Glass Corrosion in the Presence of Iron-Bearing Materials and Potential Corrosion Suppressors

Joelle Reiser; Lindsey Neill; Jamie Weaver; Benjamin Parruzot; Christopher Musa; James Neeway; Joseph Ryan; Nikolla Qafoku; Stéphane Gin; Nathalie A. Wall

doi:10.1557/opl.2015.503

Glass Corrosion in the Presence of Iron-Bearing Materials and Potential Corrosion Suppressors

Joelle Reiser, Lindsey Neill, Jamie Weaver, Benjamin Parruzot, Christopher Musa, James Neeway, Joseph Ryan, Nikolla Qafoku, Stéphane Gin, Nathalie A. Wall

Research output: Chapter in Book/Report/Conference proceeding › Conference contribution › peer-review

7 Scopus citations

Abstract

A complete understanding of radioactive waste glass interactions with near-field materials is essential for appropriate nuclear waste repository performance assessment. In many geologic repository designs, Fe is present both in the natural environment and in the containers that will hold the waste glasses. In this paper we discuss investigations of the alteration of International Simple Glass (ISG) in the presence of Fe° foil and hematite (Fe203). Based on solid analysis, ISG alteration is more pronounced in the presence of Fe° than with hematite. Additionally, typical glass corrosion is observed for distances of 5 mm between Fe materials and ISG, but incorporation of Fe in the alteration layer is only observed for systems exhibiting full contact between Fe° material and ISG. Solution analysis results indicate that diatomaceous earth minimizes corrosion to a larger extent than fumed silica does when present with iron and ISG.

Original language	English
Title of host publication	Scientific Basis for Nuclear Waste Management XXXVIII
Editors	Stephane Gin, Robert Jubin, Eric Vance, Josef Matyas
Publisher	Materials Research Society
Pages	139-144
Number of pages	6
ISBN (Electronic)	9781605117218
DOIs	https://doi.org/10.1557/opl.2015.503
State	Published - 2015
Externally published	Yes
Event	2014 MRS Fall Meeting - Boston, United States Duration: Nov 30 2014 → Dec 5 2014

Publication series

Name	Materials Research Society Symposium Proceedings
Volume	1744
ISSN (Print)	0272-9172

Conference

Conference	2014 MRS Fall Meeting
Country/Territory	United States
City	Boston
Period	11/30/14 → 12/5/14

UN SDGs

This output contributes to the following UN Sustainable Development Goals (SDGs)

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10.1557/opl.2015.503

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Reiser, J., Neill, L., Weaver, J., Parruzot, B., Musa, C., Neeway, J., Ryan, J., Qafoku, N., Gin, S., & Wall, N. A. (2015). Glass Corrosion in the Presence of Iron-Bearing Materials and Potential Corrosion Suppressors. In S. Gin, R. Jubin, E. Vance, & J. Matyas (Eds.), Scientific Basis for Nuclear Waste Management XXXVIII (pp. 139-144). (Materials Research Society Symposium Proceedings; Vol. 1744). Materials Research Society. https://doi.org/10.1557/opl.2015.503

Reiser, Joelle ; Neill, Lindsey ; Weaver, Jamie et al. / Glass Corrosion in the Presence of Iron-Bearing Materials and Potential Corrosion Suppressors. Scientific Basis for Nuclear Waste Management XXXVIII. editor / Stephane Gin ; Robert Jubin ; Eric Vance ; Josef Matyas. Materials Research Society, 2015. pp. 139-144 (Materials Research Society Symposium Proceedings).

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title = "Glass Corrosion in the Presence of Iron-Bearing Materials and Potential Corrosion Suppressors",

abstract = "A complete understanding of radioactive waste glass interactions with near-field materials is essential for appropriate nuclear waste repository performance assessment. In many geologic repository designs, Fe is present both in the natural environment and in the containers that will hold the waste glasses. In this paper we discuss investigations of the alteration of International Simple Glass (ISG) in the presence of Fe° foil and hematite (Fe203). Based on solid analysis, ISG alteration is more pronounced in the presence of Fe° than with hematite. Additionally, typical glass corrosion is observed for distances of 5 mm between Fe materials and ISG, but incorporation of Fe in the alteration layer is only observed for systems exhibiting full contact between Fe° material and ISG. Solution analysis results indicate that diatomaceous earth minimizes corrosion to a larger extent than fumed silica does when present with iron and ISG.",

author = "Joelle Reiser and Lindsey Neill and Jamie Weaver and Benjamin Parruzot and Christopher Musa and James Neeway and Joseph Ryan and Nikolla Qafoku and St{\'e}phane Gin and Wall, {Nathalie A.}",

