Functionalization of used tire rubber by hydrosilylation

Madan Banda; Amit K. Naskar; K. Prasanna U. Perera; Cal Moreland; Tom Hodge; Kevin Wallace; Haskell W. Beckham; Dennis W. Smith

doi:10.5254/1.3672430

Functionalization of used tire rubber by hydrosilylation

Madan Banda
, Amit K. Naskar
, K. Prasanna U. Perera
, Cal Moreland
, Tom Hodge
, Kevin Wallace
, Haskell W. Beckham
, Dennis W. Smith

Research output: Contribution to journal › Article › peer-review

7 Scopus citations

Abstract

A new method for the surface modification of used tire rubber (UTR) is being developed. The method involves hydrosilylation of ground UTR particles with trichlorosilane (TCS) under various reaction conditions. The reaction has been carried out with and without solvents and catalysts (Karsted's/Pt catalyst). TCS treated UTR particles are then hydrolyzed to obtain silanol functionalized hydrosilylated rubber powder. Attenuated total reflection-Fourier transform infrared, solid-state ¹³C NMR spectroscopy, and thermogravimetric analysis are provided as evidence of hydrosilylation onto rubber particles.

Original language	English
Pages (from-to)	68-79
Number of pages	12
Journal	Rubber Chemistry and Technology
Volume	85
Issue number	1
DOIs	https://doi.org/10.5254/1.3672430
State	Published - Mar 2012

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title = "Functionalization of used tire rubber by hydrosilylation",

abstract = "A new method for the surface modification of used tire rubber (UTR) is being developed. The method involves hydrosilylation of ground UTR particles with trichlorosilane (TCS) under various reaction conditions. The reaction has been carried out with and without solvents and catalysts (Karsted's/Pt catalyst). TCS treated UTR particles are then hydrolyzed to obtain silanol functionalized hydrosilylated rubber powder. Attenuated total reflection-Fourier transform infrared, solid-state 13C NMR spectroscopy, and thermogravimetric analysis are provided as evidence of hydrosilylation onto rubber particles.",

author = "Madan Banda and Naskar, \{Amit K.\} and Perera, \{K. Prasanna U.\} and Cal Moreland and Tom Hodge and Kevin Wallace and Beckham, \{Haskell W.\} and Smith, \{Dennis W.\}",

year = "2012",

month = mar,

doi = "10.5254/1.3672430",

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T1 - Functionalization of used tire rubber by hydrosilylation

AU - Banda, Madan

AU - Naskar, Amit K.

AU - Perera, K. Prasanna U.

AU - Moreland, Cal

AU - Hodge, Tom

AU - Wallace, Kevin

AU - Beckham, Haskell W.

AU - Smith, Dennis W.

PY - 2012/3

Y1 - 2012/3

N2 - A new method for the surface modification of used tire rubber (UTR) is being developed. The method involves hydrosilylation of ground UTR particles with trichlorosilane (TCS) under various reaction conditions. The reaction has been carried out with and without solvents and catalysts (Karsted's/Pt catalyst). TCS treated UTR particles are then hydrolyzed to obtain silanol functionalized hydrosilylated rubber powder. Attenuated total reflection-Fourier transform infrared, solid-state 13C NMR spectroscopy, and thermogravimetric analysis are provided as evidence of hydrosilylation onto rubber particles.

AB - A new method for the surface modification of used tire rubber (UTR) is being developed. The method involves hydrosilylation of ground UTR particles with trichlorosilane (TCS) under various reaction conditions. The reaction has been carried out with and without solvents and catalysts (Karsted's/Pt catalyst). TCS treated UTR particles are then hydrolyzed to obtain silanol functionalized hydrosilylated rubber powder. Attenuated total reflection-Fourier transform infrared, solid-state 13C NMR spectroscopy, and thermogravimetric analysis are provided as evidence of hydrosilylation onto rubber particles.

UR - https://www.scopus.com/pages/publications/84860828103

U2 - 10.5254/1.3672430

DO - 10.5254/1.3672430

M3 - Article

AN - SCOPUS:84860828103

SN - 0035-9475

VL - 85

SP - 68

EP - 79

JO - Rubber Chemistry and Technology

JF - Rubber Chemistry and Technology

IS - 1

ER -

Functionalization of used tire rubber by hydrosilylation

Abstract

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