From the Junkyard to the Power Grid: Ambient Processing of Scrap Metals into Nanostructured Electrodes for Ultrafast Rechargeable Batteries

Nitin Muralidharan, Andrew S. Westover, Haotian Sun, Nicholas Galioto, Rachel E. Carter, Adam P. Cohn, Landon Oakes, Cary L. Pint

Research output: Contribution to journalArticlepeer-review

9 Scopus citations

Abstract

Here we present the first full cell battery device that is developed entirely from scrap metals of brass and steel - two of the most commonly used and discarded metals. A room-temperature chemical process is developed to convert brass and steel into functional electrodes for rechargeable energy storage that transforms these multicomponent alloys into redox-active iron oxide and copper oxide materials. The resulting steel-brass battery exhibits cell voltages up to 1.8 V, energy density up to 20 Wh/kg, power density up to 20 kW/kg, and stable cycling over 5000 cycles in alkaline electrolytes. Further, we show the versatility of this technique to enable processing of steel and brass materials of different shapes, sizes, and purity, such as screws and shavings, to produce functional battery components. The simplicity of this approach, building from chemicals commonly available in a household, enables a simple pathway to the local recovery, processing, and assembly of storage systems based on materials that would otherwise be discarded.

Original languageEnglish
Pages (from-to)1034-1041
Number of pages8
JournalACS Energy Letters
Volume1
Issue number5
DOIs
StatePublished - Nov 11 2016
Externally publishedYes

Funding

The authors would like to thank Matt McCarthy and PSC metals for useful insights into scrap metal refining procedures and on-site tours of PSC metals, a local scrap metal processing facility. We would also like to acknowledge Rizia Bardhan for use of Raman facilities. This work was supported in part by NASA EPSCoR Grant NNX13AB26A, the Vanderbilt University Discovery Grant program, and National Science Foundation graduate fellowship under grant no. 1445197.

FundersFunder number
NASA EPSCoRNNX13AB26A
National Science Foundation1445197
Vanderbilt University

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