Abstract
Isostructural metal-organic frameworks (MOFs) have been prepared from a variety of metal-oxide clusters, including transition metals, lanthanides, and actinides. Experimental and calculated shifts in O-H stretching frequencies for hydroxyl groups associated with the metal-oxide nodes reveal varying electronic properties for these units, thereby offering opportunities to tune support effects for other materials deposited onto these nodes.
| Original language | English |
|---|---|
| Pages (from-to) | 13246-13251 |
| Number of pages | 6 |
| Journal | Inorganic Chemistry |
| Volume | 57 |
| Issue number | 21 |
| DOIs | |
| State | Published - Nov 5 2018 |
| Externally published | Yes |
Funding
O.K.F. acknowledges the support from the U.S. Department of Energy, National Nuclear Security Administration, under Award Number DE-NA0003763 and Northwestern University for the experimental work. The theoretical work was supported as part of the Inorganometallic Catalyst Design Center, an EFRC funded by the DOE, Office of Basic Energy Sciences (DE-SC0012702). The computations were performed at the Minnesota Supercomputing Institute.