Formation of [M + 14] anions from fluorene: Negative ion CI studies using GC/MS, MS/MS and FTMS

M. V. Buchanan; I. B. Rubin; M. B. Wise; G. L. Glish

doi:10.1002/bms.1200140807

Formation of [M + 14] anions from fluorene: Negative ion CI studies using GC/MS, MS/MS and FTMS

M. V. Buchanan, I. B. Rubin, M. B. Wise, G. L. Glish

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Abstract

Under negative ion chemical ionization conditions, fluorene yields an anion at [M + 14] mass units. This species has been determined to correspond to [M + O − 2H]⁻, with the loss of two hydrogen atoms at the C‐9 position and addition of oxygen to form a structure similar to 9‐fluorenone.

Original language	English
Pages (from-to)	395-399
Number of pages	5
Journal	Journal of Mass Spectrometry
Volume	14
Issue number	8
DOIs	https://doi.org/10.1002/bms.1200140807
State	Published - Aug 1987

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title = "Formation of [M + 14] anions from fluorene: Negative ion CI studies using GC/MS, MS/MS and FTMS",

abstract = "Under negative ion chemical ionization conditions, fluorene yields an anion at [M + 14] mass units. This species has been determined to correspond to [M + O − 2H]−, with the loss of two hydrogen atoms at the C‐9 position and addition of oxygen to form a structure similar to 9‐fluorenone.",

author = "Buchanan, {M. V.} and Rubin, {I. B.} and Wise, {M. B.} and Glish, {G. L.}",

year = "1987",

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AU - Wise, M. B.

AU - Glish, G. L.

PY - 1987/8

Y1 - 1987/8

N2 - Under negative ion chemical ionization conditions, fluorene yields an anion at [M + 14] mass units. This species has been determined to correspond to [M + O − 2H]−, with the loss of two hydrogen atoms at the C‐9 position and addition of oxygen to form a structure similar to 9‐fluorenone.

AB - Under negative ion chemical ionization conditions, fluorene yields an anion at [M + 14] mass units. This species has been determined to correspond to [M + O − 2H]−, with the loss of two hydrogen atoms at the C‐9 position and addition of oxygen to form a structure similar to 9‐fluorenone.

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DO - 10.1002/bms.1200140807

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JO - Journal of Mass Spectrometry

JF - Journal of Mass Spectrometry

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ER -

Formation of [M + 14] anions from fluorene: Negative ion CI studies using GC/MS, MS/MS and FTMS

Abstract

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