Formation of extended tapes of cyclic water hexamers in an organic molecular crysatal host

Radu Custelcean; Cerasela Afloroaei; Mircea Vlassa; Mihai Polverejan

doi:10.1002/1521-3773(20000901)39:17<3094::AID-ANIE3094>3.0.CO;2-P

Formation of extended tapes of cyclic water hexamers in an organic molecular crysatal host

Radu Custelcean, Cerasela Afloroaei, Mircea Vlassa, Mihai Polverejan

Research output: Contribution to journal › Article › peer-review

274 Scopus citations

Abstract

An icelike chair conformation is adopted by the cyclic water hexamers found in an organic inclusion complex. Self-assembly of the hexamers into one-dimensional tapes (see picture), which interact very weakly with the organic host, confers on them characteristics similar to those of liquid water, as attested by FT-IR spectroscopy.

Original language	English
Pages (from-to)	3094-3096
Number of pages	3
Journal	Angewandte Chemie - International Edition
Volume	39
Issue number	17
DOIs	https://doi.org/10.1002/1521-3773(20000901)39:17<3094::AID-ANIE3094>3.0.CO;2-P
State	Published - Sep 1 2000
Externally published	Yes

Keywords

Hydrogen bonds
Inclusion compounds
Supramolecular chemistry
Water

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10.1002/1521-3773(20000901)39:17<3094::AID-ANIE3094>3.0.CO;2-P

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abstract = "An icelike chair conformation is adopted by the cyclic water hexamers found in an organic inclusion complex. Self-assembly of the hexamers into one-dimensional tapes (see picture), which interact very weakly with the organic host, confers on them characteristics similar to those of liquid water, as attested by FT-IR spectroscopy.",

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AU - Custelcean, Radu

AU - Afloroaei, Cerasela

AU - Vlassa, Mircea

AU - Polverejan, Mihai

PY - 2000/9/1

Y1 - 2000/9/1

N2 - An icelike chair conformation is adopted by the cyclic water hexamers found in an organic inclusion complex. Self-assembly of the hexamers into one-dimensional tapes (see picture), which interact very weakly with the organic host, confers on them characteristics similar to those of liquid water, as attested by FT-IR spectroscopy.

AB - An icelike chair conformation is adopted by the cyclic water hexamers found in an organic inclusion complex. Self-assembly of the hexamers into one-dimensional tapes (see picture), which interact very weakly with the organic host, confers on them characteristics similar to those of liquid water, as attested by FT-IR spectroscopy.

KW - Hydrogen bonds

KW - Inclusion compounds

KW - Supramolecular chemistry

KW - Water

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DO - 10.1002/1521-3773(20000901)39:17<3094::AID-ANIE3094>3.0.CO;2-P

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ER -

Formation of extended tapes of cyclic water hexamers in an organic molecular crysatal host

Abstract

Keywords

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