Forensics of soot: C5-related nanostructure as a diagnostic of in-cylinder chemistry

Randy L. Vander Wal; Andrea Strzelec; Todd J. Toops; C. Stuart Daw; Caroline L. Genzale

doi:10.1016/j.fuel.2013.05.104

Forensics of soot: C5-related nanostructure as a diagnostic of in-cylinder chemistry

Randy L. Vander Wal, Andrea Strzelec, Todd J. Toops, C. Stuart Daw, Caroline L. Genzale

Applied Catalysis&Emissions Res. Group

Research output: Contribution to journal › Article › peer-review

47 Scopus citations

Abstract

We report observations of nanoscale microstructural changes in soot from an experimental light-duty diesel engine, produced with varying levels of biodiesel fuel blending. Based on these observations and current information in the literature, we propose a mechanistic hypothesis to explain the effects of biodiesel blending. Our underlying assumption is that particulate nanostructure is closely coupled to the local chemistry at the time the soot is formed. In the context of in-cylinder soot formation, this implies that changes in nanostructure may aid in diagnosing important changes in fuel-air mixing.

Original language	English
Pages (from-to)	522-526
Number of pages	5
Journal	Fuel
Volume	113
DOIs	https://doi.org/10.1016/j.fuel.2013.05.104
State	Published - 2013

Funding

This work was funded by DOE OVT under contract with Oak Ridge National Laboratory. The authors acknowledge the support of DOE Sponsors Gurpreet Singh, Ken Howden and Kevin Stork.

Funders	Funder number
DOE Sponsors Gurpreet Singh
Ken Howden and Kevin Stork
U.S. Department of Energy
Oak Ridge National Laboratory

Keywords

Biodiesel
HRTEM
In-cylinder mixing
Nanostructure
Soot

UN SDGs

This output contributes to the following UN Sustainable Development Goals (SDGs)

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10.1016/j.fuel.2013.05.104

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@article{344a04909b4444f597c2e45d74d7aaca,

title = "Forensics of soot: C5-related nanostructure as a diagnostic of in-cylinder chemistry",

abstract = "We report observations of nanoscale microstructural changes in soot from an experimental light-duty diesel engine, produced with varying levels of biodiesel fuel blending. Based on these observations and current information in the literature, we propose a mechanistic hypothesis to explain the effects of biodiesel blending. Our underlying assumption is that particulate nanostructure is closely coupled to the local chemistry at the time the soot is formed. In the context of in-cylinder soot formation, this implies that changes in nanostructure may aid in diagnosing important changes in fuel-air mixing.",

keywords = "Biodiesel, HRTEM, In-cylinder mixing, Nanostructure, Soot",

author = "{Vander Wal}, {Randy L.} and Andrea Strzelec and Toops, {Todd J.} and {Stuart Daw}, C. and Genzale, {Caroline L.}",

year = "2013",

doi = "10.1016/j.fuel.2013.05.104",

language = "English",

volume = "113",

pages = "522--526",

journal = "Fuel",

issn = "0016-2361",

publisher = "Elsevier",

}

TY - JOUR

T1 - Forensics of soot

T2 - C5-related nanostructure as a diagnostic of in-cylinder chemistry

AU - Vander Wal, Randy L.

AU - Strzelec, Andrea

AU - Toops, Todd J.

AU - Stuart Daw, C.

AU - Genzale, Caroline L.

PY - 2013

Y1 - 2013

N2 - We report observations of nanoscale microstructural changes in soot from an experimental light-duty diesel engine, produced with varying levels of biodiesel fuel blending. Based on these observations and current information in the literature, we propose a mechanistic hypothesis to explain the effects of biodiesel blending. Our underlying assumption is that particulate nanostructure is closely coupled to the local chemistry at the time the soot is formed. In the context of in-cylinder soot formation, this implies that changes in nanostructure may aid in diagnosing important changes in fuel-air mixing.

AB - We report observations of nanoscale microstructural changes in soot from an experimental light-duty diesel engine, produced with varying levels of biodiesel fuel blending. Based on these observations and current information in the literature, we propose a mechanistic hypothesis to explain the effects of biodiesel blending. Our underlying assumption is that particulate nanostructure is closely coupled to the local chemistry at the time the soot is formed. In the context of in-cylinder soot formation, this implies that changes in nanostructure may aid in diagnosing important changes in fuel-air mixing.

KW - Biodiesel

KW - HRTEM

KW - In-cylinder mixing

KW - Nanostructure

KW - Soot

UR - http://www.scopus.com/inward/record.url?scp=84879926964&partnerID=8YFLogxK

U2 - 10.1016/j.fuel.2013.05.104

DO - 10.1016/j.fuel.2013.05.104

M3 - Article

AN - SCOPUS:84879926964

SN - 0016-2361

VL - 113

SP - 522

EP - 526

JO - Fuel

JF - Fuel

ER -

Forensics of soot: C5-related nanostructure as a diagnostic of in-cylinder chemistry

Abstract

Funding

Keywords

UN SDGs

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