Abstract
Recent advances in lower-cost processing of titanium, coupled with its potential use as a light weight material in engines and brakes has renewed interest in the tribological behavior of titanium alloys. To help establish a baseline for further studies on the tribology of titanium against various classes of counterface materials, pin-on-disk sliding friction and wear experiments were conducted on two different titanium alloys (Ti-6Al-4V and Ti-6Al-2Sn-4Zr-2Mo). Disks of these alloys were slid against fixed bearing balls composed of 440C stainless steel, silicon nitride, alumina, and polytetrafluoroethylene (PTFE) at two speeds: 0.3 and 1.0 m/s. The friction coefficient and wear rate were lower at the higher sliding speed. Ceramic sliders suffered unexpectedly higher wear than the steel slider. The wear rates, ranked from the highest to the lowest, were alumina, silicon nitride, and steel, respectively. This trend is inversely related to their hardness, but corresponds to their relative fracture toughness. Comparative tests on a Type 304 stainless steel disk supported the fracture toughness dependency. Energy dispersive spectroscopy (EDS) and X-ray diffraction (XRD) analyses confirmed the tendency of Ti alloys to transfer material to their counterfaces and suggested possible tribochemical reactions between the ceramic sliders and Ti alloy disks. These reaction products, which adhere to the ceramic sliders, may degrade the mechanical properties of the contact areas and result in high wear. The tribochemical reactions along with the fracture toughness dependency helped explain the high wear on the ceramic sliders.
Original language | English |
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Pages (from-to) | 1348-1356 |
Number of pages | 9 |
Journal | Wear |
Volume | 258 |
Issue number | 9 |
DOIs | |
State | Published - Apr 2005 |
Funding
The authors with to acknowledge with appreciation Y. Kosaka of Titanium Metals Corporation, USA, for supplying alloy billets along with their chemical analyses. Support for this research was provided by the U.S. Department of Energy, Assistant Secretary for Energy Efficiency and Renewable Energy, Office of FreedomCAR and Vehicle Technologies, as part of the High Strength Weight Reduction Materials Program, under contract DE-AC05-00OR22725 with UT-Battelle, LLC. J. Qu and N. Kulkarni were supported in part by appointments to the ORNL Postdoctoral Research Associates Program administered jointly by ORNL and ORISE.
Keywords
- Ceramics
- Material transfer
- Titanium
- Tribochemical reaction