Fluorinated microporous organic polymers: Design and applications in CO2 adsorption and conversion

Zhen Zhen Yang; Yanfei Zhao; Hongye Zhang; Bo Yu; Zhishuang Ma; Guipeng Ji; Zhimin Liu

doi:10.1039/c4cc06423b

Fluorinated microporous organic polymers: Design and applications in CO₂ adsorption and conversion

Zhen Zhen Yang, Yanfei Zhao, Hongye Zhang, Bo Yu, Zhishuang Ma, Guipeng Ji, Zhimin Liu

Research output: Contribution to journal › Article › peer-review

103 Scopus citations

Abstract

Fluorinated microporous organic polymers (F-MOPs) were designed, showing twice higher CO₂ adsorption capacity than corresponding non-fluorous MOPs. The incorporation of phenanthroline moieties into F-MOPs afforded them the ability to coordinate with Ag(I), and the resultant F-MOP-Ag(I) displayed high efficiency for the reaction of CO₂ with propargyl alcohols to form α-alkylidene cyclic carbonates at 25 °C.

Original language	English
Pages (from-to)	13910-13913
Number of pages	4
Journal	Chemical Communications
Volume	50
Issue number	90
DOIs	https://doi.org/10.1039/c4cc06423b
State	Published - Oct 16 2014
Externally published	Yes

Funding

Funders	Funder number
National Natural Science Foundation of China	21321063, 21402208, 21125314

Access to Document

10.1039/c4cc06423b

Cite this

@article{13d619502ad44c9da5ad5455b68902ce,

title = "Fluorinated microporous organic polymers: Design and applications in CO2 adsorption and conversion",

abstract = "Fluorinated microporous organic polymers (F-MOPs) were designed, showing twice higher CO2 adsorption capacity than corresponding non-fluorous MOPs. The incorporation of phenanthroline moieties into F-MOPs afforded them the ability to coordinate with Ag(I), and the resultant F-MOP-Ag(I) displayed high efficiency for the reaction of CO2 with propargyl alcohols to form α-alkylidene cyclic carbonates at 25 °C.",

author = "Yang, {Zhen Zhen} and Yanfei Zhao and Hongye Zhang and Bo Yu and Zhishuang Ma and Guipeng Ji and Zhimin Liu",

year = "2014",

month = oct,

day = "16",

doi = "10.1039/c4cc06423b",

language = "English",

volume = "50",

pages = "13910--13913",

journal = "Chemical Communications",

issn = "1359-7345",

publisher = "Royal Society of Chemistry",

number = "90",

}

TY - JOUR

T1 - Fluorinated microporous organic polymers

T2 - Design and applications in CO2 adsorption and conversion

AU - Yang, Zhen Zhen

AU - Zhao, Yanfei

AU - Zhang, Hongye

AU - Yu, Bo

AU - Ma, Zhishuang

AU - Ji, Guipeng

AU - Liu, Zhimin

PY - 2014/10/16

Y1 - 2014/10/16

N2 - Fluorinated microporous organic polymers (F-MOPs) were designed, showing twice higher CO2 adsorption capacity than corresponding non-fluorous MOPs. The incorporation of phenanthroline moieties into F-MOPs afforded them the ability to coordinate with Ag(I), and the resultant F-MOP-Ag(I) displayed high efficiency for the reaction of CO2 with propargyl alcohols to form α-alkylidene cyclic carbonates at 25 °C.

AB - Fluorinated microporous organic polymers (F-MOPs) were designed, showing twice higher CO2 adsorption capacity than corresponding non-fluorous MOPs. The incorporation of phenanthroline moieties into F-MOPs afforded them the ability to coordinate with Ag(I), and the resultant F-MOP-Ag(I) displayed high efficiency for the reaction of CO2 with propargyl alcohols to form α-alkylidene cyclic carbonates at 25 °C.

UR - http://www.scopus.com/inward/record.url?scp=84907969972&partnerID=8YFLogxK

U2 - 10.1039/c4cc06423b

DO - 10.1039/c4cc06423b

M3 - Article

AN - SCOPUS:84907969972

SN - 1359-7345

VL - 50

SP - 13910

EP - 13913

JO - Chemical Communications

JF - Chemical Communications

IS - 90

ER -

Fluorinated microporous organic polymers: Design and applications in CO₂ adsorption and conversion

Abstract

Funding

Access to Document

Other files and links

Fingerprint

Cite this