been demonstrated in this new material.

UR - http://www.scopus.com/inward/record.url?scp=85068124303&partnerID=8YFLogxK

U2 - 10.1021/acsenergylett.9b00991

DO - 10.1021/acsenergylett.9b00991

M3 - Article

AN - SCOPUS:85068124303

SN - 2380-8195

VL - 4

SP - 1579

EP - 1583

JO - ACS Energy Letters

JF - ACS Energy Letters

IS - 7

ER -

Green Emitting Single-Crystalline Bulk Assembly of Metal Halide Clusters with Near-Unity Photoluminescence Quantum Efficiency

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