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year = "2015",

doi = "10.1557/opl.2015.503",

language = "English",

series = "Materials Research Society Symposium Proceedings",

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Reiser, J, Neill, L, Weaver, J, Parruzot, B, Musa, C, Neeway, J, Ryan, J, Qafoku, N, Gin, S & Wall, NA 2015, Glass Corrosion in the Presence of Iron-Bearing Materials and Potential Corrosion Suppressors. in S Gin, R Jubin, E Vance & J Matyas (eds), Scientific Basis for Nuclear Waste Management XXXVIII. Materials Research Society Symposium Proceedings, vol. 1744, Materials Research Society, pp. 139-144, 2014 MRS Fall Meeting, Boston, United States, 11/30/14. https://doi.org/10.1557/opl.2015.503

Glass Corrosion in the Presence of Iron-Bearing Materials and Potential Corrosion Suppressors. / Reiser, Joelle; Neill, Lindsey; Weaver, Jamie et al.
Scientific Basis for Nuclear Waste Management XXXVIII. ed. / Stephane Gin; Robert Jubin; Eric Vance; Josef Matyas. Materials Research Society, 2015. p. 139-144 (Materials Research Society Symposium Proceedings; Vol. 1744).

Research output: Chapter in Book/Report/Conference proceeding › Conference contribution › peer-review

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AU - Reiser, Joelle

AU - Neill, Lindsey

AU - Weaver, Jamie

AU - Parruzot, Benjamin

AU - Musa, Christopher

AU - Neeway, James

AU - Ryan, Joseph

AU - Qafoku, Nikolla

AU - Gin, Stéphane

AU - Wall, Nathalie A.

PY - 2015

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N2 - A complete understanding of radioactive waste glass interactions with near-field materials is essential for appropriate nuclear waste repository performance assessment. In many geologic repository designs, Fe is present both in the natural environment and in the containers that will hold the waste glasses. In this paper we discuss investigations of the alteration of International Simple Glass (ISG) in the presence of Fe° foil and hematite (Fe203). Based on solid analysis, ISG alteration is more pronounced in the presence of Fe° than with hematite. Additionally, typical glass corrosion is observed for distances of 5 mm between Fe materials and ISG, but incorporation of Fe in the alteration layer is only observed for systems exhibiting full contact between Fe° material and ISG. Solution analysis results indicate that diatomaceous earth minimizes corrosion to a larger extent than fumed silica does when present with iron and ISG.

AB - A complete understanding of radioactive waste glass interactions with near-field materials is essential for appropriate nuclear waste repository performance assessment. In many geologic repository designs, Fe is present both in the natural environment and in the containers that will hold the waste glasses. In this paper we discuss investigations of the alteration of International Simple Glass (ISG) in the presence of Fe° foil and hematite (Fe203). Based on solid analysis, ISG alteration is more pronounced in the presence of Fe° than with hematite. Additionally, typical glass corrosion is observed for distances of 5 mm between Fe materials and ISG, but incorporation of Fe in the alteration layer is only observed for systems exhibiting full contact between Fe° material and ISG. Solution analysis results indicate that diatomaceous earth minimizes corrosion to a larger extent than fumed silica does when present with iron and ISG.

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ER -

Reiser J, Neill L, Weaver J, Parruzot B, Musa C, Neeway J et al. Glass Corrosion in the Presence of Iron-Bearing Materials and Potential Corrosion Suppressors. In Gin S, Jubin R, Vance E, Matyas J, editors, Scientific Basis for Nuclear Waste Management XXXVIII. Materials Research Society. 2015. p. 139-144. (Materials Research Society Symposium Proceedings). doi: 10.1557/opl.2015.503

Glass Corrosion in the Presence of Iron-Bearing Materials and Potential Corrosion Suppressors

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