Fluorinated microporous organic polymers: Design and applications in CO2 adsorption and conversion

Zhen Zhen Yang; Yanfei Zhao; Hongye Zhang; Bo Yu; Zhishuang Ma; Guipeng Ji; Zhimin Liu

doi:10.1039/c4cc06423b

Fluorinated microporous organic polymers: Design and applications in CO₂ adsorption and conversion

Zhen Zhen Yang
, Yanfei Zhao
, Hongye Zhang
, Bo Yu
, Zhishuang Ma
, Guipeng Ji
, Zhimin Liu

Research output: Contribution to journal › Article › peer-review

113 Scopus citations

Abstract

Fluorinated microporous organic polymers (F-MOPs) were designed, showing twice higher CO₂ adsorption capacity than corresponding non-fluorous MOPs. The incorporation of phenanthroline moieties into F-MOPs afforded them the ability to coordinate with Ag(I), and the resultant F-MOP-Ag(I) displayed high efficiency for the reaction of CO₂ with propargyl alcohols to form α-alkylidene cyclic carbonates at 25 °C.

Original language	English
Pages (from-to)	13910-13913
Number of pages	4
Journal	Chemical Communications
Volume	50
Issue number	90
DOIs	https://doi.org/10.1039/c4cc06423b
State	Published - Oct 16 2014
Externally published	Yes

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title = "Fluorinated microporous organic polymers: Design and applications in CO2 adsorption and conversion",

abstract = "Fluorinated microporous organic polymers (F-MOPs) were designed, showing twice higher CO2 adsorption capacity than corresponding non-fluorous MOPs. The incorporation of phenanthroline moieties into F-MOPs afforded them the ability to coordinate with Ag(I), and the resultant F-MOP-Ag(I) displayed high efficiency for the reaction of CO2 with propargyl alcohols to form α-alkylidene cyclic carbonates at 25 °C.",

author = "Yang, \{Zhen Zhen\} and Yanfei Zhao and Hongye Zhang and Bo Yu and Zhishuang Ma and Guipeng Ji and Zhimin Liu",

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T1 - Fluorinated microporous organic polymers

T2 - Design and applications in CO2 adsorption and conversion

AU - Yang, Zhen Zhen

AU - Zhao, Yanfei

AU - Zhang, Hongye

AU - Yu, Bo

AU - Ma, Zhishuang

AU - Ji, Guipeng

AU - Liu, Zhimin

PY - 2014/10/16

Y1 - 2014/10/16

N2 - Fluorinated microporous organic polymers (F-MOPs) were designed, showing twice higher CO2 adsorption capacity than corresponding non-fluorous MOPs. The incorporation of phenanthroline moieties into F-MOPs afforded them the ability to coordinate with Ag(I), and the resultant F-MOP-Ag(I) displayed high efficiency for the reaction of CO2 with propargyl alcohols to form α-alkylidene cyclic carbonates at 25 °C.

AB - Fluorinated microporous organic polymers (F-MOPs) were designed, showing twice higher CO2 adsorption capacity than corresponding non-fluorous MOPs. The incorporation of phenanthroline moieties into F-MOPs afforded them the ability to coordinate with Ag(I), and the resultant F-MOP-Ag(I) displayed high efficiency for the reaction of CO2 with propargyl alcohols to form α-alkylidene cyclic carbonates at 25 °C.

UR - https://www.scopus.com/pages/publications/84907969972

U2 - 10.1039/c4cc06423b

DO - 10.1039/c4cc06423b

M3 - Article

AN - SCOPUS:84907969972

SN - 1359-7345

VL - 50

SP - 13910

EP - 13913

JO - Chemical Communications

JF - Chemical Communications

IS - 90

ER -

Fluorinated microporous organic polymers: Design and applications in CO₂ adsorption and conversion

Abstract

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