TY - JOUR
T1 - Full three-body primitive semiclassical treatment of [Formula Presented]
AU - Sohlberg, Karl
AU - Tuzun, Robert E.
AU - Sumpter, Bobby G.
AU - Noid, Donald W.
PY - 1998
Y1 - 1998
N2 - Primitive semiclassical quantization of H[Formula Presented] and D[Formula Presented] without the restriction of the separation of electronic and nuclear motions, reveals the existence of a small (10%) classical contribution to the one-electron chemical bond. It is found that in the electronic ground state the electron is exchanged classically between the two nuclei and that this exchange is correlated with the molecular vibration.
AB - Primitive semiclassical quantization of H[Formula Presented] and D[Formula Presented] without the restriction of the separation of electronic and nuclear motions, reveals the existence of a small (10%) classical contribution to the one-electron chemical bond. It is found that in the electronic ground state the electron is exchanged classically between the two nuclei and that this exchange is correlated with the molecular vibration.
UR - http://www.scopus.com/inward/record.url?scp=0000520586&partnerID=8YFLogxK
U2 - 10.1103/PhysRevA.57.906
DO - 10.1103/PhysRevA.57.906
M3 - Article
AN - SCOPUS:0000520586
SN - 1050-2947
VL - 57
SP - 906
EP - 913
JO - Physical Review A - Atomic, Molecular, and Optical Physics
JF - Physical Review A - Atomic, Molecular, and Optical Physics
IS - 2
ER -